中亚陆间区南带上古生界构造和油气远景(代序)

安加拉-阿尔丹和华北-塔里木两大克拉通之间地壳相对活动性的地区,地质界多称为中亚陆间区,其南带大部分在中国境内。近年来,中国开始把其上古生界作为油气新区、新领域。多数人认为,其在晚古生代已形成过渡型地壳区,其中有许多地块已逐步拼合,在其上发育裂谷型沉积地质体,未受到区域变质,若干实体变形微弱并被上覆层掩盖而得到保存。源于上古生界的油气既可赋存在其内,也可运聚于中生界或基岩内,在其西段已发现了大中型油气田群。但其整体地质研究程度偏低,仍有许多重大区域地质、油气地质问题存在歧见。针对其近年来的进展、存在的问题和油气远景评价作了概括性的评论。     

基于无机成因的油气勘查概念模型(BRCF)

基于超基性岩蛇纹石化成油理论,根据构造条件和沉积条件,提出了石油勘查概念模型——"BRCF"模型:B代表侵入地壳超基性岩;R代表储油层;C代表盖层;F代表深大断裂。运用该模型分析了波斯湾地区油气田和中国典型油气田油气成藏规律,并预测了中国大陆油气勘查靶区。     

Investigation of gas content of organic-rich shale:A case study from Lower Permian shale in southern North China Basin,central China

Measuring gas content is an essential step in estimating the commerciality of gas reserves. In this study,eight shale core samples from the Mouye-1 well were measured using a homemade patented gas desorption apparatus to determine their gas contents. Due to the air contamination that is introduced into the desorption canister, a mathematical method was devised to correct the gas quantity and quality.Compared to the chemical compositions of desorbed gas, the chemical compositions of residual gas are somewhat different. In residual gas, carbon dioxide and nitrogen record a slight increase, and propane is first observed. This phenomenon may be related to the exposure time during the transportation of shale samples from the drilling site to the laboratory, as well as the differences in the mass, size and adsorptivity of different gas molecules. In addition to a series of conventional methods, including the USBM direct method and the Amoco Curve Fit(ACF) method, which were used here for lost gas content estimation, a Modified Curve Fit(MCF) method, based on the 'bidisperse' diffusion model, was established to estimate lost gas content. By fitting the ACF and MCF models to gas desorption data, we determined that the MCF method could reasonably describe the gas desorption data over the entire time period, whereas the ACF method failed. The failure of the ACF method to describe the gas desorption process may be related to its restrictive assumption of a single pore size within shale samples. In comparison to the indirect method, this study demonstrates that none of the three methods studied in this investigation(USBM, ACF and MCF) could individually estimate the lost gas contents of all shale samples and that the proportion of free gas relative to total gas has a significant effect on the estimation accuracy of the selected method. When the ratio of free gas to total gas is lower than 45%, the USBM method is the best for estimating the lost gas content, whereas when the ratio ranges from 45% to 75% or is more than 75%, the ACF and MCF methods, are the best options respectively.     

Results of magnetotelluric surveyon reference geophysical profiles of the Karaton-Sarkamys block in Kazakhstan

A digital geoelectric model of the Karaton-Sarkamys block located in the southern (Kazakhstan) part of the Caspian Depression has been developed on the basis of processing and interpretation of magnetotelluric sounding data. Geoelectric sections and structural maps of geoelectric layers have been constructed. It has been shown that magnetotelluric sounding combined with seismic and GIS data can be efficiently used to obtain additional information on the lithologic and reservoir properties of petroleum plays.     

Magnetic measurements in electrical prospecting by resistivity methods

The electrical resistivity and induced polarization (IP) methods are widely used in geological mapping, prospecting and exploration of mineral deposits, engineering geology, hydrogeology, archaeology, and geotechnical and environmental applications. Historically, these methods have formed the basis of the electrical prospecting technique. In these methods, a DC or low-frequency AC electrical current is introduced into the earth through a grounded transmitter line. The measured quantity is the electric field. However, if the earth’s resistivity or chargeability changes horizontally, this change gives rise to an anomalous magnetic field, which is studied by the magnetometric resistivity (MMR) and magnetic induced polarization (MIP) methods, respectively. Along with advantages, some shortcomings are inherent in the MMR and MIP techniques. Apparently, the main drawback of these methods is that the magnetic fields of both the transmitter line wire and ground electrodes on the surface are several orders of magnitude greater than the anomalous magnetic field response. This introduces a significant “noise” to magnetic-resistivity data. We investigate the potential of using a circular electric dipole (CED) in magnetometric resistivity techniques. It has been found that the application of a CED, instead of a conventional transmitter line, dramatically enhances the signal-to-noise ratio.     

Effect of 2D spatial variability on slope reliability: A simplified FORM analysis

To meet the high demand for reliability based design of slopes, we present in this paper a simplified HLRF(Hasofere Linde Rackwitze Fiessler) iterative algorithm for first-order reliability method(FORM). It is simply formulated in x-space and requires neither transformation of correlated random variables nor optimization tools. The solution can be easily improved by iteratively adjusting the step length. The algorithm is particularly useful to practicing engineers for geotechnical reliability analysis where standalone(deterministic) numerical packages are used. Based on the proposed algorithm and through direct perturbation analysis of random variables, we conducted a case study of earth slope reliability with complete consideration of soil uncertainty and spatial variability.     

Probabilistic stability analyses of undrained slopes by 3D random fields and finite element methods

A long slope consisting of spatially random soils is a common geographical feature. This paper examined the necessity of three-dimensional(3 D) analysis when dealing with slope with full randomness in soil properties. Although 3 D random finite element analysis can well reflect the spatial variability of soil properties, it is often time-consuming for probabilistic stability analysis. For this reason, we also examined the least advantageous(or most pessimistic) cross-section of the studied slope. The concept of"most pessimistic" refers to the minimal cross-sectional average of undrained shear strength. The selection of the most pessimistic section is achievable by simulating the undrained shear strength as a 3 D random field. Random finite element analysis results suggest that two-dimensional(2 D) plane strain analysis based the most pessimistic cross-section generally provides a more conservative result than the corresponding full 3 D analysis. The level of conservativeness is around 15% on average. This result may have engineering implications for slope design where computationally tractable 2 D analyses based on the procedure proposed in this study could ensure conservative results.     

Origin of natural sulfur-metal chimney in the Tangyin hydrothermal field,Okinawa Trough: constraints from rare earth element and sulfur isotopic compositions

For the first time, we present the rare earth element (REE) and sulfur isotopic composition of hydrothermal precipitates recovered from the Tangyin hydrothermal field (THF), Okinawa Trough at a water depth of 1206 m. The natural sulfur samples exhibit the lowest ΣREE concentrations (ΣREE= 0.65×10^–6–4.580×10^–6) followed by metal sulfides (ΣREE=1.71×10^–6–11.63×10^–6). By contrast, the natural sulfur-sediment samples have maximum ΣREE concentrations (ΣREE=11.54×10^–6–33.06×10^–6), significantly lower than those of the volcanic and sediment samples. Nevertheless, the δEu, δCe, (La/Yb)_N, La/Sm, (Gd/Yb)_N and normalized patterns of the natural sulfur and metal sulfide show the most similarity to the sediment. Most hydrothermal precipitate samples are characterized by enrichments of LREE (LREE/HREE=10.09–24.53) and slightly negative Eu anomalies or no anomaly (δEu=0.48–0.99), which are different from the hydrothermal fluid from sediment-free mid-oceanic ridges and back-arc basins, but identical to the sulfides from the Jade hydrothermal field. The lower temperature and more oxidizing conditions produced by the mixing between seawater and hydrothermal fluids further attenuate the leaching ability of hydrothermal fluid, inducing lower REE concentrations for natural sulfur compared with metal sulfide; meanwhile, the negative Eu anomaly is also weakened or almost absent. The sulfur isotopic compositions of the natural sulfur (δ³⁴S=3.20‰–5.01‰, mean 4.23‰) and metal sulfide samples (δ³⁴S=0.82‰–0.89‰, mean 0.85‰) reveal that the sulfur of the chimney is sourced from magmatic degassing.     

The evolution of the Huangling uplift and its control on the accumulation and preservation of shale gas

There are plenty of Sinian and Cambrian potential shale gas resources in South China, which is characterized by high thermal evolution degrees, poor drilling performances and only occurs in local areas. Taking the principle “high to find low” is the key issue to achieving a breakthrough in older shale. China Geological Survey drilled in the periphery of the Proterozoic basement, i.e. the Huangling anticline, in the western Hubei, and Hannan paleocontinent in the southern Shanxi. It received high-quality gas-bearing shale with relatively low Ro in the in Lower Cambrian Niutitang formation and Sinian Doushantuo formation. Based on geological conditions of shale gas reservoirs in the Huangling anticline, this paper puts forward the new model named “Control over reservoirs by periphery of basement” about shale gas accumulation, suggesting that the shale deposited in a deepwater continental shelf in the periphery of the basement is characterized by shallow burial, a short burial time, stable tectonics, relatively low thermal evolution degrees, and shale gas reservoirs in a good condition. The shale of the Sinian-Cambrian strata deposited in deepwater continental shelves in the periphery of Chuanzhong paleo-uplift in Sichuan, Hannan paleocontinent in the southern Shanxi, Huangling anticline in western Hubei and Jiangnang-Xuefeng paleo-uplift in Hunan and Guizhou province have good shale gas exploration potential.     

黔东地区航磁特征与岩性构造填图

为了弄清黔东深覆盖地区的成矿地质背景,以2014年该区1:5万比例尺的直升机航磁资料为基础,结合地质、重力等资料,研究了该区不同岩浆岩、断裂构造的航磁特征,在综合分析的基础上,编制了该区的岩性构造图。通过分析对比,本次新圈定具有一定规模的隐伏岩体7处、蚀变岩15处,新圈定不同规模的断裂17条 。上述成果对黔东地区基础地质研究和找矿工作具有重要意义。