辽北地区钾长石矿地质特征及开发应用方向

以铁岭县湾龙背地区的钾长石矿为例,研究了辽北地区伟晶岩型钾长石矿的分异相带特点及空间分布规律。指出具新太古代壳源岩浆成因的钾长石分异相带明显,可分为内中外三个相带,其中内部相带的块体状钾长石、中间相带的团块状具文象结构的钾长石质量好,并在对国内的钾长石的市场潜力分析的基础上,指明了辽北地区钾长石矿的开发利用方向。     

胶东英格庄金矿床地质地球化学特征

英格庄金矿床是胶东牟平-乳山金矿成矿带重要的石英脉型金矿床之一,其产出和分布严格受NNE向断裂控制,围岩以古老变质岩和昆嵛山花岗岩为主,金矿物主要以晶隙金形式赋存于黄铁矿-脉石晶体之间。通过成矿流体包裹体地球化学研究可知:均一温度变化有3个峰值(155℃～165℃、205℃～215℃和245℃～265℃);该矿床包裹体盐度w(NaCl)较低(17.17(),在1.05(～17.17(之间变化,应属于低盐度流体;据其成矿压力21.3～58.8MPa,进一步求得的该矿床主要成矿深度为0.83～2.31km,为中浅成矿床;依据包裹体成分测试结果可知,矿床流体属K+-Na+-SO24-Cl-型。氢氧同位素显示其成矿流体主要来源于岩浆水和变质水,并有一定的大气降水混入。     

东准噶尔蒙西斑岩铜钼矿床脉体特征及其形成机制

蒙西斑岩铜钼矿床位于东准噶尔伊吾县琼河坝花岗岩北侧,以发育细脉、网脉状矿化为特征。脉体类型多样,包括石英脉、石英硫化物脉和硫化物脉等。根据脉体力学成因机制,其又可划分为水压破裂充填脉和构造破裂充填脉。构造破裂充填脉体按破裂形成的位错特征有正断与逆断两种。地表石英脉产状陡立,明显受断裂控制。脉体体积分数统计结果显示流体富集区呈向北缓倾的带状分布于深100～400m范围内,并与矿化富集带有较好的对应关系。脉体富集带内,脉体以共轭形式存在,一组为倾角较小的逆断破裂充填脉,另一组为倾角较大的正断破裂充填脉,他们可能为缓倾逆冲剪切带的次级破裂与充填脉,即富矿带内脉体是沿矿区低角度逆冲断裂次级破裂面充填的。矿区地表及深部(400m以下)脉体以陡立为主,矿化较弱。矿区流体的运移具先沿水压直立破裂往上运移,进入剪切带后沿剪切带次级破裂侧向和向上运移,并在剪切带中富集成矿。低温矿物组合脉体穿切高温矿物组合脉体的特征说明脉体形成过程矿区处于隆升构造环境,这对斑岩铜矿成矿有利。     

黔东南与黔西南浊积岩中两种不同类型金矿的比较

黔西南和黔东南是贵州的两个主要产金地区,大部分金矿都产于浊积岩中。但黔西南的金矿主要是含金蚀变岩型（或称卡林型、微细浸染型）,以不可见金为主;黔东南的金矿却是含金石英脉型,以明金为主。这两种金矿都产在造山带,赋矿围岩是浊积岩,区内岩浆侵入作用不显著,成矿受背斜与断裂控制,成矿温度不高,矿石物质成分基本一致。研究表明,产生不同类型矿化的原因主要在于：黔东南地区的容矿岩石是浅变质的硅质碎屑岩,碳酸盐矿物很少;而黔西南地区是未变质的富钙硅质碎屑岩,碳酸盐矿物多。前者形成石英脉型金矿床,后者形成蚀变岩型金矿床。     

135~130 Ma: 大别山第二次“去根”时间？

大别杂岩主要由早白垩世侵入岩和三叠纪变质岩组成。它的四周是四条区域性韧性剪切带:郯城—庐江断裂,商城—麻城断裂,襄樊—广济断裂和晓天—磨子潭断裂。其中,晓天—磨子潭断裂和襄樊—广济断裂在早白垩世具有相反的走滑剪切方向:北侧的边界断裂(晓天—磨子潭断裂)是一个左行剪切断裂,而南侧的边界断裂(襄樊—广济断裂)是一个右行剪切断裂。在大别杂岩内部,早白垩世低角度剪切面理的倾伏向以SE向或NW向为主。这些晚期剪切面理上的拉伸线理的倾伏向同样为SE或NW向。大别杂岩总体具有朝SE向挤出和顶部相对朝NW向剪切的构造特征。这些表明晚中生代是该杂岩演化的重要阶段。该杂岩的边界断裂和内部构造特征指示其晚期抬升是沿造山带方向(SE—NW)以低角度方式进行的。这一过程直接导致高压-超高压变质岩和同构造岩浆岩被抬升至近地表。同时,年代学研究表明:大别杂岩(扬子板块东北缘地壳)在晚侏罗世—早白垩世经历大规模混合岩化的时间为145~135 Ma,同造山岩浆作用的时间为145~135 Ma,后造山火山-岩浆活动的时间为135~120 Ma。因此,该杂岩中三叠纪高压-超高压变质岩所记录的早白垩世抬升过程不是印支事件的后续,而是燕山期陆内造山及随后发生的伸展过程有关。尽管这一陆内造山事件的起始时间至今仍不确定,但大别山未变形岩体(130~120 Ma)的年代学研究结果和我们新测得的同构造伟晶岩脉的锆石U-Pb年龄(130 Ma)为早白垩地壳变形提供了良好的上限制约。这样,大别山经历了三叠纪碰撞造山和伸展,晚侏罗世—早白垩世陆内造山-伸展二次过程。     

广西苍梧社垌石英脉型钨钼多金属矿床流体演化及来源示踪

广西苍梧社垌矿床是大瑶山隆起南侧新发现的一个大型斑岩-矽卡岩-石英脉型钨钼多金属矿床。本文重点对其中的石英脉型矿床进行了研究,依据脉体穿插关系及矿物共生组合将成矿过程划分为I石英-黄铁矿阶段、II石英-白钨矿-辉钼矿阶段、III石英-多金属硫化物阶段以及IV石英-方解石-萤石阶段,其中II和III阶段为主成矿阶段。从早到晚,均一温度逐渐下降(第一阶段550℃→370℃,第二阶段370℃→330℃,第三阶段330℃→210℃,第四阶段190℃→150℃),流体密度逐渐上升(0.61g/cm3→0.72g/cm3→0.82g/cm3→0.94g/cm3),盐度先升后降(第一阶段5.86%～8.55%NaCleqv,第二阶段4.49%～43%NaCleqv,第三阶段0.53%～46.37%NaCleqv,第四阶段0%～12.85%NaCleqv)。激光拉曼成分分析显示,社垌石英脉型矿床的成矿流体属于H2O-NaCl体系,但是该体系的流体成分在成矿前后发生了较大的变化,反映第I阶段以氧化环境为主,(II、III、)IV阶段则为还原环境。氢氧同位素研究显示成矿流体来自于岩浆水,后期大气降水的加入导致矿质发生沉淀。此外金属硫化物的δ34S组成(-3.8‰～+1.7‰)平均为-0.46‰,接近于零值,也表明为岩浆来源。引起矿质沉淀的主要原因是流体混合导致的温度下降等环境条件的改变。总体而言,社垌石英脉型钨钼多金属矿床的成矿流体主要来自岩浆热液,为中高温、中低盐度、低密度的NaCl-H2O流体体系,钨钼等多金属成矿与区内加里东期岩浆作用密切相关。     

榴辉岩相峰期流体活动：来自东昆仑榴辉岩石英脉的证据

本文通过对东昆仑温泉地区榴辉岩中石英脉的锆石U-Pb定年和Lu-Hf同位素的综合研究,为榴辉岩相峰期变质阶段的流体活动提供了一定的证据。石英脉中的锆石晶型较好,具有振荡环带或弱分带,排除了从寄主榴辉岩中捕获锆石的可能性。石英脉和寄主榴辉岩中锆石U-Pb年龄的加权平均值分别为450±2Ma和451±2Ma,说明石英脉中锆石的形成年龄与榴辉岩相的峰期变质阶段一致。两种锆石Hf同位素组成的相似性说明形成石英脉的流体/熔体为内部来源,推测可能为榴辉岩中石英发生溶解以及绿辉石和石榴石分子结构中羟基的出溶作用形成。锆石较低的U、Th含量以及Th/U比值说明石英脉更可能是流体活动形成而非熔体。     

新疆阿尔泰伟晶岩中绿柱石拉曼光谱特征研究——以可可托海3号脉与阿祖拜328、528号脉为例

本文对新疆可可托海3号伟晶岩脉中的绿柱石与阿祖拜328、528号伟晶岩脉中的宝石级绿柱石开展拉曼光谱对比研究,获得以下主要结论: ① 阿祖拜328、528号伟晶岩脉中宝石级绿柱石以富含Ⅰ型H₂O为特征,可可托海3号脉早期形成的结构带(Ⅰ-Ⅱ带)中绿柱石以及相对富H₂O岩浆体系中形成的绿柱石(Ⅳ带)以存在Ⅰ型H₂O为主,演化程度相对较高,岩浆体系中结晶的结构带(Ⅲ带)以及岩浆-热液过渡阶段体系形成的结构带(Ⅴ带)中绿柱石以含有Ⅱ型H₂O为特征; ② 在可可托海3号脉以及阿祖拜328号、528号脉绿柱石矿物中均发现冰晶石矿物包体,指示伟晶岩岩浆含有较高的F含量;③ 绿柱石通道水类型(Ⅰ型H₂O、Ⅱ型H₂O)及相对比例,是伟晶岩岩浆-热液演化过程及其形成条件的响应,在相对氧化的岩浆体系中主要形成绿柱石矿物,而相对还原的富H₂O岩浆体系更有利于海蓝宝石形成.     

P–T–t evidence for mechanisms of vertical tectonic motion in a contractional orogen: north-western US and Canadian Cordillera

The >1800 km long Coast Mountains–North Cascades orogen of the Canadian Cordillera and north-western US developed as a continental magmatic arc. Metamorphic rocks in the orogen contain widespread evidence for burial of supracrustal rocks to depths of c. 40 km, followed by nearly isothermal decompression to depths of <10 km. Near many shallowly-emplaced, mid-Cretaceous plutons, low-pressure contact metamorphic effects were overprinted by high-pressure regional metamorphic minerals and textures, as evidenced by kyanite±staurolite pseudomorphs after andalusite in metapelitic rocks. Therefore, near-pluton rocks record the loading history of the orogen. Metapelitic rocks not associated with plutons only preserve evidence for high-pressure conditions and/or high-temperature decompression, as indicated, for example, by sillimanite and cordierite after kyanite and garnet, respectively. Petrological evidence for burial and decompression is therefore recorded in different rocks. Various regions of the orogen differ in timing of metamorphism, the overall shape of P–T paths and the relative timing and regional extent of the high-pressure event, but most of these data and observations are consistent with thrusting and/or pure shear thickening as primary loading mechanisms throughout the orogen, as opposed to magma-dominated loading. This interpretation is further supported by comparison with thermal models, which demonstrate that the P–T paths are consistent with simultaneous thrusting and folding at a high initial geothermal gradient (35–40 °C km^?1) in much of the orogen. A high geothermal gradient supports tectonic models invoking intra-arc contraction and suggests that magmatism played an important role in regional temperature-time paths. This tectonic-thermal history may be typical of other contractional orogens and illustrates the importance of large vertical displacement of crust in magmatic arcs.     

Application of K-feldspar–jadeite–quartz barometry to eclogite facies metagranites and metapelites in the Sesia Lanzo Zone (Western Alps, Italy)*

The eclogite facies assemblage K-feldspar–jadeite–quartz in metagranites and metapelites from the Sesia-Lanzo Zone (Western Alps, Italy) records the equilibration pressure by dilution of the reaction jadeite+quartz=albite. The metapelites show partial transformation from a pre-Alpine assemblage of garnet (Alm₆₃Prp₂₆Grs₁₀)–K-feldspar–plagioclase–biotite±sillimanite to the Eo-Alpine high-pressure assemblage garnet (Alm₅₀Prp₁₄Grs₃₅)–jadeite (Jd_80–97Di_0–4Hd_0–8Acm_0–7)–zoisite–phengite. Plagioclase is replaced by jadeite–zoisite–kyanite–K-feldspar–quartz, and biotite is replaced by garnet–phengite or omphacite–kyanite–phengite. Equilibrium was attained only in local domains in the metapelites and therefore the K-feldspar–jadeite–quartz (KJQ) barometer was applied only to the plagioclase pseudomorphs and K-feldspar domains. The albite content of K-feldspar ranges from 4 to 11 mol% in less equilibrated assemblages from Val Savenca and from 4 to 7 mol% in the partially equilibrated samples from Monte Mucrone and the equilibrated samples from Montestrutto and Tavagnasco. Thermodynamic calculations on the stability of the assemblage K-feldspar–jadeite–quartz using available mixing data for K-feldspar and pyroxene indicate pressures of 15–21 kbar (±1.6–1.9 kbar) at 550±50 °C. This barometer yields direct pressure estimates in high-pressure rocks where pressures are seldom otherwise fixed, although it is sensitive to analytical precision and the choice of thermodynamic mixing model for K-feldspar. Moreover, the KJQ barometer is independent of the ratio PH2O/P_T. The inferred limiting a(H₂O) for the assemblage jadeite–kyanite in the metapelites from Val Savenca is low and varies from 0.2 to 0.6.