湿地土壤和沉积物异化铁还原过程研究进展

异化铁还原是湿地土壤和沉积物中重要的生物地球化学过程,也是有机质矿化的主要途径之一。湿地干湿交替等过程会使土壤的氧化还原状态发生改变,影响铁元素及与其相关的元素的迁移和转化。总结了湿地土壤和沉积物中异化铁还原过程及其与碳、磷、硫等元素在生物地球化学循环关键过程中的相互作用,阐述了湿地土壤和沉积物中异化铁还原过程对微量金属元素迁移和转化的影响,分析了影响湿地土壤和沉积物异化铁还原过程的主要环境因子。未来相关研究应集中于湿地土壤和沉积物中异化铁还原微生物分析和纯化、不同有机质形式对异化铁还原过程的影响以及异化铁还原对土壤有机质矿化的贡献。     

Effects of rainfall intensity and compaction on water transport from opencast coal mine soils: An experimental study

The use of heavy machinery during opencast coal mining can result in soil compaction. Severe soil compaction has a negative impact on the transport of water and gas in the soil. In addition, rainfall intensity has traditionally been related to soil surface sealing affecting water transport. To assess the effects of rainfall intensity and compaction on water infiltration and surface runoff in an opencast coal mining area, the disturbed soils from the Antaibao opencast mine in Shanxi Province, China, were collected. Four soil columns with different bulk densities (i.e., 1.4 g cm^-3, 1.5 g cm^-3, 1.6 g cm^-3, and 1.7 g cm^-3) were designed, and each column received water five times at rainfall intensities of 23.12, 28.91, 38.54, 57.81, and 115.62 mm hr^-1. The total volume of runoff, the time to start runoff, and the volumetric water contents at the depths of 5 cm, 15 cm, 25 cm, 35 cm, 45 cm, 55 cm, and 65 cm were measured. Under the same soil bulk density, high rainfall intensity reduced infiltration, increased surface runoff, and decreased the magnitude of change in the volumetric water contents at different depths. Under the same rainfall intensity, the soil column with a high bulk density showed relatively low water infiltration. Treatments 3 (1.6 g cm^-3) and 4 (1.7 g cm^-3) had very small changes in volumetric water contents of the profiles even under a lower rainfall intensity. Severe soil compaction was highly prone to surface runoff after rainfall. Engineering and revegetation measures are available to improve compacted soil quality in dumps. Our results provide a theoretical basis for the management of land reclamation in opencast coal mine areas.     

Influence of ferric iron on phase equilibria in greenschist facies assemblages: the hematite‐rich metasedimentary rocks from the Monti Pisani (Northern Apennines)

We have investigated the effects of different Fe₂O₃ bulk contents on the calculated phase equilibria of low‐T/intermediate‐P metasedimentary rocks. Thermodynamic modelling within the MnO–Na₂O–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (MnNKFMASHTO) chemical system of chloritoid‐bearing hematite‐rich metasedimentary rocks from the Variscan basement of the Pisani Mountains (Northern Apennines, Italy) fails to reproduce the observed mineral compositions when the bulk Fe₂O₃ is determined through titration. The mismatch between observed and computed mineral compositions and assemblage is resolved by tuning the effective ferric iron content by P–XFe₂O₃ diagrams, obtaining equilibration conditions of 475 °C and 9–10 kbar related to a post‐compressional phase of the Alpine collision. The introduction of ferric iron affects the stability of the main rock‐forming silicates that often yield important thermobaric information. In Fe₂O₃‐rich compositions, garnet‐ and carpholite‐in curves shift towards higher temperatures with respect to the Fe₂O₃‐free systems. The presence of a ferric‐iron oxide (hematite) prevents the formation of biotite in the mineral assemblage even at temperatures approaching 550 °C. The use of P–T–XFe₂O₃ phase diagrams may also provide P–T information in common greenschist facies metasedimentary rocks.     

利用井中三分量磁测△T三维异常体特征分析磁铁矿体产状——以山东省兰陵县兰陵矿区古林矿段为例

常规的单孔井中三分量磁测能在二维空间上较准确地判断磁性地质体的方位和大致空间位置,该文利用群孔井中三分量磁测实现在三维空间上对磁性地质体赋存状态的准确判定,特别是ΔT磁参量,能更准确、更清晰地反映磁性地质体的三维空间形态。对古林矿区群孔井中三分量磁测数据进行整理后,利用Voxler软件进行井中三分量磁测ΔT磁异常三维立体成图,利用各岩性已知磁性参数特征,圈定可推断为矿致的ΔT三维异常体。通过对圈定的矿致三维异常体的分析,正确的推断了本矿区磁铁矿体的空间赋存状态,为该矿区勘查工作的顺利进行,起到了有力的推动作用。     

利用三山岛金矿尾矿制备塑料母料

经磨矿作业后,金矿选别过程通常会产生大量细粒尾矿,三山岛金矿尾矿堆存量较大,尾矿资源丰富。尾矿中有价元素含量不高,尾矿中丰富的非金属矿资源尚未得到有效回收利用。本文以三山岛金矿尾矿为主要原料,进行了有价元素回收探索研究、分级提纯研究、表面改性研究以及制备PP,PE母料添料的试验研究。将分级提纯后的尾矿作为碳酸钙替代料制备的PP,PE母料添料具有良好的性能指标,实现节能减排,减轻环境负担的同时,减少橡胶原料的消耗。     

大气气溶胶中的铁及其溶解度研究综述

生物活性铁(Fe) 进入生物地球化学循环中能够调节碳循环,影响海洋初级生产力,间接影响全球气候变化。决定 Fe生物可利用度的关键因子是可溶Fe含量,其中大气气溶胶的长距离传输是上层海洋获取生物可利用Fe的重要来源。近年来,对气溶胶中的Fe及溶解度的研究取得了重要进展,包括对不同区域Fe质量浓度和溶解度的观测以及对Fe溶解度影响因素的讨论。基于以上研究成果,汇总了近二十年全球部分陆地和海洋站点观测所得的不同粒径气溶胶颗粒物中的Fe质量浓度及其溶解度数据;重点介绍了气溶胶沉降入海洋前影响Fe溶解度的主要因素,包括Fe的来源、大气物理过程以及大气化学和传输混合过程等,并就各影响因素间的关联及相对重要性展开讨论;对未来气溶胶 Fe的研究方向和方法提出建议。     

灰色聚类分析在煤矿瓦斯分区中的应用

以灰色理论为依据,结合南屯煤矿瓦斯分布规律的研究,探索了利用灰色聚类分析进行煤矿瓦斯分布规律研究的一般方法。      

密集台网微震定位技术在矿山开采动态监测中的应用研究

利用河南新密超化镇某矿区布设的密集临时地震台网观测资料,通过微震震源精确定位手段,实现强干扰背景下该地区某煤矿地下开采面的定位追踪试验研究。微震定位后,爆破点位置的水平精度为±70m,垂直精度为±500m。试验研究结果表明,利用高密度数字地震台网资料,可较为准确地监测矿山地下开采面的动态变化,从而实现对矿产资源越界开采和小矿非法开采的有效制约和监督。同时,本次试验结果显示地震台网的监测控制范围受爆炸源能量、地下开采面的深度、监测区背景噪声、监测仪器的灵敏度和抗干扰能力等因素影响,试验结果可对今后矿区地震监测台网的合理布设提供有效指导。     

老挝爬立山铁矿二长花岗斑岩地球化学特征及其成矿意义

老挝爬立山铁矿位于长山褶皱带北西端,为一个大型矽卡岩型铁矿床。铁矿化产于二长花岗斑岩的内、外接触带。二长花岗斑岩具有富碱,硅、铝过饱和的特征,属钙碱性岩。微量元素配分模式与正常大陆弧花岗岩类似,稀土配分模式为右倾轻稀土富集型,正铕异常,轻重稀土分馏明显,属下地壳重熔被动侵位形成的"S"型花岗岩。岩体U-Pb年龄为283±2.9Ma,侵位时间为早二叠世。爬立山铁矿床潜在资源量巨大,外围地区具有相同类型铁矿床的找矿远景。     

中国钢铁产品国际贸易流与碳排放跨境转移

控制温室气体排放最终要落实到不同国家、不同行业之间的利益分配和责任分担,尤其是通过国际商品贸易转移的碳排放是在国家间分配排放配额时必须考虑的指标。基于中国钢铁产品国际贸易流的分析表明,中国在国际钢铁产品贸易中处于垂直产业内贸易的低端,中国具有比较优势的钢铁产品多为加工程度低、技术含量低、能源消耗强度大的初级产品。由于我国进出口钢铁产品在附加价值和能源消耗强度方面存在明显的差异,随着中国钢铁产品国际贸易规模的扩大,使大量CO₂排放责任向中国净转移。我国学者应以更加积极的姿态参与到国际谈判、国际规则的制订中,从产品生产者和消费者两个层面合理界定中国在全球温室气体减排中的责任,力争在气候变化国际谈判中确保中国的经济贸易利益。