鲁西枣庄-临沂地区新元古界震碛岩的主要特征

鲁西枣庄—临沂地区新元古界碳酸盐岩系中,发育有由地震造成的同沉积构造现象,如微晶方解石脉、层内变形褶曲、层内微断层和内碎屑碳酸盐岩堆积等。野外实地观察、地质剖面测量和室内分析研究认为它们是由地震产生的强震动,使距震中一定范围的未固结沉积物经震动液化,震动变形形成的震积岩组合。根据其发育规律与组合特征,该地区震碛岩的形成应与古郯庐断裂在新元古代的活动密切相关。可初步确定为含有A、B和C3个震积岩单元的震动液化地震序列。     

渤海湾盆地济阳坳陷潜山油藏分布规律及控制因素

济阳坳陷潜山油藏类型复杂,构造裂缝是油藏的主要储集空间。济阳坳陷潜山储层的分布主要受控于盆地的形成过程,构造运动是控制潜山分布的最主要的因素。潜山储层非均质性强,且不同潜山的储层性质存在较大差异。济阳坳陷潜山油藏的开发特征复杂,稳产阶段短、产能差异大、含水上升快。中生代及以前形成的古地貌早隆潜山是济阳坳陷最有利的潜山油藏勘探目标。      

Adding the missing third and fourth dimensions to trajectory analysis in carbonate systems

We developed a seismic geomorphology-based procedure to enhance traditional trajectory analysis with the ability to visualize and quantify lateral variability along carbonate prograding-margin types (ramps and rimmed shelves) in 3D and 4D. This quantitative approach analysed the shelf break geometric evolution of the Oligo-Miocene carbonate clinoform system in the Browse Basin and delineated the feedback between antecedent topography and carbonate system response as controlling factor on shelf break rugosity. Our geometrical analysis identified a systematic shift in the large-scale average shelf break strike direction over a transect of 10 km from 62° to 55° in the Oligo-Miocene interval of the Browse Basin, which is likely controlled by far-field allogenic forcing from the Timor Trough collision zone. Plotting of 3D shelf break trajectories represents a convenient way to visualize the lateral variability in shelf break evolution. Shelf break trajectories that indicate contemporaneous along-strike progradation and retrogradation correlate with phases of autogenic slope system re-organization and may be a proxy for morphological stability of the shelf break. Shelf break rugosity and shelf break trajectory rugosity are not inherited parameters and antecedent topography does not dictate long-term differential movement of the shelf margin through successive depositional sequences. The autogenic carbonate system response to antecedent topography smooths high-rugosity areas by filling accommodation and maintains a relatively constant shelf break rugosity of ~150 m. Color-coding of the vertical component in the shelf break trajectory captures the creation and filling of accommodation, and highlights areas of the transect that are likely to yield inconsistent 2D sequence stratigraphic interpretations.     

全球主要河流流域碳酸盐岩风化碳汇评估

碳酸盐岩风化吸收的大气CO₂主要以HCO₃ ^-形式连续地经由河流从大陆输送到海洋,成为陆地生态系统的重要碳汇。目前主要河流流域的碳酸盐岩风化碳汇估算存在不确定性,分布格局尚不清晰。基于GEMS-GLORI全球河流数据库提供的全球10万km ²以上主要河流流域多年平均监测数据,利用水化学径流法估算出全球主要河流流域碳酸盐岩对CO₂的吸收速率为0.43±0.15 Pg CO₂ yr ^-1,平均CO₂吸收通量为7.93±2.8 t km ^-2 yr ^-1。CO₂吸收通量在不同气候带下差异显著,热带和暖温带CO₂年吸收速率占全球主要河流流域年吸收速率的62.95%。冷温带CO₂年吸收速率占全球主要河流流域的33.05%,仅次于热带地区。本文划分出全球CO₂吸收通量的9个关键带,关键带的交汇处CO₂吸收通量较高。喀斯特出露流域碳酸盐岩对CO₂吸收通量的均值为8.50 t km ^-2 yr ^-1,约为非喀斯特流域的3倍。全球喀斯特出露流域碳酸盐岩风化碳汇在全球碳循环、水循环及碳收支平衡估算研究方面占据重要地位。     

再探温跃层有孔虫B/Ca与温度和[CO32-]的依赖性及其在24 ka以来热带西太平洋次表层碳酸盐系统重建中的应用

The B/Ca ratio of planktonic foraminifer shells has been used as a proxy for reconstructing past ocean carbonate chemistry. However, recent studies have revealed significant uncertainties associated with this proxy, such as whether seawater temperature or [ CO_3~(2-)] is the dominant control on the partition coefficient(K_D) of planktonic foraminiferal B/Ca. To address these uncertainties and thus improve our understanding of the planktonic foraminiferal B/Ca proxy, we analysed B/Ca ratios in the tests of Neogloboquadrina dutertrei(300–355 μm) and Pulleniatina obliquiloculata(355–400 μm) in surface sediment samples from the tropical western Pacific and South China Sea. The relationship between these B/Ca ratios and bottom water calcite saturation states(Δ[ CO_3~(2-)]) is weak, thus suggesting only a small dissolution effect on the B/Ca of the two species. The correlation coefficients(R~2) between the B/Ca ratios of N. dutertrei and P. obliquiloculata and environmental parameters(e.g., temperature, salinity, phosphate, DIC and ALK) in the tropical western Pacific and South China Sea are not high enough to justify using B/Ca ratios as a palaeoenvironmental proxy in the study areas. The significant correlation between K_D values of N. dutertrei and P. obliquiloculata and carbonate system parameters(e.g.,[ CO_3~(2-)], DIC, ALK, pH and [ HCO_3~-]) in the study area reflect chemical links between the K_D denominator and these variables. Based on our surface sediment calibration, an empirical relationship between the K_D of N.dutertrei and temperature is proposed in the tropical western Pacific. We also generated a record of B/Ca ratios in N. dutertrei(300–355 μm) from Core MD06-3052 in the tropical western Pacific over the past 24 ka to evaluate the application of the revised B/Ca proxy method. Based on the reconstructed empirical relationship for B/Ca and subsurface seawater ALK, we estimated subsurface seawater carbonate system parameters in the tropical western Pacific since 24 ka. In general, the estimated subsurface seawater pH and [ CO_3~(2-)] show an increase with time, and the record of subsurface seawater pCO_2 shows a decrease with time, in the tropical western Pacific over the past 24 ka. The consistent trends in subsurface seawater pCO_2 and opal flux during deglaciation may imply that the reported increase in subsurface water pCO_2 in the study area was promoted by enhanced upwelling in the Southern Ocean.     

中国西南典型地质背景区土壤重金属分布及生态风险特征

中国西南有22.3％的耕地重金属含量超标,区内广泛分布的峨眉山玄武岩和碳酸盐岩被认为是土壤中重金属的主要母质来源.目前,中国西南地区,尤其是峨眉山玄武岩分布区土壤重金属生态风险的研究程度仍有待提升,不同地质背景区(成土母岩)土壤中重金属含量、空间分布与生态风险缺乏对比.本文选择四川省典型地质背景区采集土壤样品,采用原子...     

南海东沙东北部甲烷缺氧氧化作用的生物标志化合物及其碳同位素组成

南海东沙东北部碳酸盐岩和泥质沉积物中的生物标志化合物组合及其碳同位素组成分析表明,研究区内甲烷缺氧氧化作用(anaerobic oxidation of methane-AOM)发育.研究区内碳酸盐岩中含丰富的AOM标志化合物,2,6,11,15-四甲基十六烷(Crocetane-Cr.)、2,6,10,15,19-五甲基番茄烷(Pentamethylicosane-PMI)和2,6,10,15,19,23-六甲基二十四烷(Squalane-Sq角鲨烷)的13C亏损强烈(δ13C值介于-74.2‰~-119.0‰PDB之间),表明碳酸盐岩形成于AOM,同时反映该研究区曾发生过强烈、持续的富CH₄流体释放活动.柱状泥质沉积物中,AOM生物标志化合物在硫酸岩-甲烷过渡带(SMI-Sulfate-Methane Interface)边界附近相对丰度高,SMI之上样品中含量低,或未检出,表明现代环境在SMI附近有大量嗜甲烷微生物生长,使得深部上升的甲烷被大量消耗,很少有甲烷逸出海底.AOM生物标志化合物可用来指示SMI边界.不同站位、不同岩性AOM生物标志化合物组成(包括碳同位素组成)的差异反映了嗜甲烷古细菌组成的不同.     

Sedimentary facies,production rates and facies models for recent coralline algal gravels,Co. Galway,Ireland

Five sedimentary facies are described from SCUBA diving examination and sampling of Mannin Bay, Ireland. A Bank facies is built up by the unattached coralline algae Lithothamnium corallioides and Phymatolithon calcareum. This autochthonous facies occurs in shallow sheltered environments. In exposed areas a rippled Clean Algal Gravel facies is found composed of coralline and molluscan debris. In intermediate energy areas a Muddy Algal Gravel facies is found with small amounts of live corallines. Sheltered creeks have a Mud facies which is partly carbonate and partly terrigenous. The shallow water coralline algal sediments are overlapped by a Fine Sand facies of mixed biogenic composition. Each facies is characterized by particular phenotypic growth forms of the unattached corallines. Rates of organic calcium carbonate production are obtained which are found to be similar to rates from shallow tropical non-reef environments. The carbonate sediments of Mannin Bay are compared with similar sediments from Kilkerrin Bay. Ireland, from Brittany and from Falmouth Harbour. From these comparisons, facies models are proposed for these carbonate sediments. The major factor controlling facies distribution is coastal morphology. The present day shelf is considered to be too exposed to preserve complete sequences of the shallow water sediments.     

琉球群岛东部海区表层沉积物中浮游有孔虫分布及指示意义

对琉球群岛东部海区123个表层沉积物样品中浮游有孔虫因子分析结果表明,浮游有孔虫组合在溶跃面以上表现为Globigerinoides ruber-Globigerinata glutinata组合,溶跃面以下为Globorotalia inflata-Neoglobo-quadrina pachyderma (dex.)组合,局部受黑潮影响区域黑潮标志种Pulleniatina obliquiloculata含量相对丰富,为Neogloboquadrina dutertrei-P.obliquiloculata组合;表层沉积物中浮游有孔虫的丰度及组合分布特征对于碳酸盐溶跃面深度及碳酸盐补偿深度有一定的指示意义。另外,碳酸盐保存特征研究表明,该区域现代碳酸盐溶跃面深度约为3100 m,碳酸盐补偿深度约为4300 m。