Assessment of erosion and settling properties of fine sediments stored in cobble bed rivers: the Arc and Isère alpine rivers before and after reservoir flushing

Cohesive sediment dynamics in mountainous rivers is poorly understood even though these rivers are the main providers of fine particles to the oceans. Complex interactions exist between the coarse matrix of cobble bed rivers and fine sediments. Given that fine sediment load in such environments can be very high due to intense natural rainfall or snowmelt events and to man‐induced reservoir or dam flushing, a better understanding of the deposition and sedimentation processes is needed in order to reduce ecohydrological downstream impacts. We tested a field‐based approach on the Arc and Isère alpine rivers combining measurements of erosion and settling properties of river bed deposits before and after a dam flushing, with the U‐GEMS (Gust Erosion Microcosm System) and SCAF (System Characterizing Aggregates and Flocs), respectively. These measurements highlight that critical shears, rates of erosion, settling velocities and propensity of particles to flocculate are highly variable in time and space. This is reflective of the heterogeneity of the hydrodynamic conditions during particle settling, local bed roughness, and nature and size of particles. Generally the deposits were found to be stable relative to what is measured in lowland rivers. It was, however, not possible to make a conclusive assessment of the extent to which the dynamics of deposits after reservoir flushing were different from those settled after natural events. The absence of any relationships between erosion and deposition variables, making it impossible to predict one from another, underlined the need to measure all of them to have a full assessment of the fine sediment dynamics and to obtain representative input variables for numerical models. While the SCAF was found to be effective, an alternative to the U‐GEMS device will have to be found for the erodibility assessment in cobble bed rivers, in order to make more rapid measurements at higher shears. Copyright © 2017 John Wiley & Sons, Ltd.     

SHRIMP U–Pb ages of detrital zircons from the Early Cretaceous Nakdong Formation,South East Korea: Timing of initiation of the Gyeongsang Basin and its provenance

To constrain the depositional age of the lowermost Nakdong Formation in the Early Cretaceous Gyeongsang Basin, SHRIMP U–Pb age determination was carried out on zircon separates. The U–Pb compositions of detrital zircons from the Nakdong Formation yield a wide range of ages from the Archean to the Cretaceous but show a marked contrast in age distribution according to the geographical locations within the basin. The provenance of the southern Nakdong Formation is dominantly the surrounding Yeongnam Massif, which is composed of Paleoproterozoic metamorphic rocks and Triassic to Jurassic plutonic rocks, whereas the central to northern Nakdong Formation records significant sediment derivation from the Okcheon Metamorphic Belt, which is distributed to the northwest, in addition to the contribution from the Yeongnam Massif. It is suggested that the maximum depositional age of the Nakdong Formation is ca 127 Ma, based on its youngest detrital zircon age population. The onset of its deposition at 127 Ma coincided with the tectonic inversion in East Asia from a compressional to an extensional geodynamic setting, probably due to the contemporaneous change in the drift direction of the Izanagi Plate and its subsequent oblique subduction.     

A ‘superoutburst’ in XTEJ1118+480

I propose that the properties of the two outbursts observed in the X‐ray transient XTEJ1118+480 in 2000 are akin to superoutbursts of SU UMa stars. In these systems a ‘normal’ outburst immediately precedes a 5–10 times longer (‘super’) outburst. The optical light curve of the outbursts of XTEJ1118+480 is remarkably similar to that seen in some SU UMa stars, such as UVPer and TLeo, where the precursor outburst is distinct from the superoutburst, but the time scales are a factor of ∼15 different. The first outburst of XTEJ1118+480 was relatively short (∼1 month) while the second outburst was ∼5 times longer. During the second outburst superhumps were seen, a feature characteristic for superoutbursts. The gap of about a month between the two outbursts is longer in X‐rays with respect to the optical, a feature not previously recognized for X‐ray transients. Also in SU UMa stars the precursor outburst becomes more distinct at shorter wavelengths. Finally, I show that the time of appearance of the superhumps in XTEJ1118+480 is consistent with the expected superhump growth time, if the superhump mechanism was triggered during the first outburst. I conclude that the similarity in outburst behaviour in the two types of systems provides further support that a common mechanism is at work to start the long (‘super’) outbursts.     

Spectroscopic Characterization of Organic Structures and Organic‐Inorganic Interactions in Paper Mill Sludge

The organic composition and organic‐inorganic interaction in paper mill sludge (PS) solvent extracts (hexane, ethyl acetate, acetone and ethanol) and humic fractions, humic acid (HA) and humin (HU) were studied by electron paramagnetic resonance spectroscopy (EPR), proton and carbon‐13 nuclear magnetic resonance spectroscopy (¹H NMR; ¹³C NMR), Fourier‐transformed infrared spectroscopy (FTIR), and ultraviolet‐visible spectroscopy (UV‐vis). The strategy of fractionating the PS, sequentially, with organic solvents of increasing polarity is a reliable analytical procedure for humic substance sample separation because it results in more purified fractions. FTIR, ¹H NMR and ¹³C NMR results showed that hexane extract consisted mainly of aliphatic hydrocarbon structures. Their contents in the extracts decreased as the polarity of the extracting solvent increased and the content of oxygen functional groups increased. Carboxylic and carboxylate functional groups were found in the acetone extract, and ester and ether functions were predominantly found in the ethanol extract. EPR spectra revealed some Fe³⁺ complexes with rhombic structure (g₁ = 4.3; g₂ = 9.0) in the humic fractions and in all solvent extracts, except hexane. Quasi‐octahedral Fe³⁺ complexes (g = 2.3; ΔH_pp ≤ 400 G) were found in the HU fraction and in the acetone extract. The organic free radical content in the HA fraction was higher than the non‐fractionated PS sample and HU fraction.     

Characterisation of Fulvic Acids and Glycyrrhizic Acid by Time‐of‐Flight Secondary Ion Mass Spectrometry

Fulvic acids of different origin, spray deposited on polished silicon after dissolution in high‐purity water without any additives, were analysed by time‐of‐flight secondary ion mass spectrometry (TOF‐SIMS) in combination with oblique 24...36 keV SF₅⁺ ion bombardment. The observed, highly reproducible mass spectra cover more than five orders of magnitude in dynamic range, without background subtraction. Apart from lines due to atomic ions and low‐mass ion fragments, the mass spectra exhibit broad maxima between m/z 200...350, mainly due to a beat‐like superposition of lines at every single mass number, up to at least m/z 400. In the negative ion spectra the beats have a spacing of m/z 14, corresponding to a CH₂‐unit. The high‐mass tails of the spectra extend well beyond m/z 5000, with similar slopes in the positive and the negative ion mass spectra. The negative spectra appear to be less affected by fragmentation products than the positive spectra. Fulvic acids (FAs) of different origin show distinctly different spectra, with mean masses ranging between m/z ≈ 450 and 580 (for a low‐mass cut‐off m/z 150). To further verify the ability of TOF‐SIMS to detect molecules and clusters with masses significantly above the maxima of the FA spectra, samples of glycyrrhizic acid (GA, as GA ammonium salt with molecular weight 840) were also analysed. Parent ions as well as multimers (GA)_n were observed as positive and negative ions, up to n = 4 (m/z 3320). The results are compared with spectra recently obtained by other mass spectrometric techniques.     

Sorption and Chemical Reactions of PAHs with Dissolved Humic Substances and Related Model Polymers

Sorption coefficients measured for PAHs on dissolved humic substances by SPME and FQT were found to be inevitably different and method‐dependent – SPME provides activity‐based and FQT concentration‐based sorption coefficients. Poly(acrylic acid) esters as well‐defined model polymers were used in sorption experiments, leading to the conclusion that short aliphatic chains are more effective in binding PAHs than aromatic moieties. FQT was inappropriate to measure sorption coefficients for the interaction of pyrene with poly(acrylic acid) esters but the experiments revealed a characteristic shift in the fluorescence spectrum. Using pyrene as a probe for the molecular environment in the sorbed state, the observed spectral shift indicated a highly hydrophobic microenvironment. The empirical relationships between lg K_DOC and lg K_OW were generalized on the basis of a modified Flory‐Huggins concept. Introducing only one sorbent‐specific parameter, the solubility parameter δ_DOM, the calculation of sorption coefficients became possible for a wide range of HOCs using fundamental data readily available from the literature. Long‐term experiments showed that reactive PAHs (such as acenaphthylene and 9‐methylanthracene) are able to react with HAs under strictly abiotic and anoxic conditions, whereas less reactive PAHs (such as naphthalene and dihydroanthracene) do not form bound residues. The HA reveals two functions in the interaction, behaving as a reaction partner and as a protecting ligand.     

Lagoon–tidal flat sedimentation in an epeiric sea: Proterozoic Bhander Group,Son Valley,India

The Bhander Group, the uppermost stratigraphic unit of the Proterozoic Vindhyan Supergroup in Son Valley, exhibits in its upper part a 550 m thick, muddy siliciclastic succession characterized by features indicative of deposition in a wave‐affected coastal, lagoon–tidal flat environment suffering repeated submergence and emergence. The basic architecture of the deposit is alternation of centimetre‐ to decimetre‐thick sheet‐like interbeds of coarser clastics (mainly sandstone) and decimetre‐thick mudstones. The coarser interlayers are dominated by a variety of ripple‐formed laminations. The preserved ripple forms on bed‐top surfaces and their internal lamination style suggest both oscillatory and combined flows for their formation. Interference, superimposed, ladder‐back and flat‐topped ripples are also common. Synsedimentary cracks, wrinkle marks, features resembling rain prints and adhesion structures occur in profusion on bed‐top surfaces. Salt pseudomorphs are also present at the bases of beds. The mudstone intervals represent suspension settlement and show partings with interfaces characterized by synsedimentary cracks. It is inferred that the sediments were deposited on a coastal plain characterized by a peritidal (supratidal–intertidal) flat and evaporative lagoon suffering repeated submergence and emergence due to storm‐induced coastal setup and setdown in addition to tidal fluctuations. The 550 m thick coastal flat succession is surprisingly devoid of any barrier bar deposits and also lacks shoreface and shelfal strata. The large areal extent of the coastal flat succession (c. 100,000 km²) and its great thickness indicate an extremely low‐gradient epeiric basin characterized by an extensive coastal flat sheltered from the deeper marine domain. It is inferred that the Bhander coastal flat was protected from the open sea by the Bundelkhand basement arch to the north of the Vindhyan basin, instead of barrier bars. Such a setting favoured accumulation of a high proportion of terrigenous mud in the coastal plain, in contrast to many described examples from the Proterozoic. Copyright © 2001 John Wiley & Sons, Ltd.