西菲律宾海沉积物稀土元素地球化学

对取自西菲律宾海区3个沉积物柱样（WP1、WP2和WP40）的32个样品的稀土元素（REE）地球化学行为进行了系统的研究。区内沉积物表现出以下特征：①稀土元素含量及总量（ZREE）较低，WP1、WP2和WP40孔的ΣREE依次为72．91×10－6，54．15×10－6和54．18×10－6，REE在粘土粒级中得到了较大富集；②REE球粒陨石标准化的分布模式曲线表现为负斜率，富集轻稀土，WP1、WP2和WP40孔LREE／HREE比值平均值为37．36，26．33和17．16，页岩标准化曲线大致呈水平；③与球粒陨石和页岩相比，Ce都表现为强烈的亏损；以球粒陨石为标准，WP40孔表现为弱的Eu正异常，其他两孔表现为弱的Eu负异常；以页岩为标准，皆显示Eu正异常；④ΣREE纵向变化曲线与CaCO3旋回曲线有良好的对应关系。上述特征表明：①沉积物的来源复杂，有陆源、火山源、生物源和自生源，在所研究的三个孔中，WP1孔含有较多的陆源物质，WP2和WP40含有较多的火山物质；②被粘土吸附是本区REE重要的存在形式；③沉积物形成环境为氧化条件；④据ΣREE的纵向变化曲线与CaCO3旋回曲线，将本区沉积物自下而上划分为末次冰期亚间冰期沉积、冰期最盛期沉积和全新世沉积。     

陕西洛川黄土沉积物中稀土元素及其它微量元素的化学淋滤研究

本文采用化学淋滤的方法对洛川黄土沉积物的酸溶和酸不溶相中稀土元素以及其它微量元素的分布分配特征进行了系统的分析。     

楚雄盆地铜、盐、有机质相互作用与砂岩铜矿生成

矿床的有机地球化学研究表明:楚雄盆地含煤、含铜和含膏盐建造中的有机质在来源、类型和成熟度上是不一致的。成岩期干酪根降解形成的短链羧酸是矿源层中铜活化的重要因素,石油烃是矿质搬运的重要载体。改造成矿期,天水淋滤膏盐展形成富SO_4~(2-)的下渗氧化性流体,为改造成矿提片供了硫源。另一方面,来自基底的含矿流体沿同生断裂上涌,混染煤系地层形成还原性流体,沿次级断裂进入到高渗透的砂岩储集层。当两种流体在砂岩中相遇时,发生氧化-还原作用而形成改造期矿体。     

Behaviours of REE and Other Trace Elements During Pedological Weathering-Evidence from Chemical Leaching of Loess and Palaeosol from the Luochuan Section in Central China

The chemical leaching method is used for a systematic analysis of distribution characteristics of acid-soluble and acid-insoluble REE and other trace elements from the Luochuan loess deposits. The study shows that the acid-insoluble phase in loess and palaeosol is a stable component of old aeolian dusts and is characteristic of the provenance; the acid-soluble phase is the unstable component in the weathering pedogenic process and reflects rock-forming features after accumulation of aeolian dusts. The acid-insoluble REE and acid-soluble Sr and Pb can be used as geochemical indicators respectively to trace the provenance characteristics and the weathering pedogenic process.     

Rare earth and other trace element mobility during mylonitization: a comparison of the Brevard and Hope Valley shear zones in the Appalachian Mountains, USA

In progressing from a granitoid mylonite to an ultramylonite in the Brevard shear zone in North Carolina, Ca and LOI (H₂O) increase, Si, Mg, K, Na, Ba, Sr, Ta, Cs and Th decrease, while changes in Al, Ti, Fe, P, Sc, Rb, REE, Hf, Cr and U are relatively small. A volume loss of 44% is calculated for the Brevard ultramylonite relative to an Al–Ti–Fe isocon. The increase in Ca and LOI is related to a large increase in retrograde epidote and muscovite in the ultramylonite, the decreases in K, Na, Si, Ba and Sr reflect the destruction of feldspars, and the decrease in Mg is related to the destruction of biotite during mylonitization. In an amphibolite facies fault zone separating grey and pink granitic gneisses in the Hope Valley shear zone in New England, compositional similarity suggests the ultramylonite is composed chiefly of the pink gneisses. Utilizing an Al–Ti–Fe isocon for the pink gneisses, Sc, Cr, Hf, Ta, U, Th and M-HREE are relatively unchanged, Si, LOI, K, Mg, Rb, Cs and Ba are enriched, and Ca, Na, P, Sr and LREE are lost during deformation. In contrast to the Brevard mylonite, the Hope Valley mylonite appears to have increased in volume by about 70%, chiefly in response to an introduction of quartz. Chondrite-normalized REE patterns of granitoids from both shear zones are LREE-enriched and have prominent negative Eu anomalies. Although REE increase in abundance in the Brevard ultramylonites (reflecting the volume loss), the shape of the REE pattern remains unchanged. In contrast, REE and especially LREE decrease in abundance with increasing deformation of the Hope Valley gneisses. Mass balance calculations indicate that ≥95% of the REE in the Brevard rocks reside in titanite. In contrast, in the Hope Valley rocks only 15–40% of the REE can be accounted for collectively by titanite, apatite and zircon. Possible sites for the remaining REE are allanite, fluorite or grain boundaries. Loss of LREE from the pink gneisses during deformation may have resulted from decreases in allanite and perhaps apatite or by leaching ofy REE from grain boundaries by fluids moving through the shear zone. Among the element ratios most resistant to change during mylonitization in the Brevard shear zone are La/Yb, Eu/Eu*, Sm/Nd, La/Sc, Th/Sc, Th/Yb, Cr/Th, Th/U and Hf/Ta, whereas the most stable ratios in the Hope Valley shear zone are K/Rb, Rb/Cs, Th/U, Eu/Eu*, Th/Sc, Th/Yb, Sm/Nd, Th/Ta, Hf/Ta and Hf/Yb. However, until more trace element data are available from other shear zones, these ratios should not be used alone to identify protoliths of deformed rocks.     

铜陵地区中酸性侵入岩年代学研究

本文选择了铜陵地区主要岩石类型的代表性岩体中黑云母为测定对象，准确地测定了侵入岩的４０Ａｒ／３９Ａｒ同位素年龄。测定结果表明，区内侵入岩的年龄均小于１４０Ｍａ，属燕山晚期的产物，后期热事件为成矿时代，晚于岩浆侵入时代，在此基础上，分析了ＫＡｒ法、ＲｂＳｒ法同位素年龄产生偏差的原因     

浙江杭嘉湖平原区环境地球化学研究

根据杭嘉湖平原区区域地球化学调查结果,对本区开展了区域和城市(杭州市)环境质量评价的环境地球化学研究。研究结果表明,杭嘉湖平原区区域环境质量和杭州市区环境质量良好,各环境质量区较好的反映各区内工业生产水平、人口密集程度、历史长短。通过对杭州市不同环境质量区内蔬菜的分析研究证明,杭州市区污染区内有害元素尚未对人体健康产生影响,但为防止今后出现超标现象,应当高度重视,加强土壤环境保护。     

山东牟平邓格庄金矿的地球化学特征及成因

邓格庄大型石英脉型金矿，分布于燕山期昆嵛山花岗岩体内金牛山断裂带次级断裂中。成矿年龄１１８×１０６ａ，它比容矿岩体冷凝至３５０℃时还晚１２×１０６ａ。成矿深度小于１ｋｍ（约０．７５ｋｍ），而容矿岩体的定位深度大于１３ｋｍ，它们的定位深度差大于１２ｋｍ。成矿流体来自地壳深部，通过水－岩反应又从容矿岩体中萃取一部分金。故此金矿不是传统意义的岩浆期后热液矿床     

云南腾冲热泉金的有机地球化学研究——Ⅰ生物标志物浅析

本文主要通过对比分析研究热泉软泥中的金含量与有机质及含硫化合物的相关性。并测定泉水及软泥中含金量和软泥中有机碳含量，以及对抽提物中的饱和烃和芳烃族组分进行色谱—质谱分析，最后得出的结论：有机质的沉积环境为还原—强还原，有机质属于腐泥－腐殖型，接近和达到了成熟阶段。软泥中金含量与有机质的性质无明显相关关系，与有机碳含量也无明显相关关系，而与其成熟度相关密切。样品分析证实软泥中含硫化合物与金含量呈正相关性。对比分析了水及软泥中金含量，认为两者之间也无明显相关关系     

胶东昆嵛山花岗岩的特征、成因及其与金矿的关系

昆嵛山花岗岩是牟平—乳山金矿成矿带的围岩，在其成因和定位时代上长期存在争议。本文对岩体地质和地球化学特征进行了系统研究，并就岩体成因及其与金矿的关系进行了讨论。作者认为，昆嵛山花岗岩是在中生代由岩浆缓慢冷凝结晶形成的大型复式岩基，并非交代成因。它由垛崮顶片麻状花岗闪长岩（１４７Ｍａ）、八门邹家斑状花岗闪长岩（１３５Ｍａ）、瓦善—水道弱片麻状二长花岗岩及五爪山片麻状含榴二长花岗岩（１２０Ｍａ）组成，成分具贫铝富碱的特点。岩浆来源于中下地壳中酸性变质火山岩系部分熔融形成的岩浆，其形成温度为６５０—７５０℃。岩体经历了韧性和脆性变形作用，不同方向的片麻状构造是岩浆结晶期韧性变形作用的结果。脆性变形形成的断裂和破碎带是本区主要的导矿和容矿构造。花岗岩定位、韧和脆性变形作用与金矿成矿作用有十分密切的关系