中国云南哀牢山含海蓝宝石伟晶岩的起源和成岩模拟实验研究

The Ailaoshan aquamarine-bearing pegmatites are associated with Proterozoic metamorphic rocks in the southern portion of the Ailaoshan fault-folded complex.The gem-bearing pegmatite mineralization zones of the region occur in areas generally consistent with the regional tectonic trend.The pegmatites are found in metamorphic rocks,migmatites and in the inner/outer contact zones of gneissoid granites. The Rb-Sr isochron drawn for the pegmatites is 26～31 Ma,(i.e.in Himalayan).The homogenization temperatures of melt and liquid inclusions in minerals vary from 185 to 920℃,which are comparable to the inclusions observed in banded migmatites and ptygmatic quartz veins in the surrounding metamorphic rocks. The mineralization fluids of the pegmatite were rich in HCO_3 and CO_2,and their compositional assemblages are comparable to metamorphic fluids.Results of H,O,C,Si etc.isotopic analyses and REE,and Be analyses indicates that the sources of mineralization components that formed the pegmatites are closely associated with metamorphic fluids and the enclosing metamorphic rocks. A pegmatite structure simulation experiment was conducted at high temperature and pressure(840℃and 1,500×105Pa.),with various metamorphic rock samples in a water-rich and volatile-rich environment.When the liquidus was reached,the temperature was gradually decreased at the rate of 5～10℃/day over a time period of three months.SEM energy-dispersive spectrum analyses were performed on the experimental products.A series of pegmatoid textures were observed including zonal texture,megacryst texture,drusy cavities,crystal druses,and vesicular texture along with more than ten types of minerals including plagioclase,microcline,quartz and biotite.Different metamorphic rock melts generated different mineral assemblages.Experiment results revealed that the partial melting of metamorphic rocks could form melts similar to pegmatite magmas. Based upon the geological characteristics,geochemistry,and pegmatite texture simulation experimental results,it is concluded that the mineralization components of Ailaoshan aquamarine-bearing pegmatites came from metamorphic rocks.The petrogenetic model for the origin of pegmatites is related to ultrametamorphism and metamorphic anatexis.     

吉林省龙井市后底洞金矿床的成因探讨

后底洞金矿床是吉林省延边优地槽区一个与基性岩有关的典型矿床,通过研究其地质特征及矿床矿石的硫,氢氧同位素组成等,认为该矿床的物质来源及成矿热液来源是深部基性岩浆,矿床属中温岩浆热液型金矿床。     

普朗斑岩铜矿包裹体、同位素研究及成矿时代

普朗斑岩铜矿产于印支-燕山早期普朗复式斑岩体中。成矿流体来源广、盐度高,成矿温度从高温440℃到低温120℃,集中在160℃-240℃、280℃-320℃、340℃-380℃三阶段,多期次、多阶段性,与斑岩成矿作用特征一致。硫同位素3δ4SCDT‰T为（-2.23-3.75）‰,显示单一深源岩浆硫。岩体黑云母等40Ar-39Ar和矿石石英-辉钼矿Re-Os同位素年龄为206.4M a-213±3.8M a,属岛孤斑岩型铜矿床。     

Origin of high H2S concentrations in the Upper Permian Changxing reservoirs of the Northeast Sichuan Basin,China

Intense thermochemical sulfate reduction (TSR) and up to 18% H₂S are found in the Upper Permian Changxing Formation (P₃ch) in the northeast (NE) Sichuan Basin, China, despite that rare gypsum or anhydrite was found in this formation. Here, we present new concentration data of carbonate-associated sulfate (CAS) from carbonate host rocks, C, O, and Sr isotope data for TSR-related calcites, and S isotope data for sulfur compounds obtained during this study. These data along with spatial-temporal changes in palaeogeopressure conditions, hydraulic conductivity and the physical capacity indicate that the H₂S was generated locally from TSR within the P₃ch reservoirs. We propose that the reactive sulfates were derived from CAS released during dolomitization and recrystallization of earlier dolomite within the P₃ch Fm. and from the cross-formational migration of evaporative brines from the Lower Triassic Feixianguan Formation (T₁f) to P₃ch Fm. Our calculation shows that the two sources could provide enough SO₄²⁻ for the generation of H₂S within the P₃ch reservoirs. Early downward migration of sulfate-rich evaporative brines from the T₁f formation occurred in near-surface and shallow burial diagenetic settings (mainly <1000 m). The evaporative brines seeped into porous grainstones and displaced preexisting seawater, causing pervasive dolomitization within the P₃ch Fm. Subsequently, TSR calcites precipitated from the pore water have high Sr concentrations (up to 7767 ppm), close to the T₁f TSR calcites, and ⁸⁷Sr/⁸⁶Sr ratios mainly from 0.7074 to 0.7078, which are significantly higher than those of Late Permian seawater but within the range of early Triassic seawater.     

An analysis and comparison of observed Pleistocene South Carolina (USA) shoreline elevations with predicted elevations derived from Marine Oxygen Isotope Stages

Geological maps of South Carolina, covering > 6800 km², confirm the existence of eight preserved Pleistocene shorelines above current sea level: Marietta (+ 42.6 m), Wicomico (+ 27.4 m), Penholoway (+ 21.3 m), Ladson (+ 17.4 m), Ten Mile Hill (+ 10.7 m), Pamlico (+ 6.7 m), Princess Anne (+ 5.2 m), and Silver Bluff (+ 3 m). Current geochronologic data suggest that these eight shorelines correlate with Marine Oxygen Isotope Stages (MIS) as follows: Marietta—older than MIS 77; Wicomico—MIS 55–45; Penholoway—MIS 19 or 17; Ladson—MIS 11; Ten Mile Hill—MIS 7; Pamlico—MIS 5; Princess Anne—MIS 5; and Silver Bluff—MIS 5 or 3. Except for the MIS 5e Pamlico, and possibly the MIS 11 Ladson, the South Carolina elevations are higher than predicted by isotope proxy-based reconstructions. The < 4 m of total relief from the Pamlico to the Silver Bluff shoreline in South Carolina, for which other reconstructions suggest an expected relief of ~ 80 m, illustrates the lack of match. Our results suggest that processes affecting either post-depositional changes in shoreline elevations or the creation of proxy sea-level estimates must be considered before using paleo sea-level position on continental margins.     

11颗行星际尘粒中的锂,硼同位素丰度分析

我们首次测量了4颗行星际尘粒(IDPs)中的~6Li/~7Li,~(10)B/~(11)B。它们的平均值分别是(8.40±0.37)×10~(-2)和(2.40±0.18)×10~(-2),随后又精确测量了7颗IDPs~6Li/Li的同位素丰度。     

Lu–Hf constraints on pre-, syn,and post-collision associations of the Gurupi Belt,Brazil: Insights on the Rhyacian crustal evolution

The Gurupi Belt (together with the São Luís cratonic fragment), in north-northeastern Brazil, has been described in previous studies that used extensive field geology, structural analysis, airborne geophysics, zircon U–Pb dating, and whole-rock Sm–Nd isotope and geochemical data as a polyphase orogenic belt, with the Rhyacian being the main period of crust formation. This was related to a 2240 Ma to 2140 Ma accretionary processes that produced juvenile crust, which has subsequently been reworked during a collisional event at 2100 ± 20 Ma, with little evidence of Archean crust. In this study, we use Lu–Hf isotopic data in zircon from granitoids (including gneiss) of variable magmatic series, and amphibolite to improve the knowledge of this scenario, and investigate additional evidence of recycling of Archean basement. Pre-collisional high Ba-Sr and ferroan granitoids and amphibolite formed in island arc (2180–2145 Ma), show only zircons with suprachondritic εHf values (ca. +1 to +8) indicating the large predominance of juvenile magmas. Only 10% of the data show slightly negative εHf values (0 to ?4), which have been observed in granodiorite-gneiss formed in continental arc (2170–2140 Ma), and in strongly peraluminous collisional granites (2125–2070 Ma), indicating the rework of older Paleoproterozoic to Archean components (Hf_TDM = 2.11–3.69 Ga). A two-component mixing model using both Hf and published Nd isotope data are in line with this interpretation and indicate more than 90% of juvenile material, and less influence of Archean materials. Comparing with other Rhyacian terranes that are interpreted to have been close to Gurupi in a pre-Columbia configuration (ca. 2.0 Ga), our results differ from those of SE-Guiana Shield, which show strong influence of Archean protoliths, and are very similar to those of the central-eastern portion of the Baoulé-Mossi Domain of the West African Craton, which has also been formed largely by juvenile magmas in an accretionary-collisional orogen.     

δ34S isotope values of dissolved sulfate (SO4 2−) as a tracer for battery acid (H2SO4) contamination in groundwater

The application of sulfur isotope (³⁴S) values of sulfate in groundwater provided the information necessary to evaluate the source, transport and fate of battery acid and associated contaminants at the Gulf Coast Recycling (GCR) facility. The chemical and isotopic composition of groundwater beneath the (GCR) property, a battery recycling facility in east Tampa, Florida, varies more than expected for an area of comparable size. Sulfate (SO₄^2–) values, for example, range from 1.2 to 11,500 mg/L and oxygen and hydrogen isotopes do not attenuate towards the weighted annual mean. Those samples that are high in sulfate generally have a low pH, which immediately indicates battery acid (H₂SO₄) contamination as a potential source for the sulfate. The low pH and high reactivity of the sulfuric acid groundwater cause the formation of hydrogeological microenvironments due to preferential dissolution of carbonate minerals, which in turn causes enhanced recharge and groundwater flow in certain areas; thus, the extreme scatter in the data set. Because of the difficult hydrogeology it is not straightforward to delineate the point-sources of contamination and up to five potential scenarios have to be evaluated: (1) seawater intrusion, (2) upwelling of high-sulfate groundwater, (3) local dissolution of gypsum, (4) an up-gradient contaminant source to the northeast of the GCR property and (5) battery acid contamination.     

Scale of pluton/wall rock interaction near May Lake,Yosemite National Park,CA, USA

Interaction of magma with wall rock is an important process in igneous petrology, but the mechanisms by which interactions occur are poorly known. The western outer granodiorite of the Cretaceous Tuolumne Intrusive Suite of Yosemite National Park, California, intruded a variety of metasedimentary and igneous wall rocks at 93.1 Ma. The May Lake metamorphic screen is a metasedimentary remnant whose contact zone exhibits a variety of interaction phenomena including xenolith incorporation, disaggregation, and partial melting. The chemical contrast of these metasedimentary rocks with the invading pluton provides an excellent measure of pluton/wall rock interactions. Wall rock xenoliths (mostly pelitic quartzite) are predominantly located in an elongate horizon surrounded by a hybridized fine-grained granodiorite. Initial Sr and Nd isotopic ratios of the hybridized granodiorite indicate significant local incorporation of crustal material. Major- and trace-element geochemical data indicate that contamination of the granodiorite occurred via selective assimilation of both high-K and low-K, high-silica partial melts derived from pelitic quartzite. Although the hybridized granodiorite shows significant amounts of contamination, adjacent to xenoliths the proportion of contamination is undetectable more than a meter away. These results indicate that the chemical and isotopic variability of the Tuolumne Intrusive Suite is not caused by magma contamination via in situ wall rock assimilation.