近40年来气候变化对青海盐湖及其矿产资源开发的影响——以小柴旦湖为例

青海是中国盐湖主要分布区之一,蕴藏着丰富的矿产资源。文章以RS和GIS技术为基础,从20世纪70年代、90年代、2000年前后、2008~2009年和2013~2014年五期Landsat遥感影像中提取了青海面积大于10 km2的所有盐湖(不包括干盐湖),分析了其近40年来的变化趋势:总体上,盐湖总面积除在2000年前后有所减少外,基本上呈现增加的趋势;具体而言,2000年前后,萎缩的盐湖主要分布在柴达木盆地;其他时期均呈现全面扩张的趋势。在全球气候变暖的大背景下,通过分析青海地区11个气象台站的年平均气温、年降雨量和蒸发量数据,可知青海地区气候呈现了向暖湿方向转型的趋势,且2002年之后更为明显。最后,以青海省小柴旦湖为例,分析了湖泊淡化、矿产资源贫化对盐湖资源开发的影响,具体为:1资源开发成本升高、难度加大,甚至使一些处于工业开发临界品位的盐湖失去开发价值;2盐湖淡化条件下,锂等矿产资源有效提取技术亟待研发;3政府制定矿产资源开发政策时,需要对气候及盐湖的动态变化过程综合考虑。以上说明,青海地区的暖湿气候使盐湖大幅度淡化,给盐湖矿产资源开发带来了新的挑战。     

再论甘肃镜铁山铁矿成因

甘肃“镜铁山”铁矿位于北祁连山加里东褶皱带西段,因铁矿规模大、类型特殊,并同时赋存一个中型铜矿而倍受关注。有关矿床成因各家意见不一,有“火山热液沉积”说,“变质沉积”说,“海底喷气沉积”说,“Sedex型”等,但均认为铁矿属沉积矿产。笔者近期在野外工作期间,在与成矿关系密切的黑色千枚岩中发现了钙质千枚岩捕掳体,证明黑色千枚岩为火成岩,所采矿石、围岩样品的地球化学性质也显示出火成岩特征,因局部地段黑色千枚岩与铁矿成过渡关系,并结合前人所测成矿温度在280℃至340℃之间等证据,综合分析认为镜铁山铁矿可能不是沉积成因,而是与中、基性岩有关的热液变质铁矿。     

基于地质异常的甘肃省铅锌矿成矿定量预测

查明地质异常是成矿预测的基础、找矿的前提、靶区圈定的依据。本文以"三联式"成矿预测理论为指导,着重探讨了甘肃省铅锌矿地质、地球物理以及地球化学异常的识别、提取与圈定,运用定量分析方法,厘定地质异常与铅锌矿种之间的关联,在此基础上,运用证据权成矿预测方法实现对甘肃省铅锌矿床的成矿定量预测及成矿远景区圈定。     

Mineralogy and major-element geochemistry of the lower Permian Greta Seam,Sydney Basin,Australia

The mineralogy of the high-volatile bituminous coals and associated strata from the Greta seam, Sydney Basin, Australia, has been evaluated in this study. Although the seam is not immediately overlain by marine strata, percolation of marine water into the original peat bed is indicated by the petrological, mineralogical and geochemical characteristics, which resemble those of coals with marine roof strata. The upper and lower sections of the seam have contrasting mineralogy. Pyrite typically comprises 40 to 56 wt% of the mineral assemblage in the marine-influenced upper part of the seam section. The lower part contains much less pyrite (typically <5 wt%, organic-free basis), and also relatively abundant dawsonite (up to 14 wt%, organic-free basis). The minerals within most coal plies are largely of authigenic origin. These include pyrite, siderite, clay minerals (mainly kaolinite and Na-rich mixed-layer illite/smectite), and quartz, most of which have a relatively early, syngenetic origin. Minor Ti-bearing minerals, anatase or rutile, and phosphate minerals, fluorapatite and goyazite, were probably also formed during early diagenesis. Other minerals have features that indicate late-stage precipitation. These include abundant cleat- and fracture-filling dawsonite, which may be the result of reactions between earlier-precipitated kaolinite and Na₂CO₃- or NaHCO₃-bearing fluids. Minor albite may also be epigenetic, possibly precipitated from the same Ca–Al bearing fluids that formed the dawsonite. The most abundant detrital minerals in the Greta coals are quartz, poorly ordered kaolinite, illite and mixed-layer illite/smectite (I/S). These occur mainly in the floor, roof and other epiclastic horizons of the seam, reflecting periods of greater clastic influx into those parts of the original peat-forming environment. Detrital minerals are rare in the coals away from the epiclastic horizons, probably owing to almost complete sediment bypassing in the depositional system. Alternatively, any detrital minerals that were originally present may have been leached from the peat bed by diagenetic or post-diagenetic processes.     

优化的NSGA-Ⅱ方法在马莲河流域水资源综合管理中的应用研究

根据马莲河流域水资源总量极端贫乏、年际年内分配不均、常规水资源量低、水污染问题较严重等特点,利用系统分析理论和优化技术建立了流域的大系统、多目标水资源优化配置模型,并利用优化的NSGA-Ⅱ方法进行求解,得到流域2020年期望水资源配置下的最佳分配方案为:流域总供水量57 086×104m3,工业供水量21 690×104m3(总产值约为144.6亿元),能源基地供水量4 329×104m3(总产值约为346.32万元),农业供水量20 840×104m3,生活供水量9 452×104m3,生态供水量811×104m3。对比期望方案供水量增加了6 710×104m3,综合缺水率减少了11.41%。并根据预测的流域的分配方案和预测的流域需水量,进行了流域的水资源平衡分析,通过平衡分析的结果进行流域的综合管理研究。2020年在最优水资源分配方案下,工业缺水率3.21%、减少了4.51%;能源基地缺水率0.00%;农业缺水率4.64%、缺水率增加26.17%;生活缺水率0.00%;生态缺水率1.00%、缺水率增加了1.00%。配置方案实现了流域内水资源的最佳分配,使宝贵、有限的水资源产生最大的社会、经济及环境效益,为流域经济、能源产业的快速发展提供水资源保障。     

山东张家洼矽卡岩型铁矿矿物学特征及其对成矿环境的指示意义

张家洼矽卡岩型铁矿位于华北克拉通东南部,赋存在石炭系本溪组与奥陶系马家沟组之间的假整合面处及闪长岩体与奥陶系马家沟组大理岩的接触带附近,富铁矿石资源量已达大型规模。研究发现矽卡岩矿物种类在内外接触带分布有一定区别,内带为石榴石等钙质矽卡岩矿物,而外带为阳起石、金云母等镁质矽卡岩矿物,整体构成钙镁质矽卡岩。对矽卡岩矿物系统的研究表明,透辉石及石榴石发育有环带,其氧化物含量随矿物环带的形成比例不断变化,暗示酸碱度及氧逸度随着成矿流体的演化而发生相应的变化,即由早期矽卡岩阶段的相对还原的酸性环境演化为退化蚀变阶段相对氧化的碱性环境从而导致铁质逐渐萃取多次富集、沉淀,后期随着磁铁矿的沉淀又逐渐在硫化物阶段转化为还原环境生成金属硫化物。     

新疆雅满苏铁矿床矽卡岩和磁铁矿矿物学特征及其地质意义

雅满苏铁矿床位于东天山中段,矿体赋存于下石炭统雅满苏组安山质火山碎屑岩中,受近EW向断裂及环形断裂构造控制。矿体主要呈层状、似层状、透镜状,近矿围岩蚀变强烈,形成石榴石矽卡岩及复杂矽卡岩。电子探针分析结果表明,石榴石为钙铁榴石-钙铝榴石系列,其化学组成可表示为And45.68~100Gro0.67~57.95(A1m+Sps)11~29.03,与典型的矽卡岩型铁矿中石榴石端员组分相似。在磁铁矿Ca+Al+Mn-Ti+V图解中,大部分样品落入矽卡岩型铁矿区;TiO2-Al2O3-MgO图解中,大多数的样品落入沉积变质接触交代磁铁矿趋势区,部分早期磁铁矿落在岩浆趋势区内。结合矿床地质特征和矿物学研究,认为大多数样品经过了一个热液交代作用过程,表明雅满苏铁矿的形成与岩浆热液交代作用有关。     

羌塘盆地结构构造与油气勘探方向

羌塘盆地是我国陆域大型中生代海相沉积盆地,富含烃源岩,但结构构造非常复杂。结合野外观测及相关资料对地震反射剖面进行地质构造详细解释,良好地揭示了羌塘盆地结构和深部构造。羌塘盆地逆冲推覆构造延伸存在显著差别,北羌塘凹陷多格错仁逆冲推覆构造、阿木错逆冲推覆构造与南羌塘凹陷肖茶卡—双湖逆冲推覆构造、多玛—其香错逆冲推覆构造仅发育于盆地表层0~3km深度范围,北羌塘凹陷龙尾错逆冲推覆构造、羌中隆起北缘逆冲推覆构造、南羌塘凹陷赛布错—扎加藏布逆冲推覆构造、拉萨地块北缘色林错逆冲推覆构造系统自地表向深部延伸深度超过6km,羌塘盆地深部还发育中生界底部逆冲系和基底逆冲系,伴有不同规模的褶皱构造。逆冲推覆构造形成活动时代包括晚白垩世、古近纪早期和古近纪晚期,晚白垩世与古近纪早期逆冲推覆构造运动导致构造隆升的裂变径迹年龄分别为87±5~75±4Ma、64±5~46±4Ma。经过多期逆冲推覆构造改造和褶皱变形,羌塘盆地中生界海相沉积地层与烃源岩显著增厚,为新生代晚期二次生烃及油气成藏提供了非常有利的地质构造条件;北羌塘凹陷发育万安湖向斜、半岛湖背斜、东湖向斜、阿木错向斜,南羌塘凹陷发育宁日圈闭、鲁雄错背斜、诺尔玛错圈闭、协德圈闭、崩则错圈闭,羌中隆起下伏侏罗系和三叠系烃源岩,色林错下白垩统下伏古近纪湖相沉积,这些构造部位都是油气勘探的重要靶区。     

Geochemistry of mafic rocks and melt inclusions and their implications for the heat source of the 14.0°S hydrothermal field,South Mid-Atlantic Ridge

Fresh rocks sampled from the 14.0°S hydrothermal field of the South Atlantic Ridge can be divided into two categories： olivine-gabbro and basalt. The olivine-gabbro is composed mainly of three types of minerals： olivine, clinopyroxene and plagioclase, while a multitude of melt inclusions occur in the plagioclase phenocrysts of the basalts. We analyzed the whole-rock, major and trace elements contents of the basaks, the mineral chemistry of phenocrysts and melt inclusions in the basalts, and the mineral chemistry of olivine-clinopyroxene-plagioclase in the olivine-gabbro, then simulated magma evolution within the crust using the COMAGMAT program. The whole-rock geochemistry shows that all the basalts exhibit typical N-MORB characteristics. In addition, the mineral chemistry characteristics of the olivine-gabbro （low-Fo olivine, low-Mg# clinopyroxene, high-TiO2 clinopyroxene, low-An plagioclase）, show that strong magma differentiation occurred within the crust. Nevertheless, significant discrepancies between those minerals and phenocrysts in the basalts （high-Fo olivine, high-An plagioclase） reflect the heterogeneity of magma differentiation. High Mg# （-~0.72） melt inclusions isobaric partial crystallization simulations suggest that the magma differentiation occurred at the depth shallower than 13.03 km below the seafloor, and both the vertical differentiation column shows distinct discrepancies from that of a steady-state magma chamber. Instead, a series of independent magma intrusions probably occurred within the crust, and their corresponding crystallized bodies, as the primary high-temperature thermal anomalies within the off-axis crust, probably act as the heat source for the development of the 14.0°S hydrothermal system.     

Mineral characteristics and their geological significance of black shales in southeastern Ordos Basin by X-ray diffraction analysis

X-ray diffraction analysis of black shale of Upper Triassic Member Chang 7 of the Yanchang Formation in southeastern Ordos Basin showed that black shales were deposited in brackish, strongly reducing, semi-deep-deep lacustrine facies, and mainly composed of quartz, feldspar, carbonate （dolomite）, clay minerals （illite and il- lite/smectite） and a certain amount of pyrite. The mineral composition characteristics of this set of black shales are similar to those of highly productive shale gas in North America, for example shallow burial, low clay mineral and abundant brittle mineral, so the strata are conducive to the development of cracks and fractures. Thus, this area is favorable for shale oil/gas exploration and development.