东疆红山Cu-Au矿床氧化带硫酸盐矿物穆斯堡尔谱特征及其意义

穆斯堡尔谱对确定铁离子占位、核外环境及氧化态方面有着独特的优势。在红山铜金矿床氧化带硫酸盐矿物的XRD、TA、湿法化学分析和红外光谱测试的基础上,测定了板铁矾、针绿矾等8种硫酸盐矿物的室温57Fe穆斯堡尔谱,并根据常温下硫酸盐矿物穆斯堡尔谱参数和其晶体结构中Fe3+和Fe2+的占据位置对其谱峰进行了指派。结果表明本矿床氧化带硫酸盐矿物的穆斯堡尔谱的同质异能位移较小、四级矩分裂值分布范围较大、无磁超精细分裂等特征,且硫酸盐矿物结构中存在着共价键。通过与青海锡铁山铅锌矿氧化带硫酸盐矿物的穆斯堡尔谱相比较,两者在近地表风化及氧化过程中所处的物理化学条件基本相同,酸性和氧化性的环境为硫酸盐矿物的产生和保存提供了良好条件,但红山矿床更为干旱少雨,导致两者硫酸盐的穆斯堡尔谱参数略有不同。     

A thermal centroid or a mass centroid?

This study reveals the physical backgrounds of the geometric centroid and the thermal centroid of the Western Pacific Warm Pool (WPWP) and points out their differences. The geometric centroid (actually a very close approximation to the mass centroid) anomaly of the surface WPWP correlates more closely with the Niño-3 region sea surface temperature anomaly (Niño-3 SSTA, an important indicator of El Niño/La Niña events) than the surface thermal centroid. Taking the WPWP depth (or heat storage) into account, the “real” mass or thermal centroid of the WPWP might correlate better with the El Niño/Southern Oscillation (ENSO) signals.     

“916”低聚糖抗卵磷脂氧化活性的研究

作者采用自由基引发氧化模型。通过测定卵磷脂氢过氧化物 ( PCOOH) ,研究了“916”低聚糖对卵磷脂 ( PC)氧化的抑制作用。实验结果表明 :( 1)“916”低聚糖具有良好的抗氧化活性 ;( 2 )各低聚糖在质量相同和含硫量大致相同的条件下 ,总体上分子量越小抗氧化活性越高。     

小振幅海洋内波的演变、破碎和所致混合

利用基于谱方法和MPI并行运算的数值模式SpectralModel,直接数值模拟了三维小振幅海洋内波的演变、破碎和所致湍流混合,指出导致其不稳定而破碎的为PSI(parametric subharmonic instability)机制;对于内波破碎所致的湍流混合过程,分析了跨等密度面扩散系数kρ、混合效率γ、浮力通量谱、动能谱以及势能谱等统计性质:内波破碎前,kρ和γ保持低值水平,浮力通量谱值为负,且集中在低波数段;内波破碎后,kρ和γ迅速增大,最大值分别约为0.9×103m2/s和0.18,浮力通量谱值在低波数段为负值,在高波数段为正值,这是因为层化湍流中势能向小尺度运动传递和动能向小尺度运动传递相比更为有效。在内波破碎、强湍流混合阶段,势能谱存在一谱段满足kz3律,P(kz)=0.2N2kz3。此外,与二维模拟结果相比较,导致内波不稳定而破碎的均为PSI机制,kρ、浮力通量谱、势能谱变化趋势大体一致;但三维数值实验中,内波破碎时间提前,湍流衰减加快;KE谱在高波数部分下降速度相对减小,更接近于kz3。     

藏南冈底斯岩基东段中新世中酸性高Sr/Y比岩浆岩的地球化学特征及成因探讨

藏南冈底斯带广泛发育中新世中酸性高Sr/Y比岩浆岩,对该类型岩石的成因研究可为藏南后碰撞岩浆活动提供良好的记录和约束。通过对冈底斯带东段中酸性岩浆岩进行锆石U-Pb年代学研究表明,该中酸性岩浆岩形成于16～18Ma,为中新世时期;全岩地球化学数据表明岩浆岩具有高SiO_2含量( 64%),高钾富钠,高Sr、低Y和高Sr/Y比,轻稀土富集、重稀土亏损且较平坦的特征,显示出埃达克质岩的地球化学亲缘性;与冈底斯带中段～14Ma埃达克质闪长玢岩脉相比,冈底斯带东段的中新世岩浆岩具有更高的K含量;锆石Hf同位素分析结果表明,中新世中酸性岩浆岩具有正的且变化较大的εHf(t)值(+1. 2～+14. 4);全岩(La/Yb)N值对中新世地壳厚度的估算结果为77～84km,处于壳幔边界处。综合上述数据分析表明,冈底斯带东段中新世中酸性高Sr/Y岩浆岩的成因为拉萨地块加厚下地壳(占主体的新生下地壳+少量古老地壳)的部分熔融,并在源区残留了石榴子石和角闪石,造成熔融的热量来源可能为拉萨地体岩石圈根部拆沉导致的热扰动。     

Heat flow and crustal thermal structure in the Late Archaean Closepet Granite batholith,south India

The Late Archaean Closepet Granite batholith in south India is exposed at different crustal levels grading from greenschist facies in the north through amphibolite and granulite facies in the south along a ∼400 km long segment in the Dharwar craton. Two areas, Pavagada and Magadi, located in the Main Mass of the batholith, best represent the granitoid of the greenschist and amphibolite facies crustal levels respectively. Heat flow estimates of 38 mW m⁻² from Pavagada and 25 mW m⁻² from Magadi have been obtained through measurements in deep (430 and 445 m) and carefully sited boreholes. Measurements made in four boreholes of opportunity in Pavagada area yield a mean heat flow of 39 ± 4 (s.d.) mW m⁻², which is in good agreement with the estimate from deep borehole. The study, therefore, demonstrates a clear-cut heat flow variation concomitant with the crustal levels exposed in the two areas. The mean heat production estimates for the greenschist facies and amphibolite facies layers constituting the Main Mass of the batholith are 2.9 and 1.8 μW m⁻³, respectively. The enhanced heat flow in the Pavagada area is consistent with the occurrence of a radioelement-enriched 2-km-thick greenschist facies layer granitoid overlying the granitoid of the amphibolite facies layer which is twice as thick as represented in the Magadi area. The crustal heat production models indicate similar mantle heat flow estimates in the range 12–14 mW m⁻², consistent with the other parts of the greenstone-granite-gneiss terrain of the Dharwar craton.     

厦门花岗岩残积土物理力学指标关联性定量表征初探

厦门地区花岗岩残积土的颗分试验表明其粒度呈“两头多,中间少”的特征,级配较独特。孔隙比等物性指标与压缩模量等设计中常用指标定量关联性不强,离散性大且没有明显规律。结合厦门地铁工程地质勘察资料,通过粒间状态参量、级配控制模式确定所研究土体的关键物理状态参量,分析该参量与岩土工程设计中常用指标之间的相关关系。结果表明,引入Thevanayagam提出的粒间孔隙比作为参变量,压缩模量随粒间孔隙比的增大而减小,建立了估计残积砾质黏性土、残积砂质黏性土压缩模量的经验公式。级配控制模式下的特征粒径比可以作为估计花岗岩残积土抗剪强度指标的关键参变量,黏聚力随特征粒径比的增大而增大,内摩擦角随特征粒径比的增大而减小,且线性相关性较好。文中建立的预测花岗岩残积土压缩模量、抗剪强度指标经验公式,可供厦门地区工程设计时参考。     

Composition and origin of the Çaldağ oxide nickel laterite,W. Turkey

The Çalda? nickel laterite deposit located in the Aegean region of W. Turkey contains a reserve of 33 million tons of Ni ore with an average grade of 1.14% Ni. The deposit is developed on an ophiolitic serpentinite body which was obducted onto Triassic dolomites in the Late Cretaceous. The deposit weathering profile is both laterally and vertically variable. A limonite zone, which is the main ore horizon, is located at the base of the profile. A hematite horizon is located above the limonite, which in the south of the deposit is capped by Eocene freshwater limestones and in the north by a siliceous horizon. The deposit is unusual in lacking a significant saprolite zone with little development of Ni-silicates. The boundary between the limonite zone and serpentinite below is sharp with a marked decrease in concentrations of MgO from 13 to 1 wt.% over a distance of 2 mm representing the ‘Mg discontinuity’. Ni concentrations within goethite, the main ore mineral, reach a maximum of ~3 wt.% near the base of the limonite zone. Silica concentrations are high throughout most of the laterite with up to 80 wt.% silica in the upper portion of some profiles. The combination of a serpentinite protolith and a high water table at Çalda?, in association with an aggressive weathering environment in a tropical climate, resulted in the formation of an oxide-dominated deposit. The precipitation of silica may coincide with a change in climate with silica precipitation linked to an increase in seasonality. Additional variations within profile morphology are attributed to transportation during and after laterite development as a result of faulting, pocket type laterite formation and slumping, each of which produces a contrasting set of textural and geochemical features.     

郯庐断裂带及邻区构造组合研究

地壳岩石圈中的各种构造要素是相互关联和相互依存的。本文从构造变形场的角度 ,分别分析和总结了郯庐断裂带及邻区伸展构造组合、挤缩构造组合、走滑构造组合和垂直构造组合的不同类型 ,分析了相同构造活动期不同部位构造组合的并列和干涉 ,以及不同构造活动期构造组合的叠加复合。对构造组合的分析和归并 ,实现了大中小型构造的衔接 ,对油气构造的成藏控制机制分析及油气资源的预测和评价具有重要的指导意义。     

Observations of the North Equatorial Current,Mindanao Current,and Kuroshio current system during the 2006/07 El Niño and 2007/08 La Niña

Two onboard observation campaigns were carried out in the western boundary region of the Philippine Sea in December 2006 and January 2008 during the 2006/07 El Niño and the 2007/08 La Niña to observe the North Equatorial Current (NEC), Mindanao Current (MC), and Kuroshio current system. The NEC and MC measured in late 2006 under El Niño conditions were stronger than those measured during early 2008 under La Niña conditions. The opposite was true for the current speed of the Kuroshio, which was stronger in early 2008 than in late 2006. The increase in dynamic height around 8°N, 130°E from December 2006 to January 2008 resulted in a weakening of the NEC and MC. Local wind variability in this region did not appear to contribute to changes in the current system.