壳幔混染作用——下扬子区早中生代玄武岩同位素地质特征

下扬子区中生代（231Ma）玄武质火山岩全岩εNd（t）值-8.62～1.92,87Sr/86Sr 值0.7074～0.7179，206Pb/204Pb值为17.786～18.323。岩石中含有前寒武纪捕虏晶锆石。研究表明玄武质岩石可能是由亏损地幔与元古宙地壳岩石混染作用的结果。     

The origin and distribution of HAPs elements in relation to maceral composition of the A1 lignite bed (Paleocene, Calvert Bluff Formation, Wilcox Group), Calvert mine area, east-central Texas

The origin and distribution of twelve potentially Hazardous Air Pollutants (HAPs; As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, and U) identified in the 1990 Clean Air Act Amendments were examined in relation to the maceral composition of the A1 bed (Paleocene, Calvert Bluff Formation, Wilcox Group) of the Calvert mine in east-central Texas. The 3.2 m-thick A1 bed was divided into nine incremental channel samples (7 lignite samples and 2 shaley coal samples) on the basis of megascopic characteristics. Results indicate that As, Cd, Cr, Ni, Pb, Sb, and U are strongly correlated with ash yield and are enriched in the shaley coal samples. We infer that these elements are associated with inorganic constituents in the coal bed and may be derived from a penecontemporaneous stream channel located several kilometers southeast of the mining block. Of the HAPs elements studied, Mn and Hg are the most poorly correlated to ash yield. We infer an organic association for Mn; Hg may be associated with pyrite. The rest of the trace elements (Be, Co, and Se) are weakly correlated with ash yield. Further analytical work is necessary to determine the mode of occurrence for these elements. Overall, concentrations of the HAPs elements are generally similar to or less than those reported in previous studies of lignites of the Wilcox Group, east-central region, Texas. Petrographic analysis indicates the following ranges in composition for the seven lignite samples: liptinites (5–8%), huminites (88–95%), and inertinites (trace amounts to 7%). Samples from the middle portion of the A1 bed contain abundant crypto-eugelinite compared to the rest of the samples; this relationship suggests that the degradation of plant material was an important process during the development of the peat mire. With the exception of Hg and Mn, relatively low levels of the HAPs elements studied are found in the samples containing abundant crypto-eugelinite. We infer that the peat-forming environment for this portion of the coal bed was very wet with minimal detrital input. Relatively high concentrations of crypto-humotelinite were found in samples from the top and base of the coal bed. The presence of abundant crypto-humotefinite in this part of the coal bed suggests the accumulation of wood-rich peat under conditions conducive to a high degree of tissue preservation in the peat mire. Although several of the trace elements (Be, Co, Ni, and Sb) exhibit enrichment in these samples, they are not necessarily chemically associated with humotelinite. We infer that these elements, with the exception of Be, are possibly associated with deposition of the roof and floor rock of the coal bed; however, further analytical work would be necessary to confirm this hypothesis. Beryllium may have an organic origin.     

The Origin of the Early Proterozoic Kuandian Complex: Evidence from Geochemistry

The Kuandian Complex is scarcely preserved Early Proterozoic volcanic suite, formed2.3-2.4 Ga ago. It is located in an Early Proterozoic mobile belt bounded by the ArchaeanRangrim and Ryonggang Blocks of the northeastern Sino-Korean Craton. The Complex ismainly made up of amphibolites, gneisses, leucoleptite, leptite and layered granite. Petrologicaland geochemical studies show that the protoliths of the Complex are mainly assoctations ofbimodal volcanics and anorogenic granites. The Kuandian amphibolites are depleted in Nb, Ta,P and Ti, and enriched in LILE, e.g. K, Rb and Cs, with pronounced depletion of Sr relative toNd and Pb; La/Nb ratios are higher than 1(1.75 to 5.18). The trace element patterns of theamphibolites are similar to continental flood basalts formed by the Gondwana break-up, suchas those in South Karoo and Tasmania, which shows continental contamination. ε_(Nd) valuesranging from 0.70 to 1.94 of the Kuandian amphibolites and the relationships between Nb/Yband La/Yb suggest that contamination of basaltic magma happened in the mantle, rather thanalong the conduit. Isotope ratios of ~(208)Pb/~(204)Pb, ~(207)Pb/ ~(204)Pb, ~(206)Pb/~(204)Pb, ~(143)Nd/~(144)Ndand ~(87)Sr/~(86)Sr indicate that the magma was derived from a contaminated mantle source likeDMM or a mixture of DMM and EM2. The Kuandian Complex has Dupal anomaly, as is thecase with some continental basalts in the south hemisphere, e.g. in South Karoo and Tasmania.Petrochemical modelling proposes that the Kuandian gneiss, granite, and amphibolite camefrom the same parental magma, being products of strong fractional crystallization. Protoliths ofthe Kuandian Complex were formed in extensional tectonic setting during the transition fromcontinental crust to oceanic crust. The formation of the Kuandian Complex indicates that 2.3or 2.4 Ga ago tectonic evolution of the Sino-Korean craton was different from that of otherwell-studied Precambrian cratons, e.g. the North American shield, European platform andAustralian continent in that strong volcanic eruption resulted in its accretion. Besides, the con-taminated magma source with a Dupal anomaly for the Complex indicates that crust-mantleconvection whose scale was similar to that of the present plate tectonics had occurred at leastbefore the formation of the Kuandian Complex (2.3-2.4 Ga B.P).     

云南老王寨金矿煌斑岩地球化学研究中的某些问题──与宋新宇等同志商榷

本文对“云南老王寨金矿煌斑岩地球化学研究”一文中的部分结论及其解释，提出一些不同意见与原文作者宋新宇等先生商榷     

扬子地块西缘灯影组层控铅锌矿床成因的地球化学论证

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粤东北嵩溪银锑矿床地质地球化学初步研究

粤东北嵩溪银锑矿床地质地球化学初步研究肖振宇郑庆年（广东有色金属地质勘查院，广州５１００８０）陈繁荣张湖（中国科学院广州地球化学研究所，广州５１０６４０）关键词地质地球化学银锑矿床嵩溪嵩溪银锑矿床发现于粤东北地区，有嵩溪、黄沙塘等矿床和梅子坑、仙客社...     

高温高压下水岩界面反应与金的迁移富集

高温高压下水岩界面反应与金的迁移富集王玉荣阚小凤王志强（中国科学院广州地球化学研究所，广州５１０６４０）关键词水岩界面反应自发电池实验地球化学本实验以哈达门沟［１］及东坪金矿［２］为地质背景，研究钾长石岩中金矿化富集的物理化学条件。该区金矿既与早期变...     

安徽铜山铜矿床地球化学特征及其成因

铜山铜矿床不同矿石类型在硫、铅、氢、氧同位素，硫化物矿物中微量元素，稀土元素，矿物生成温度等地球化学方面明显地显示了内生成矿作用和外生成矿作用两种不同特征。结合成矿地质条件所进行的矿床成因分析表明，该矿床为一矿石矿质和含矿热液（介质水）分别来自燕山期中酸性岩浆和地下热雨水的多来源矿床，并据此建立了成矿模式。     

九甸峡工程区断层测年结果研究与讨论

断层的年代测定是研究断层活动性的重要内容之一。然而, 一个工程同一条断层会出现不同的测年结果, 从而引起争议和难予决断。近年来我们通过几个大型工程区域稳定性研究, 对此获得了一些认识。本文以洮河九甸峡地区几条主干断层为研究对象, 采用同位素年龄测定与野外地质调查和显微构造分析相结合的方法, 对断层测年问题作一分析和讨论, 也许对岩土工程断层活动性研究有一定参考价值。     

天山东段尾亚地区白尖山超单元特征

早石炭世白尖山超单元横亘于尾亚站东西两侧，沙泉子断裂以南的狭长地带（研究区长５０余千米，宽３～６ｋｍ）。它是北部觉洛塔格早石炭世火山型被动陆缘与其南（以沙泉子断裂为界）卡瓦布拉克古陆块汇聚事件的产物。这次事件导致沿卡瓦布拉克地块北缘成线状分布的巨大岩基链的形成，即该带事实上成为一个活动陆缘弧──白尖山岩浆弧（白尖山超单元）。根据各岩石单元的接触关系，白尖山超单元由早至晚为辉长岩—石英闪长岩—花岗闪长岩—二长花岗岩—钾长花岗岩—碱长花岗岩。从沙泉子断裂向南，大体上反映出偏基性的石英闪长岩单元偏北侧分布，钾长花岗岩及碱长花岗岩单元偏南分布，表现出当时碰撞带的特性。由于晚石炭世末受到韧性剪切作用，大部分产生塑性变形，成为初糜棱岩—超糜棱岩的花岗质岩石，宏观上似具片麻状构造。无论从岩石学、岩石化学及地球化学特征方面来看，均具同源岩浆演化的特征。白尖山超单元侵入于含早石炭世动物化石的卡拉火大山组中，被二叠纪尾亚超单元组合（原尾亚岩体）侵入，测定Ｕ—Ｐｂ同位素年龄为３３８．４Ｍａ及３２５．２４Ｍａ，从而确定白尖山超单元形成时代为早石炭世。