Noble gas tracers for characterisation of flow dynamics and origin of groundwater: A case study in Switzerland

The Grenchen aquifer system in the Swiss Plateau was extensively investigated in order to determine the extent of groundwater contamination and to assess the natural attenuation capacity. Environmental tracer data were applied to estimate groundwater travel times, mixing ratios, and evaluate groundwater origin. Recharge is basically possible in two distinct topographical areas, the immediate vicinity of the town of Grenchen and the elevated plateau of the first Jura Mountain ridge. Groundwater dating was performed with the ³H/³He dating method and supplemented by ⁸⁵Kr measurements. Stable isotope data (δ¹⁸O, δ²H) and dissolved noble gas concentrations allow the determination of the recharge temperature, which is correlated to the recharge elevation. Noble gas temperatures (NGT) decrease in the direction of groundwater flow and range from 10 to 13 °C in the upstream area of the town to 7–9 °C in the downstream river plain. This trend could suggest the admixture of water from the underlying limestone aquifer recharged under cooler infiltration conditions, e.g. at higher recharge elevations. However, it is shown in this study that the difference in NGT does not require such a recharge. Rather, increasing air temperatures over the last 40 years and the urban heat island effect could possibly explain most of the observed temperature shift. Furthermore, it is concluded that the downstream river plain is hydrologically disconnected from the upstream town area. Consequently most water from the town area is drained by the creek Witibach and recharge in the river plain is higher than previously assumed.     

Clean quartz matters for cosmogenic nuclide analyses: An exploration of the importance of sample purity using the CRONUS-N reference material

Reference materials are key for assessing inter-laboratory variability and measurement quality, and for placing analytical uncertainty bounds on sample analyses. Here, we investigate four years of data resulting from repeated processing of the CRONUS-N reference material for cosmogenic ¹⁰Be and ²⁶Al analyses. At University of Vermont, we prepared a CRONUS-N aliquot with most of our sample batches from 2013 to 2017; these reference material samples were then distributed to four different accelerator mass spectrometry facilities, yielding 73 ¹⁰Be analyses and 58 ²⁶Al analyses. We determine CRONUS-N ¹⁰Be concentrations of (2.26 ± 0.14) x 10⁵ atoms g⁻¹ (n = 73, mean, 1 SD) and ²⁶Al concentrations of (1.00 ± 0.08) x 10⁶ atoms g⁻¹ (n = 58, mean, 1 SD). We find a reproducibility of 6.3% for ¹⁰Be and 7.7% for ²⁶Al (relative standard deviations). We also document highly variable ²⁷Al and Mg concentrations and a ¹⁰Be dispersion twice as large as the mean AMS analytic uncertainty. Analyses of the CRONUS-N material with and without density separation demonstrate that non-quartz minerals are present in the material and have a large impact on measured concentrations of ²⁷Al, ¹⁰Be, and impurities; these non-quartz minerals represent only a very small portion of the total mass (0.6–0.8%) but have a disproportionally large effect on the resulting data. Our results highlight the importance of completely removing all non-quartz mineral phases from samples prior to Be/Al extraction for the determination of in situ cosmogenic ¹⁰Be and ²⁶Al concentrations.     

华南晋宁期造山运动──地质年代学和地球化学制约

综合了前人和作者最新的地质年代学和地球化学研究成果,对华南晚元古代晋宁期造山运动的演化提供了化学地球动力学制约晚元古代早期（0．97－1．0Ga）的皖南、赣东北和桂北蛇绿岩在元素地球化学上具有相似的岛弧特征,但它们的Nd同位素组成明显不同新获得的高精度结石U－Ph年龄资料表明,桂北地区的本洞、三防和元宝山等三个主要花岗岩岩体均形成于820-825Ma,排除了本区有中元古代晚期花岗岩的存在．扬子南缘中元古代到三叠纪各个时代地层中的泥质沉积岩的TDM在晚元古代早期从约1．8Ga急剧降低至约1．3Ga,反映了这个时期的沉积物源区有大量新生馒源物质的加入．根据研究资料,提出了华南和扬子块体晋宁期陆-弧-陆碰撞模式     

内蒙桌子山地区凝结水对岩溶地下水补给的探讨

内蒙古桌子山区为西北干旱地区,平均年降水量不足200mm。区内中、下奥陶统碳酸盐岩中岩溶水是当地重要供水水源。该区岩溶地下水氢氧同位素关系图表明,其样点基本分布在当地雨水线左上方,存在明显的反向“氧漂移”现象,这种现象在作者所见到我国北方多数岩溶泉域岩溶地下水的同位素分布是唯一的。通过本区特定的气候、水文地质条件以及自然条件分析认为,本区岩溶地下水中可能存在凝结水的补给,这一观点在2004年8月30日清晨的露水同位素取样分析后得到了进一步支持。      

15N示踪-离子质谱法测定新生产力的研究

本文提出了~(15)N示踪-离子质谱法实测新生产力的方法,并于1991年11月—1992年5月结合胶州湾现场调查的实际样品,对示踪剂量、培养时间、样品贮存、消解剂量和时间、铵离子的扩散吸收,以及方法的空白值、检出限、精密度和准确度等进行了实验研究。结果表明,该法具有较高的精密度和良好的准确度,与经典的气体质谱法相比,还具有进样量少以及可同时分析~(15)N丰度、总氮浓度和水中铵离子浓度等特点,对于含氮量极低、铵氮再生迅速的海洋环境中新生产力的研究,具有特殊的意义。     

Recent contributions to the standard Albian/Cenomanian boundary chronology from Hokkaido,Japan: A review for data reintegration and numerical age recalibration

The numerical age of the Albian/Cenomanian (A/C) boundary (=Early/Late Cretaceous Epoch boundary) has recently been updated using new radiometric dates from Hokkaido, Japan. Yet, an element of uncertainty still remains in the age scaling due to inaccurate chronostratigraphic contexts surrounding the tuff beds that have been geochronologically studied in the Oyubari and Soeushinai areas. To ensure stability in the Cretaceous time scale, this paper rigorously reevaluates the current status of Hokkaido A/C chronology, clarifying the limitations and making refinements via proper reintegration of published chronostratigraphic data. In the case of the Oyubari area, its A/C biostratigraphic scheme is limited by near-absence of ammonites and planktonic foraminifera at the Albian–Cenomanian transition, resulting in a large discrepancy in the proposed boundary levels based on these macro- and microfossil taxa. These problems can be solved by solid data integration aided by event- and δ¹³C-sratigraphy from the adjacent Ashibetsu area, wherein the A/C boundary is well documented by the superior planktonic foraminiferal record. Based on the resultant A/C boundary redefinition for the Oyubari area in conjunction with a simple linear interpolation from two published UPb ages, the A/C boundary age can be independently calibrated to be 100.8 Ma [with ±1.4 Myr uncertainty (=analytical precision)], which is consistent with that currently in use in the Geologic Time Scale 2012 (100.5 ± 0.4 Ma). In the case of the Soeushinai area, its chronostratigraphic framework is limited by rather complex geological structure and vertically/laterally variable lithologies. Moreover, the accuracy of geochronological data from this area is undermined by the fact that the dated tuff levels do not bracket the inferred A/C boundary.     

Chemical,isotopic and amino acid composition of Mukundpura CM2.0(CM1) chondrite: Evidence of parent body aqueous alteration

The carbonaceous chondrites are intriguing and unique in the sense that they are the only rocks that provide pristine records of the early solar nebular processes. We report here results of a detailed mineralogical, chemical, amino acid and isotopic studies of a recently observed fall at Mukundpura, near Jaipur in Rajasthan, India. Abundance of olivines in this meteorite is low and of serpentine minerals is high. FeO/SiO_2 = 1.05 in its Poorly Characterized Phases(PCP) is similar to that observed in other CM2.0 chondrites. The water content of ～9.8 wt.% is similar to that found in many other CM chondrites.Microscopic examination of matrix shows that its terrestrial weathering grade is WO but aqueous parent body alteration is high, as reflected in low abundance of identifiable chondrules and abundant remnants of chondrules(～7%). Thus, most of the chondrules formed initially have been significantly altered or dissolved by aqueous alterations on their parent bodies. The measured bulk carbon(2.3%) and nitrogen content and their isotopic(δ¹³C =-5.5‰, δ¹⁵N = 23.6%0) composition is consistent with CM2.0 classification probably bordering CM1. Several amino acids such as Alanine, Serine, Proline, Valine, Threonine,Leucine, Isoleucine, Asparagine and Histamine are present. Tyrosine and Tryptophan may occur in trace amounts which could not be precisely determined. All these data show that Mukundpura chondrite lies at the boundary of CM2.0 and CM1 type carbonaceous chondrites making it one of the most primitive chondrites.     

北祁连车路沟斑岩型金矿床含矿岩体年代学、地球化学与岩石成因

车路沟金矿是北祁连山发现的首例与斑岩有关的金矿床, 矿体产于加里东晚期侵入的中酸性斑岩体及其与围岩接触带内。为了查明含矿斑岩体侵位时代、岩石成因和源区性质, 本文以车路沟一带含矿斑岩体作为研究对象, 对其开展了岩石地球化学、LA-ICP-MS锆石U-Pb同位素定年和Hf同位素特征研究。该岩体主要由花岗闪长斑岩、石英闪长斑岩、英云闪长斑岩组成, 对花岗闪长斑岩、英云闪长斑岩进行了LA-ICP-MS锆石U-Pb同位素定年, 分别获得锆石²⁰⁶Pb/²³⁸U加权平均年龄为438.6±3.8Ma和433.0±3.8Ma, 指示岩浆侵位时代为早志留世晚期。岩石SiO₂含量为61.4%~68.6%, Al₂O₃含量为15.0%~16.7%, MgO含量为0.36%~2.95%, σ值介于1.20~2.03之间, A/CNK值为1.0~1.1之间, 属钙碱性系列准铝质花岗岩类; 具有弱负铕异常-正铕异常(δEu=0.90~1.18), 高Sr(319×10^-6~549×10^-6)含量和Sr/Y(36.6~77.5)比值, 低Y(7.09×10^-6~10.2×10^-6)和Yb(0.69×10^-6~0.89×10^-6)含量, 具有埃达克岩地球化学特征。该岩体的锆石ε_Hf(t)值均为正值, 变化于+12.7~+15.0之间, 两阶段模式年龄t_DM2(Hf)=461~563Ma, 推测岩浆源区可能主要来自新元古代晚期至寒武纪新生洋壳物质。研究认为车路沟斑岩体形成于陆陆碰撞后期, 地壳持续加厚, 诱发中新元古代晚期至寒武纪新生洋壳发生部分熔融, 形成埃达克质岩浆, 在其不断上侵和演化过程中, 形成车路沟斑岩体与其相伴产出的金矿体。

     

Lower crustal melting and the role of open-system processes in the genesis of syn-orogenic quartz diorite–granite–leucogranite associations: constraints from Sr–Nd–O isotopes from the Bandombaai Complex, Namibia

The Bandombaai Complex (southern Kaoko Belt, Namibia) consists of three main intrusive rock types including metaluminous hornblende- and sphene-bearing quartz diorites, allanite-bearing granodiorites and granites, and peraluminous garnet- and muscovite-bearing leucogranites. Intrusion of the quartz diorites is constrained by a U–Pb zircon age of 540±3 Ma.

Quartz diorites, granodiorites and granites display heterogeneous initial Nd- and O isotope compositions (_{Nd (540 Ma)}=−6.3 to −19.8; δ¹⁸O=9.0–11.6‰) but rather low and uniform initial Sr isotope compositions (⁸⁷Sr/⁸⁶Sr_initial=0.70794–0.70982). Two leucogranites and one aplite have higher initial ⁸⁷Sr/⁸⁶Sr ratios (0.70828–0.71559), but similar initial _Nd (−11.9 to −15.8) and oxygen isotope values (10.5–12.9‰). The geochemical and isotopic characteristics of the Bandombaai Complex are distinct from other granitoids of the Kaoko Belt and the Central Zone of the Damara orogen. Our study suggests that the quartz diorites of the Bandombaai Complex are generated by melting of heterogeneous mafic lower crust. Based on a comparison with results from amphibolite-dehydration melting experiments, a lower crustal garnet- and amphibole-bearing metabasalt, probably enriched in K₂O, is a likely source rock for the quartz diorites. The granodiorites/granites show low Rb/Sr (<0.6) ratios and are probably generated by partial melting of meta-igneous (intermediate) lower crustal sources by amphibole-dehydration melting. Most of the leucogranites display higher Rb/Sr ratios (>1) and are most likely generated by biotite-dehydration melting of heterogeneous felsic lower crust. All segments of the lower crust underwent partial melting during the Pan-African orogeny at a time (540 Ma) when the middle crust of the central Damara orogen also underwent high T, medium P regional metamorphism and melting. Geochemical and isotope data from the Bandombaai Complex suggest that the Pan-African orogeny in this part of the orogen was not a major crust-forming episode. Instead, even the most primitive rock types of the region, the quartz diorites, represent recycled lower crustal material.     

南海西部浮游有孔虫记录的MIS 3期表层海洋环境变化

对南海西部越南岸外上升流区17954-2站浮游有孔虫属种组合变化、浮游有孔虫氧同位素、AMS14C测年的分析以及浮游有孔虫表层海水温度、温跃层转换函数的研究结果表明:在MIS3期,南海西部表层海水温度大体呈现暖-冷-暖的变化趋势;温跃层深度由浅到深阶段性变化;短时间尺度上温度与温跃层发生幅度较大的快速变化。暖事件（IS）对应于浮游有孔虫暖水种、混合层属种含量的增加,冷水种、温跃层属种含量的减少以及冬夏SST的升高;冷事件则与之相反。表层海水生产力亦大致呈现3个阶段（61～51ka,51～42ka和42～32ka）的变化,在千年尺度的快速气候事件中,暖事件对应浮游有孔虫生产力属种含量降低,冷事件对应升高。此外,在MIS3内部分暖事件（IS6和IS11～13）表现出表层海水温度降低,温跃层深度变浅和表层海水生产力升高的状况,表明该区此时上升流的存在,其形成原因推测是由于东亚夏季风加强的结果。