湖泊沉积有机质的地球化学记录与古气候古环境重建

与深海沉积与冰芯记录相比,湖泊沉积主要反映区域气候变迁史,可以揭示百年、甚至十年尺度的古气候事件,是高分辨率古环境、古气候重建的理想场所.传统的地质地球化学方法主要侧重于宏观物理 /化学特性描述和孢粉学的研究,近 10年来,沉积有机质分子碳、氢同位素地球化学技术的渗入,使研究工作从传统的宏观、微观层次向分子级水平发展,对诸如古生产率估算、C3/C4植被演替史、古二氧化碳分压及古温度计算等深层次问题解决提供了强有力支持.本文评述了湖泊沉积有机质分子与碳、氢同位素地球化学记录及其在区域古环境、古气候研究中的应用前景.     

Diurnal Variations of Hydrochemistry in a Travertine-depositing Stream at Baishuitai, Yunnan, SW China

Diurnal variations of hydrochemistry were monitored at a spring and two pools in a travertine-depositing stream at Baishuitai, Yunnan, SW China. Water temperature, pH and specific conductivity were measured in intervals of 5 and 30 min for periods of 1 to 2 days. From these data the concentrations of Ca²⁺, HCO₃⁻, calcite saturation index, and CO₂ partial pressure were derived. The measurements in the spring of the stream did not show any diurnal variations in the chemical composition of the water. Diurnal variations, however, were observed in the water of the two travertine pools downstream. In one of them, a rise in temperature (thus more CO₂ degassing) during day time and consumption of CO₂ due to photosynthesis of submerged aquatic plants accelerated deposition of calcite, whereas in the other pool, where aquatic plants flourished and grew out of the water (so photosynthesis was taking place in the atmosphere), the authors suggest that temperature-dependent root respiration underwater took place, which dominated until noon. Consequently, due to the release of CO₂ by the root respiration into water, which dominated CO₂ production by degassing induced by temperature increase, the increased dissolution of calcite was observed. This is the first time anywhere at least in China that the effect of root respiration on diurnal hydrochemical variations has been observed. The finding has implications for sampling strategy within travertine-depositing streams and other similar environments with stagnant water bodies such as estuaries, lakes, reservoirs, pools and wetlands, where aquatic plants may flourish and grow out of water.     

干旱区典型流域近30年土地利用/土地覆被变化的分形特征分析——以玛纳斯河流域为例

利用1976、1989、2005年三期遥感影像,运用GIS和分形理论研究干旱区典型流域——玛纳斯河流域近30年的土地利用/土地覆被变化的复杂性和稳定性。结果表明:玛纳斯河流域各时段的土地利用/土地覆被类型分布具有分形结构,土地利用/土地覆被类型形状复杂性和斑块的稳定性波动变化,1976、1989、2005年三时期的各种土地利用/土地覆被类型总平均分维值分别为1.394 0、1.363 4和1.389 9。总平均稳定性指数分别为0.606 0、0.636 6、0.610 1。三期土地利用/覆被类型平均稳定性排序为:沙地>未利用土地>居民点工矿用地>水域>林地>草地>耕地>盐碱地。耕地、林地、草地、盐碱地稳定性相对较差。通过对流域土地利用/土地覆被类型变化复杂性和稳定性的研究,可以为政府协调水土开发和调整土地利用结构提供支持。     

叠前时间偏移方法在煤田勘探中的应用

根据克希霍夫积分法的原理,介绍了叠前时间偏移的方法特点,实现过程,以及对地震资料的要求,依托国家重大产业技术专项“西部煤炭资源高精度三维地震勘探”工程,对“青海省鱼卡煤田四井田高精度三维地震勘探”资料进行叠前时间偏移,结果表明其能较好地解决成像质量差、能量聚焦不明显、绕射波收敛不理想等方面的难题。通过与叠后时间偏移对比,对于大倾角地层、断块小且多的破碎带、陡倾角不对称向斜等地质问题,其叠前时间偏移剖面成像质量都有明显的提高,反映的构造关系更加清晰,同相轴连续性增强。总结该方法在多个矿区的推广经验．认为合理的观测系统、较高的资料信噪比,准确的测量资料及较高的中表层速度调查精度是做好叠前时间偏移的前提。     

Chromium speciation in oxide-type compounds: application to minerals,gems, aqueous solutions and silicate glasses

Cr K-edge XANES spectra were obtained for a variety of Cr-bearing model compounds containing Cr(II), Cr(III), Cr(IV), Cr(V) and Cr(VI), in which the Cr-site symmetry is D4h, Oh and Td. The centroid position of the pre-edge feature is a better indicator of the Cr valence than the edge position. In Cr-rich oxides, higher-energy transitions must be excluded in order to refine a robust valence for Cr. The pre-edge for chromates is not unique and varies as a function of the CrO₄ ^2? moiety distortion, which is often related to Cr-polymerization (monochromate vs. dichromate). Both the analogy with the Mn K-pre-edge information and ab initio FEFF calculations of the pre-edge feature for Cr(III) and Cr(VI) confirm the experimental trends. This methodology is applied to the Cr K-edge pre-edge feature collected in gems (emerald, spinel and ruby), the layered minerals fuchsite and kämmererite, two Cr-bearing aqueous solutions and a set of sodo-calcic silicate glasses used for bottling sparkling white wine. In emerald and fuchsite, the Cr-site is differently distorted than its ruby or spinel counterpart. In a Cr(III)-bearing aqueous solution and sodo-calcic glass, no evidence for Cr(III) with Td and C3v symmetry is detected. However, minor amounts of chromate moieties (most likely monomeric) are detected in a glass synthesized in air. Preliminary spectra for the wine bottle glass suggest that only trace amounts of chromates might possibly be present in these glasses.     

洞庭湖地区重力资料精细反演解释

用快速准确重力三维正演算法计算白垩系顶面及以上各密度界面的重力异常,采用“剥皮法”从实测重力异常中减去自垩系顶面及以上各密度界面的重力效应后得到剩余异常,由此反演研究区内白垩系底面深度。由于采用快速三维反演算法并顾及地质及航磁异常信息,求得了白垩系厚度,计算出的底板埋深等更为合理、精细,为洞庭地区油气资源基础性研究及评价提供了重要的信息。     

羌塘地区榴辉岩中矿物出溶体及其成因机制探讨

西藏羌塘地区榴辉岩石榴子石和磷灰石中均发育矿物出溶体,结合电子探针和扫描电镜分析及能谱分析,确定了石榴子石中的出溶体有金红石、石英和角闪石,指示其可能经历了高压/超高压变质作用。本研究在磷灰石中发现了金红石出溶,并认为其可能是在高压/超高压条件下元素相互置换的结果,置换方式为Ti~(4+)(Fe~(2+)、Si~(4+))=2Ca~(2+),这些出溶体的形成为榴辉岩曾经历高压/超高压变质作用提供了矿物学证据。     

南海南部陆缘地质流体类型及其油气成藏意义

南海南部陆缘蕴藏着非常丰富的油气资源。为了解南海南部陆缘流体活动系统以及与油气藏之间的关系,以高精度2D地震资料为基础,对南海南部陆缘流体活动系统的类型、地震反射特征、以及对油气成藏的意义开展了研究。在南海南部陆缘发现了多种流体活动系统,包括:泥底辟/泥火山、气烟囱、管状通道、与构造断层相关的流体活动系统。这些流体活动系统具有不同的地震反射特征,常常出现含气强振幅异常带、弱振幅杂乱反射带以及"下拉"或者"上拱"地震反射形态等流体活动系统的标志特征。流体活动系统受到构造运动和沉积因素的影响,并且与深部高温高压塑性流体密切相关,流体活动系统优先发育在地层薄弱部位。流体活动系统及所伴生的断裂和裂隙常常作为油气富集区的运输通道;并且流体活动系统所运移的强溶蚀性流体和深部热液流体有利于油气储层的形成,特别是对于碳酸盐岩储层的改造尤为明显。因此,流体活动系统不仅能作为油气运移通道,也可以改善储层,对油气成藏具有重要意义。     

典型隔水边界非稳定流承压含水层抽水试验研究

隔水边界附近的承压含水层,即半无限区域的承压含水层参数的准确求取对于特定地段的地下水资源量计算具有重要意义。以高密市柴沟镇小于家庄抽水试验为例,详细阐述了隔水边界附近的承压含水层参数求取过程,并对结果进行较为详尽的讨论。     

陕西华阳川铀多金属矿床黑云母~(40)Ar/~(39)Ar年龄及其地质意义

笔者采用Ar-Ar测年技术,获得华阳川铀多金属矿床碳酸岩中黑云母~(40)Ar/~(39)Ar坪年龄132.58±0.70 Ma,等时线年龄133.01±0.74 Ma,含黑云母闪石硫化物伟晶岩中黑云母的~(40)Ar/~(39)Ar坪年龄93.72±2.38 Ma,等时线年龄91.49±1.97 Ma。镜下特征显示,铌钛铀矿的形成晚于碳酸岩中的黑云母及含黑云母闪石硫化物伟晶岩中的黑云母。因此,铌钛铀矿的形成时间应晚于93.72±2.38 Ma。这表明成矿带内除了已知存在三叠纪碳酸岩型Mo-Pb矿和白垩纪斑岩型Mo矿的成矿过程之外,还存在早白垩世之后的岩浆热液型U-Nb-Ti成矿过程。