Mineral characteristics and their geological significance of black shales in southeastern Ordos Basin by X-ray diffraction analysis

X-ray diffraction analysis of black shale of Upper Triassic Member Chang 7 of the Yanchang Formation in southeastern Ordos Basin showed that black shales were deposited in brackish, strongly reducing, semi-deep-deep lacustrine facies, and mainly composed of quartz, feldspar, carbonate （dolomite）, clay minerals （illite and il- lite/smectite） and a certain amount of pyrite. The mineral composition characteristics of this set of black shales are similar to those of highly productive shale gas in North America, for example shallow burial, low clay mineral and abundant brittle mineral, so the strata are conducive to the development of cracks and fractures. Thus, this area is favorable for shale oil/gas exploration and development.     

胜利海上油田分队计量研究

通过γ射线穿透油、气、水混合物后的透射和散射计数,经理论模拟计算,实现对原油含水率在线计量分析,测量含水率范围为３％－１００％,精度在２％以内。在实际应用过程中,运行稳定,易于操作,特别是修正了由于原油中含气地含水率测量带来的误差,技术和性能指标均已契过以往各种含水测量仪,通过应用,实现了海洋石油开发公司采油一、二分公司和油气集输大队的分队计量,使生产管理水平整体上了一个新台阶。     

An experimental study on microscopic characteristics of gas-bearing sediments under different gas reservoir pressures

Gas-bearing sediments are widely distributed in five continents all over the world. Most of the gases exist in the soil skeleton in the form of discrete large bubbles. The existence of gas-phase may increase or decrease the strength of the soil skeleton. So far, bubbles’ structural morphology and evolution characteristics in soil skeleton lack research, and the influence of different gas reservoir pressures on bubbles are still unclear. The micro characteristics of bubbles in the same sediment sample were studied using an industrial CT scanning test system to solve these problems. Using the image processing software, the micro variation characteristics of gas-bearing sediments in gas reservoir pressure change are obtained. The results show that the number and volume of bubbles in different equivalent radius ranges will change regularly under different gas reservoir pressure. With the increase of gas reservoir pressure, the number and volume of tiny bubbles decrease. In contrast, the number and volume of large bubbles increase, and the gas content in different positions increases and occupies a dominant position, driving the reduction of pore water and soil skeleton movement.     

基于物理特征的平面流场拓扑简化算法

基于网格合并思想实现的平面流场拓扑简化,存在物理特征被忽略和并行实现困难的问题,难以满足远程可视化的要求。文中提出1种基于物理特征的平面流场拓扑简化算法。算法通过计算生成平面流场的物理特征参数图像,利用图像分割提取平面流场的特征区域达到流场简化的目的。实验结果表明,算法能从物理特征和宏观的角度出发快速、准确描述平面流场的拓扑结构,为平面流场可视化提供了1种新方法。     

Mineralogical characteristics of polymetallic sulfides from the Deyin-1 hydrothermal field near 15°S,southern Mid-Atlantic Ridge

A seafloor hydrothermal field, named Deyin-1 later, near 15°S southern Mid-Atlantic Ridge(SMAR) was newly found during the 22 nd cruise carried out by the China Ocean Mineral Resources Research Development Association(COMRA). Sulfide samples were collected at three stations from the hydrothermal field during the26 th cruise in 2012. In this paper, mineralogical characteristics of the sulfides were analyzed with optical microscope, X-ray diffractometer, scanning electron microscope and electron microprobe to study the crystallization sequence of minerals and the process of hydrothermal mineralization. According to the difference of the ore-forming metal elements, the sulfide samples can be divided into three types:(1) the Ferich sulfide, which contains mainly pyrite and chalcopyrite;(2) the Fe-Cu-rich sulfide consisting predominantly of pyrite, chalcopyrite and isocubanite, with lesser amount of sphalerite, marmatite and pyrrhotine; and(3) the Fe-Zn-rich sulfide dominated by pyrite, sphalerite and marmatite, with variable amounts of chalcopyrite, isocubanite, pyrrhotine, marcasite, galena and gratonite. Mineral precipitations in these sulfides are in the sequence of chalcopyrite(isocubanite and possible coarse pyrite), fine pyrite,sphalerite(marmatite), galena, gratonite and then the minerals out of the dissolution. Two morphologically distinct generations(Py-I and Py-II) of pyrite are identified in each of the samples; inclusions of marmatite tend to exist in the coarse pyrite crystals(Py-I). Sphalerite in the Fe-Zn-rich sulfide is characterized by a"chalcopyrite disease" phenomenon. Mineral paragenetic relationships and a wide range of chemical compositions suggest that the environment of hydrothermal mineralization was largely changing. By comparison, the Fe-rich sulfide was formed in a relatively stable environment with a high temperature, but the conditions for the formation of the Fe-Cu-rich sulfide were variable. The Fe-Zn-rich sulfide was precipitated during the hydrothermal venting at relatively low temperature.     

双量子阱结构OLED效率和电流的磁效应

通过结构为ITO/NPB(60 nm)/ Alq₃ ∶1 wt% rubrene(20 nm)/ Alq₃(3 nm)/ Alq₃ ∶1 wt% rubrene(20 nm)/ Alq₃(20 nm)/LiF/Al的双量子阱的黄色有机电致发光器件,研究了不同磁场强度下的发光效率和电流变化特性. 研究结果表明该器件的电流是随着磁场强度的增加而单调下降的,显示了器件的电阻是随着磁场强度的增加而增加的. 同时也得到了该结构有     

基于剖分的中尺度海洋温度场三维显示技术

针对网格化和数据量庞大的中尺度海洋标量场数据在其三维可视化中表现出来的构造效率较低和表达连续性效果较差的问题,以剖分重构为核心思想,采用三线性插值算法对数据进行加密处理,基于不同角度平面对温度场进行剖分和色彩映射,最后采用OpenSceneGraph图像渲染引擎的颜色、光照、透明度和回调等渲染技术展现更为真实的、科学的动态三维温度场,提供一种简洁、高效、科学的中尺度海洋温度场表达方法。     

Lacustrine basin unconventional resource plays: Key differences

There has been a revival in hydrocarbon source rock characterization and development associated with growing interest in unconventional resources, where these fine-grained organic-rich rocks act as both source and reservoir. To-date, the exploration focus on shale reservoirs has been largely on marine systems. Lacustrine source rocks for conventional resources are geographically important, dominating regions such as China, Indonesia, and Brazil's resource-base. However, they have been generally untested for unconventional resources.There are a number of key differences in the nature of these hydrocarbon systems that should be considered when assessing whether lacustrine systems may represent future unconventional opportunities in areas where the conventional resource-base is dominated by lacustrine-sourced oil. Among the key differences between these depositional systems is the greater sensitivity to high frequency climatic variability within lacustrine systems. Lacustrine systems are highly sensitive to changes in the balance between precipitation and evaporation, which may lead to rapid changes in lake level, potentially exceeding 600 m. These changes in depositional conditions are geologically rapid and may occur over periods of thousands of years. Such changes can reduce the areal extent of potentially thick source rock intervals to only those portions of a basin where a permanent deep lake was present. Thus the core unconventional target area may be geographically limited compared with their marine counterpart. Although potentially areally limited, a review of many lacustrine source rocks suggests that their thicknesses are often significantly greater than marine source rocks. An examination of the more distal portions of lacustrine systems, where better source rock potential is present reveals that there is generally limited connectivity between source and conventional reservoir. In these settings, such as the Wind River basin (Waltman Shale), the hydrocarbons remain trapped within the shales, potentially leading to over-pressured hydrocarbon charged systems. Such conditions suggest that although areally limited, viable unconventional targets may exist, if suitable reservoir conditions are present. Finally, the character of the oils produced is different in these settings, with lacustrine oils being waxy and displaying different hydrocarbon generation and cracking kinetics. High wax oils display distinct flow characteristics, being more viscous, and may offer different production challenges than their non-waxy marine equivalents. Additionally, differences in their cracking kinetics may indicate that the timing of gas generation for shale gas plays may differ significantly from marine systems.     

南海神狐水合物钻探区不同形态流体地震反射特征与水合物产出的关系

天然气水合物的分布在很大程度上受到含气流体运移的影响。南海北部陆坡区,尤其是珠江口盆地的白云凹陷,普遍存在流体渗漏的现象,暗示了水合物赋存的良好前景。神狐海域水合物钻探区内的高分辨率地震资料显示,区域内发育大量流体运移通道,在地震剖面上表现为不同形态的地震反射模糊带,根据其形态特征,可以划分为花冠状和穹顶状两大类模糊反射带。模糊反射带的存在意味着研究区内具有良好的含气流体运移条件,能够为甲烷气体的垂向运移提供通道。神狐海域水合物的钻探结果表明,水合物的分布与模糊反射带的分布范围具有良好的空间匹配关系,其中,花冠状地震反射模糊带侧翼部与中尺度正断层相连,促进了含气流体的侧向运移,顶部与可能的微裂隙相通,气体可向上运移至水合物稳定带,形成了水合物藏;而穹顶状地震反射模糊带顶部则通过疑似流体通道与海底沟通,这种结构极易形成气体逃逸而无法形成水合物。因此,不同形态特征的模糊反射带可能对水合物的分布具有一定的指示意义。     

上扬子盆地西南缘上组合气藏成藏过程分析

通过对代表上扬子盆地西南缘上组合气藏特征的平落坝、白马庙和观音寺3个典型气藏进行解剖,明确了中侏罗统沙溪庙组天然气分布特征。结合输导体系、流体包裹体成藏期次和构造演化研究成果,分析了气藏成藏过程,总结其成藏模式,以期为有利勘探目标区的选择及评价提供地质依据。上扬子盆地西南缘沙溪庙组气藏以构造-岩性和岩性气藏为主,天然气主要分布在沙溪庙组Ⅰ、Ⅱ、Ⅲ段,主要聚集于构造高点。油气成藏时间集中在93～72 Ma,发生过至少2幕油气充注。燕山运动是气藏形成的主要时期,其形成的断层是沟通气源的主要通道;喜山运动是气藏天然气调整的主要时期,喜山期逆冲断层的活动及构造高点的迁移是天然气调整的主要原因。不同构造区域成藏具有差异性：西部褶皱带断-砂匹配、构造、砂体物性是主要控藏因素,构造高点、断层封闭性控制其含气丰度;东部斜坡带断-砂匹配、构造、封闭断层是主要控藏因素,构造高点、砂体物性控制其含气丰度。