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31.
32.
Treatment with metallic copper for the removal of elemental sulfur from bitumen extracted from sedimentary rocks or petroleum is the most widely used method. Little attention has been paid, however, to its disadvantages. It was observed that copper can interact with some polar organic substances during conventional sulfur removal, which can strongly influence the quantitative and qualitative determination of bitumen, as has been confirmed by interaction of long-chain fatty acids with copper. The copper soap generated was analyzed by element analysis, inductively coupled plasma optical emission spectrometry (ICP-OES), thermal analysis (TG-DSC) and Fourier Transform Infrared spectroscopy (FFIR). Mechanism of the interaction was investigated and elucidated. Our experimental results would necessitate improvement of the present method for sulfur removal and/or a search for a new one. 相似文献
33.
通过对呼伦贝尔市煤矿地质环境敏感性的综合评价,结合当地实际情况,提出了以修筑拦挡建筑物、支撑与坡面防护、锚固、排水、选择更合理的开采工艺等技术手段,对该地区地质灾害进行防治的方案。方案对海拉尔河河道治理、生物措施、井下回填工程、加固边坡、抽排水、发展煤矸石砖厂、移民避让、招商引资8个部分提出了防治方法,促进地质环境治理工作的进行。 相似文献
34.
湖南煤炭坝矿区岩溶水害特征及防治对策 总被引:2,自引:0,他引:2
刘北虎 《地质灾害与环境保护》2008,19(2):18-23
煤炭坝矿区是全国闻名的大水矿区,矿区最大涌水量已超过12000m^3/h,年排水费用达1.2亿元,吨煤成本达150元,并呈上升趋势,严重影响了煤矿的安全生产。本文在详细论述煤炭坝矿区水文地质特征的基础上提出了切实可行的治理思路,治理方法,并进行了效益预测。对矿区防治水患具有指导性作用。 相似文献
35.
Environmental tracers as indicators of karst conduits in groundwater in South Dakota,USA 总被引:3,自引:1,他引:2
Environmental tracers sampled from the carbonate Madison aquifer on the eastern flank of the Black Hills, South Dakota, USA indicated the approximate locations of four major karst conduits. Contamination issues are a major concern because these conduits are characterized by direct connections to sinking streams, high groundwater velocities, and proximity to public water supplies. Objectives of the study were to estimate approximate conduit locations and assess possible anthropogenic influences associated with conduits. Anomalies of young groundwater based on chlorofluorocarbons (CFCs), tritium, and electrical conductivity (EC) indicated fast moving, focused flow and thus the likely presence of conduits. δ18O was useful for determining sources of recharge for each conduit, and nitrate was a useful tracer for assessing flow paths for anthropogenic influences. Two of the four conduits terminate at or near a large spring complex. CFC apparent ages ranged from 15 years near conduits to >50 years in other areas. Nitrate-N concentrations >0.4 mg/L in groundwater were associated with each of the four conduits compared with concentrations ranging from <0.1 to 0.4 mg/L in other areas. These higher nitrate-N concentrations probably do not result from sinking streams but rather from other areas of infiltration. 相似文献
36.
Evaluation of distributed recharge in an upland semi-arid karst system: the West Bank Mountain Aquifer,Middle East 总被引:2,自引:0,他引:2
Assessment of recharge in a structurally complex upland karst limestone aquifer situated in a semi-arid environment is difficult. Resort to surrogate indicators such as measurement of spring outflow and borehole discharge, is a common alternative, and attempts to apply conventional soil moisture deficit analysis may not adequately account for the intermittent spate conditions that arise in such environments. A modelling approach has been made using the West Bank Mountain Aquifer system in the Middle East as a trial. The model uses object oriented software which allows various objects to be switched on and off. Each of the main recharge processes identified in the West Bank is incorporated. The model allows either conventional soil moisture deficit analysis calculations or wetting threshold calculations to be made as appropriate, and accommodates both direct recharge and secondary recharge. Daily time steps enable recharge and runoff routing to be calculated for each node. Model runs have enabled a series of simulations for each of the three aquifer basins in the West Bank and for the whole of the West Bank. These provide recharge estimates comparable to those prepared by earlier workers by conventional means. The model is adaptable and has been successfully used in other environments. 相似文献
37.
Surface contamination with radioactive caesium introduced into the environment after the accident at the Chernobyl nuclear
plant was high enough in the Crimean Mountains to allow using radiocaesium as an indicator of penetration of radioactive contamination
into a karst system. Caesium concentrations have been studied in soils above Marble Cave, Tchatyrdag Plateau, in percolation
waters and in sediments transported by percolation waters within the cave. Contamination of the daylight surface with 137Cs is about 30 kqB m–2 which is approximately 13 times higher than the density of global fallouts. Besides 137Cs, almost all samples showed presence of 134Cs with the 137Cs/134Cs ratio close to that of Chernobyl contaminations.
Concentrations of 137Cs range from 9 to 15 mBq l–1 in the present percolation waters in the cave. In sediments related to percolation waters 134Cs is detected in some samples besides 137Cs, although the effect of 228Ac is not ruled out. Surprisingly, the highest concentrations of radiocaesium were measured in "old" sediments in the cave's
lower series. These sediments are not associated with modern percolation and are represented by a clay/moonmilk alternating
sequence deposited in an old dried cave lake. Moonmilk layers have higher caesium content than clay. It is assumed that Chernobyl
caesium was transported into the cave with aerosols which were then deposited mainly in areas where condensation occurs. The
sampling site is located just in the boundary between two microclimatic zones with a temperature gradient of 0.5 °C. Active
condensation processes occur in this area. Caesium was not detected in another similar sampling site (old lake deposits) located
within homogeneous microclimatic conditions. If the above interpretation is correct, these results show the geochemical significance
of the aerosol-condensation mechanism of mass transport and localisation.
Received: 1 June 1995 · Accepted: 4 December 1995 相似文献
38.
A geochemical evaluation of the Szc-Halimba-Kisld area, Hungary, covering an area of more than 200 km2 is presented using different statistical and geostatistical methods. The study area is a representative example of allochtonous karst bauxite accumulation. The three groups of deposits studied here have been explored and mined since 1950. Several thousand boreholes have been drilled, and bauxite cores were analyzed for the five main chemical components. A total of 80,000 pleces of analytical data were processed, followed by a geological examination of borehole logs and of mining excavations.The quantitative geochemical evaluation of the data set led to both geochemical and practical results: The geochemical behavior of the allochtonous, clastic karst bauxite deposits differs essentially from that of the autochtonous and parautochtonous ones, as well as that of the lateritic bauxite deposits. The deposits of the study area can be split into several subsequent geochemical-sedimentological units, each representing an event of bauxite transport and accumulation. Clear regional patterns can be revealed in the composition of these units. The geostatistically measured chemical variability of the geochemical units is rather different, the lowest units showing the smallest variability. The interrelations of the main chemical components are weaker and more irregular in the studied deposits than in the autochtonous lateritic bauxite deposits. Additional local genetic features, such as transport routes, can be delineated by the methods applied. Within each deposit, local changes of chemical composition and of its variability can be determined more precisely. These results can be used in bauxite prospecting and exploration, because areas of high or low bauxite quality can be predicted. 相似文献
39.
G. Günay 《Environmental Geology》2006,51(2):229-240
The Sakarya River is one of the largest rivers in Turkey and is fed mainly from Sakaryabaşı springs. The Sakaryabaşı springs are located in the Central Anatolia and issue from confined/semi-confined karst having a thermal component and therefore, having quite different hydrogeological characteristics as compared to the Taurus Karst region, a typical example of the Mediterranean type of karst. The karstic carbonate rocks that form the groundwater reservoir are overlain by a thick semi-pervious overburden of mainly clastics of Neogene age. Tectonics is the major factor controlling the occurrence of the karst springs in the area where topography is rather flat. This study aimed at explaining the occurrence and movement of the karst groundwater within the system by use of hydrogeological, chemical, and isotopic tools. Isotopic composition of the waters revealed that all waters in the region are of meteoric origin and the thermal component is due to deep circulation. The catchment area of the hydrogeological system extends to the south and groundwater movement is towards the outlets, which are in a depression along a major fault. The movement of the groundwater, based on analysis of remotely sensed images, is controlled mainly by structural elements. 相似文献
40.
在灰岩地区钻探施工过程中,常见孔壁坍塌、掉块现象,尤其在含泥晶灰岩地层分布区钻进过程中,这种现象尤为突出,轻则影响钻探施工效率,重则造成钻探孔内事故。针对孔内坍塌、掉块现象的征兆及特点,提出了相对应的处理办法。 相似文献