稳定氯同位素分馏机理及其应用的研究

过去一直认为稳定氯同位素比值(~(37)Cl/~(35)Cl)几乎不变。80年代以来利用高精度质谱法成功地发现了自然界氯同位素分馏作用。单纯的溶解和对流迁移作用不能引起同位素组分变化,而扩散作用、离子渗透作用和对流混合作用却可导致同位素分馏。各地不同深度海水的氯同位素成分极为一致,故以标准平均海水氯(SMOC)作为对比标准。得克萨斯—路易斯安那海湾油田水的δ~(37)Cl大致为+0.5‰~-1.25‰,且与氯浓度大致呈正相关。热液成矿系统中,氯同位素可作为研究矿床成因的示踪剂,如美国田纳西州密西西比河谷型矿床(MVD)的δ~(37)Cl在+0.2‰~-1.1‰之间,几个斑岩铜矿床(PVD)的早期脉岩与晚期脉岩中不同δ~(37)Cl的存在,都表明在成矿过程中有不同氯源的参与。     

Tectonic Units and Their Fundamental Characteristics on the Northern Margin of the Alxa Block

The northern margin of the Alxa block is the junction of a tectonic units. Four first-order tectonic units are distinguished: 1. the Yagan structural zone characteristic of an immature island arc; 2. the Zhusileng-Hangwula structural zone, which was a passive continental margin in the Early Palaeozoic and was transformed into an active continental margin in the Late Palaeozoic;3. the Shalazha structural zone characteristic of a mature island arc; 4. the Nuru-Langshan structural zone, which was a Proterozoic orogenic belt and later evolved into an extensional transtional crust in the Palaeozoic. The above-mentioned tectonic units differ remarkably in sedimentary formations, magmatic rock associations, metamorphism and geochemistry and are bounded by faults between one another.     

芷江雪峰矿泉水的水文地球化学机制

利用矿泉水的水文地质、水化学特征、环境同位素水文地质学和国际WATCH水/岩平衡计算机程序等新理论、新方法,可以推算出雪峰矿泉水的形成年龄和补给与迳流条件,计算出水的循环深度,以及主要成分的迁移系数,从而有机地研究矿泉水的水文地球化学机制,探讨矿泉水形成的水文地球化学成因模式。     

大方不规则伊／蒙间层矿物研究

通过X射线衍射、红外光谱、热分析、理化性能测试和镜下观察等手段,确定了贵州大方猫场含黄铁矿粘土岩中主要粘土矿物为伊/蒙不规则间层矿物,其间层作用类型为R=1,即累托石型有序间层。     

东营凹陷南坡近地表化探研究

利用引进的近地表化探系统,在济阳拗陷东营凹陷南坡的草桥油田进行了化探资料的采集、分析、处理及解释。研究证明:该系统在资料采集和现场质量控制方面有着明显的技术优势,在己知油田的断层、油水边界和油层尖灭线都有明显的地化异常。通过各种方法实验,对烃类在纵向上、横向上的丰度变化进行了初步探索。     

过量酸性铬蓝K隐色光度法测定铜的研究

在pH 4.0的微酸性介质中,酸性铬蓝K同Cu~(2+)形成稳定的红色络合物,用H_2O_2为隐色剂可以隐去过量显色剂的颜色,消除高色度背景的影响。络合物的最大吸收波长为540nm,摩尔吸光系数为1.6×10~4L·mol~(-1)·cm~(-1),Cu量在0～1.4μg/ml范围服从比尔定律。方法已应用于测定矿样中的Cu。     

X射线荧光光谱法测定叶腊石中的铝铁钾钠

采用同一矿区已知成分含量的叶腊石配制标样系列，克服了粉末法测定叶腊石中Ａｌ２Ｏ３，Ｆｅ２Ｏ３，Ｋ２Ｏ，Ｎａ２Ｏ的矿物和粒度效应。分析结果准确度满足出口材料的检测要求。     

A viscoelastic shear zone model of compressional and extensional plate boundaries

A model is proposed describing the mechanical evolution of a shear zone along compressional and extensional plate boundaries, subject to constant strain rate. The shear zones are assumed as viscoelastic with Maxwell rheology and with elastic and rheological parameters depending on temperature and petrology. Stress and strain are computed as functions of time and depth. For both kinds of boundaries the model reproduces the existence of a shallow seismogenic zone, characterized by a stress concentration. The thickness of the seismogenic layer is evaluated considering the variations of shear stress and frictional strength on faults embedded in the shear zone. Assuming that a fault dislocation takes place, the brittle-ductile transition is assumed to occur at the depth at which the time derivative of total shear stress changes from positive to negative values. The effects of different strain rates and geothermal gradients on the depth of the brittle-ductile transition are studied. The model predictions are consistent with values inferred from seismicity data of different boundary zones.     

Global synchroneity of a positive carbon isotope excursion at the Cenomanian/Turonian boundary: Validation by calcareous microfossil biostratigraphy of the Yezo Group, Hokkaido, Japan

Abstract Isotopic analyses of organic carbon from the mid-Cretaceous sequence in Hokkaido, Japan, revealed a 2‰ positive excursion of δ¹³C values at the biostratigraphically defined Cenomanian/Turonian (C/T) boundary recognized in the Yezo Group. The planktonic foraminiferal Whiteinella archaeocretacea Zone, which is known to bracket the Cenomanian/Turonian boundary elsewhere in the world, was recognized in the Oyubari area of central Hokkaido based on the distribution of commonly occurring planktonic foraminifera. In the Tappu area of northwestern Hokkaido, where diagnostic planktonic foraminifera are rare but calcareous nannoplankton occur commonly, the interval coeval with the W. archaeocretacea Zone can also be established by recognizing the conjoined last appearance levels of Corollithion kennedyi and Axopodorhabdus albianus, both calcareous nannoplankton species. Carbon isotope profiles exhibit a similar pattern with comparable peaks and troughs occurring in the same stratigraphic position in the sequences. A prominent, positive 2‰ shift of δ¹³C values, here called ‘δ¹³C spike’ occurs in the middle of the W. archaeocretacea Zone in the Oyubari area and just above the conjoined last appearances of the two above-mentioned nannoplankton taxa in the Tappu area. The Cenomanian/Turonian boundary can be drawn just above the peak position of the spike in both sections. The Rock Eval analyses and biomarker analyses of organic carbon indicate that organic carbon subjected to our isotope analyses is of terrestrial origin. Therefore, the observed 2%o shift should reflect changes in the isotopic composition of the atmospheric CO₂. A unique layer composed predominantly of sand-grain sized spumellarian Radiolaria is present immediately above the δ¹³C spike both in the Oyubari and Tappu areas, suggesting an increasing availability of both nutrients and silica in surface waters.     

Meanders caused by hyperconcentrated water flow: An example from the loess plateau,China

This paper describes meandering alluvial rivers with mean annual suspended-sediment concentrations of more than 100 kgm^?3 on the Loess Plateau, China, and explains their formation as caused by the effect of hyperconcentrated water flow. When the river is dominated by hyperconcentrated flow, the rate of energy expenditure required for sediment transport declines significantly. Accordingly, the river channel adjusts itself to a lower channel gradient by increasing the river length, resulting in a meandering channel. Since the stable transportation of sediment by hyperconcentrated flow is dependent on river channel boundary conditions, the latter play an important role in the formation of meanders of this kind. The paper also discusses the conditions for the discrimination of meandering and braided rivers in this area.