青岗坪金矿区折离断层系统的控矿作用

通过对青岗坪金矿区内发育的拆离断层系统的具体分析，揭示了其产生，发展的过程，对由其控制的几类金矿脉的形成机制进行了合理的探讨，并对不同的成矿阶段进行了划分。     

一种新类型铜矿床的地球化学特征及其热水沉积成因

对兰坪－思茅沉积盆地几个代表性脉状铜矿床的研究发展，矿石构造以角砾状为主；金属矿物组合中出现较多的黝铜矿系列矿物（Ｃｕ１２Ｓｂ４Ｓ１３－Ｃｕ１２Ａｓ４Ｓ１３），约占金属矿物总量的５０％以上，部分矿石达８０％以上，其中尤以砷黝铜矿占优势；矿床的元素组合以Ｃｕ－Ａｓ－Ｓｂ－Ａｇ－Ｚｎ－（Ａｕ）－（Ｈｇ）－（Ｃｏ）－（Ｇａ）为特征；脉石矿物的稀土元素表现出特异的富中组稀土（Ｓｍ－Ｈｏ）、弱或无铕异常的曲     

The Nucleus Deposit: Superposed Au–Ag–Bi–Cu Mineralization Systems at Freegold Mountain,Yukon, Canada

In this paper we present titanite U–Pb (both single crystal CA ID‐TIMS and in situ LA ICP‐MS) data, coupled with ore and gangue mineralogy and geochemical (both lithogeochemistry and microanalysis) data from the Nucleus Au–Ag–Bi–Cu deposit, in the Yukon (Canada) portion of the Tintina Au province. Arsenic‐bearing Au–Ag–Bi–Cu mineralization at Nucleus consists of two distinct styles of mineralization including: (i) reduced Au skarn and sulfide replacement; and (ii) a relatively shallow‐emplaced (as supported by textures and temperature of formation), vein‐controlled mineralization occurring mainly as veins and veinlets of various shapes (sheeted, single, stockworks, and crustiform), breccias, and disseminations. Whereas Au, Bi, and Cu mineralization from skarn is associated with hydrous retrograde alteration phases (actinolite, ferro‐actinolite, hastingsite, cannilloite, and hornblende), numerous alteration types are associated with the vein‐controlled style of mineralization and these include: biotite, phyllic, argillic, propylitic, carbonate, and quartz (silicification) alterations. The mineralization–alteration processes took place over a wide temperature range that is bracketed between 340 and 568°C, as indicated by chlorite and arsenopyrite geothermometers. The Au‐rich Nucleus deposit is characterized by anomalously high content of As and Bi (as much as 1 %), and whereas Au moderately correlates with Bi (r = 0.40) in the skarn mineralization style (where native Au is spatially associated with native Bi and Bi‐bearing sulfides), the two elements correlate poorly (r = 0.14) in the vein‐controlled type, in which native Bi‐ and Bi‐sulfide‐bearing veins are locally observed. Sphalerite from the vein‐controlled mineralized type is Fe‐rich (9.92–10.54 mol % FeS) indicative of low sulfidation conditions, as well as high temperature, with the latter further supported by arsenopyrite geothermometry (up to 491°C), low Ag content (3–7 wt.%) in Au, and the high gold fineness (926–964). Whereas molybdenite Re–Os ages from quartz‐molybdenite veins range from 75.8 to 76.2 ± 0.3 Ma, titanite from the skarn type mineralization recorded CA ID‐TIMS and LA ICP‐MS U–Pb ages of 182.6 ± 2.4 Ma and 191.0 ± 1.5 Ma, respectively, thus precluding any genetic link between the two spatially associated styles of mineralization from the Nucleus deposit area. The Au–Ag–Bi–Cu Nucleus deposit is therefore regarded as a superposed system in which two mineralization types, without any petrogenetic relationship, overlapped, possibly with remobilization of early‐formed mineralization.     

云南普朗斑岩铜矿床热液蚀变及脉体系统研究

云南普朗超大型斑岩铜矿床位于西南三江成矿带中段,形成于岛弧构造环境,是印支期甘孜-理塘洋壳向西俯冲于格咱-中甸微陆块之下,并引发大规模岩浆-成矿作用的结果。本文通过对矿区围岩蚀变及脉体系统的调查和大量的镜下薄片鉴定研究,总结首采区与外围的蚀变分带及脉体特征。结果表明,首采区的围岩蚀变从岩体由内向外,依次为钾硅酸盐化带-绢英岩化带-青磐岩化带-角岩化带,泥化和碳酸盐化多叠加于其它蚀变带之上,不形成独立蚀变带,铜矿化主要发育于钾硅酸盐化带中,以浸染状矿化为主,含矿岩体为石英二长斑岩。北部及东部外围的钾硅酸盐化带缺失或微弱,主要发育绢英岩化带-青磐岩化带-角岩化带-碳酸盐化带,铜矿化多发育于绢英岩化带中,以脉状矿化为主,含矿岩体为石英二长斑岩及闪长玢岩。首采区与外围的脉体系统具多期次-多类型特征,在A、B、D三大类型脉中,前二者对成矿的贡献大。矿区蚀变特征总体与"二长岩"模式相符合,并与国内西藏玉龙、驱龙、多龙及多不杂等斑岩型铜矿床相似。     

三江中段铜多金属矿床流体成矿作用:微量元素地球化学证据

研究区属"三江成矿带"中段,包含三个不同的地质构造单元,由西向东依次为金沙江混杂岩带、中咱地块、义敦岛弧带。本文通过对这三个构造单元中代表性铜多金属矿床中热液石英脉进行系统的采样和微量稀土元素分析,讨论了各构造单元中石英脉的微量及稀土元素地球化学特征及分布模式,在此基础上结合研究区的地质背景及演化,进一步讨论石英脉中微量元素的指示意义。结果表明:1)研究区石英脉中Cu、Zn等成矿元素与亲岩浆元素呈较好正相关,指示成矿与岩浆活动的联系,微量元素地球化学特征指示中咱地块成矿流体与岩浆活动的联系较为密切;2)中咱地块石英脉稀土元素地球化学特征与义敦岛弧带和金沙江混杂岩带成矿流体差异较大,中咱地块流体稀土元素接近于地幔的稀土组成特征,稀土元素配分曲线为近于水平的平缓曲线,稀土元素特征参数表明形成于相对还原的环境,反映出深部来源很可能是中咱地块成矿流体的主要物质来源;3)石英微量元素地球化学特征的研究为本区区域构造演化提供了佐证,金沙江混杂岩带和义敦岛弧带的成矿流体特征较为相似,而在中咱地块与扬子陆块夹持间形成的义敦岛弧带成矿流体与中咱地块存在较大的元素地球化学差异。本文通过对石英的微量元素、稀土元素地球化学特征的研究为该区的区域成矿特征、热液流体成因和构造演化提供了证据,并对西南三江地区的找矿理论提出了建议。     

吉南地区晚震旦世震积岩特征

在吉南地区晚震旦世地层序列中,普遍发育有一套地震事件沉积物,其在垂向上由振动注伦泥昌碳酸盐脉灰岩,卷曲变形灰岩,阶梯状断层,海啸颗粒灰岩,津浪丘状交错层灰岩及钙屑浊积岩组成。     

江苏镇江谏壁岩体特征与钼(钨)矿床类型

谏壁钼(钨)矿床是产于下扬子地台中的一类斑岩型矿床。在大陆边缘活动带中，陆壳碰撞、俯冲，形成了壳幔混源型中酸性、钙碱性杂岩体，为中—浅成相。岩石的演化、分异于岩浆的晚期产生了各类中酸性斑岩脉体，沿主岩体的碎裂岩化带产出。区内成矿物质主要来源于岩浆，可能有部分的围岩有益组分的加入。成矿温度、压力为中—低温和低压。矿化作用主要为热液充填作用，与石英脉带紧密相关。矿石类型为细脉状、网脉状、细脉浸染状等。矿体围岩蚀变不具有“环带模式”。因此，矿床属斑岩—石英脉型热液充填—交代钼(钨)矿床。与斑岩型(铜)矿床相比仍有一定的差异，而与钨、钼一类矿床相近。     

海洋土曲霉C23-3代谢产物epi-aszonalenin A对内皮细胞的活性机制

【目的】探究海洋土霉菌代谢产物epi-aszonalenin A(EAA)对氧化型低密度脂蛋白(ox-LDL)诱导HUVEC人脐静脉内皮细胞的动脉粥样硬化斑块内血管新生的作用。【方法】用CCK法检测细胞活力,DCFH-DA法测定活性氧(ROS)的含量,划痕实验检测细胞迁移能力,血管生成实验检测细胞成管能力,酶联免疫吸附法ELISA试剂盒检测LOX-1和VEGF蛋白表达情况,蛋白免疫印迹法检测MAPK通路、细胞间黏附分子-1(ICAM-1)、血管细胞黏附分子-1(VCAM-1)的蛋白的表达情况,分子对接模拟EAA与LOX-1蛋白的相互作用。【结果】CCK法证明EAA对HUVEC细胞无明显毒性作用(P>0.05);与空白组相比,EAA对HUVEC细胞的迁移和血管生成起到显著抑制作用(P<0.001);与对照组相比,随着实验组EAA浓度增加,细胞内ROS含量显著减少(P<0.001),LOX-1、VEGF、MAPK通路蛋白p38、JNK、ERK的磷酸化和ICAM-1、VCAM-1的表达也显著降低(P<0.001);此外EAA能与LOX-1形成稳定的相互作用。【结论】EAA能清除ROS,抑制HUVEC细胞炎性因子的表达和血管生成。     

Albany K-Feldspar: A New Pb Isotope Reference Material

Lead isotopes are a powerful and versatile tool to elucidate fundamental geological problems related to the formation and evolution of continental crust. K-feldspar is a popular target for Pb isotope measurement as it is prevalent in many rock types and tends to capture the initial Pb isotope composition of its parental magma. We present data for a new Pb isotope reference material: Albany K-feldspar; as well as updated data for Shap K-feldspar. Results of Pb double-spike TIMS for Albany K-feldspar are ²⁰⁶Pb/²⁰⁴Pb = 16.7872 ± 0.0062, ²⁰⁷Pb/²⁰⁴Pb = 15.5640 ± 0.0056, and ²⁰⁸Pb/²⁰⁴Pb = 36.6600 ± 0.0168 (2s). TIMS measurement results for Shap K-feldspar indicate two isotopically distinct Pb populations. LA-MC-ICP-MS, with a spatial resolution as high as 15 μm, indicates a homogeneous Pb isotopic composition in Albany K-feldspar. In accord with previous studies, our results show that scatter in the measured Pb isotope ratios, related to the low natural isotopic abundance of ²⁰⁴Pb, along with the effect of isobaric ²⁰⁴Hg-²⁰⁴Pb interference, increases at lower count rates. However, the mean Pb isotope ratios measured via LA-MC-ICP-MS using a range of spot sizes are in excellent agreement with TIMS results thus highlighting the feasibility of Pb isotope determination via LA-MC-ICP-MS to access geological information preserved in small crystals, including mineral inclusions.     

湘东北幕阜山地区中生代构造—岩浆特征及对稀有金属伟晶岩的控制

幕阜山地区发育燕山期大型花岗岩体,形成了大量花岗伟晶岩脉及相关稀有金属矿床或矿化体。尽管前人对该地区花岗岩、伟晶岩和稀有金属矿床的地质地球化学特征、形成时代、空间展布和演化过程等进行了系统研究并取得大量成果,但地质构造对花岗岩和稀有金属伟晶岩的控制作用尚缺乏研究。鉴此,本文通过跨幕阜山岩体接触带的多个地质剖面调查,结合区域地质和矿产发育特征,对幕阜山地区中生代构造—岩浆演化过程以及构造对花岗岩体、伟晶岩脉和接触变质带的控制作用等进行了研究,形成以下主要认识：① 中生代—新生代早期,研究区自早至晚经历了早—中三叠世海相盆地、中三叠世后期—晚三叠世印支运动、晚三叠世晚期—中侏罗世早期类前陆盆地、中侏罗世晚期早燕山运动、晚侏罗世—早白垩世早期花岗质岩浆活动与成矿、早白垩世晚期—古近纪中期区域伸展与断陷盆地、古近纪中晚期NE向挤压等7个构造阶段。② 幕阜山岩体边界主要受NW向、NE向和NEE向等3组断裂控制,其构造机制实质为岩体区断块和岩体外断块对岩浆侵位过程的控制。③ 岩体侵位构造可定性划分为低侵位缓倾接触构造、低侵位陡倾接触构造、高侵位缓倾接触构造和高侵位陡倾接触构造等4类,其中低侵位缓倾接触构造对花岗伟晶岩的形成最为有利。④ 控制伟晶岩脉（体）的构造包括层面或层间剪切面、逆断裂、岩体接触带等主导性控岩构造,以及走滑剪切破裂、膝折面等限制性控岩构造。层间剪切面主要形成于武陵运动,EW向和NWW向逆断裂、NWW向膝折面、NNE向左行剪切破裂、NNW向右行剪切破裂等形成于印支运动SN向挤压,NWW向右行剪切破裂形成于早燕山运动NWW向挤压;仁里地区构造的走向为叠加后期顺时针旋转后的结果。⑤ 受岩体接触带和不同类型与规模的面状构造控制,仁里地区自北而南,围岩中伟晶岩脉的规模自大变小、岩脉产状由简单变复杂,主要成矿元素由Nb—Ta Nb—Ta—Li—Cs变化。