大兴安岭西坡二道河子铅锌矿床硫化物Rb-Sr、锆石U-Pb年龄及其对构造背景的制约

二道河子铅锌矿床位于额尔古纳地块得尔布干成矿带的中段,地处大兴安岭西坡。为有效限制该矿床的成矿时代,对硫化物Rb-Sr年龄和安山玢岩锆石U-Pb年龄开展研究得出：该矿床的内生成矿作用共经历了3个成矿阶段：石英-黄铁矿阶段(Ⅰ)、石英-多金属硫化物阶段(Ⅱ)和石英-方解石-黄铁矿阶段(Ⅲ),其中石英-多金属硫化物阶段是主要的矿化阶段;Ⅲ号矿带主成矿阶段5件闪锌矿和3件黄铁矿的Rb、Sr含量分别为0.081×10-6~2.632×10-6和0.661×10-6~3.186×10-6,Rb-Sr同位素等时线年龄为140.8±2.3 Ma,(87Sr/86Sr)i值为0.71025~0.71205;与矿体平行、局部切穿矿体的安山玢岩脉的锆石U-Pb年龄为138.8±1.7 Ma。上述结果表明,二道河子矿床为热液脉状铅锌矿床,形成于早白垩世,与次火山岩(安山玢岩)热事件相近。结合前人研究成果,推测成矿与安山质岩浆作用有关,形成于蒙古-鄂霍茨克洋闭合后的伸展环境。     

Determination of the Platinum-Group Elements and Gold in Twenty Rock Reference Materials by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) after Pre-Concentration by Nickel Sulfide Fire Assay

The platinum-group elements (PGE) and gold have been determined in twenty international rock reference materials by inductively coupled plasma-mass spectrometry (ICP-MS) after pre-concentration by a nickel sulfide fire assay. It was possible to achieve determination limits for a 50 g sample that ranged from 1 pg g^-1 (Rh) to 23 pg g^-1 (Au). Compared to published certified and recommended values for rock reference materials, the trueness of the method was found to be good. However, in some cases we observed large deviations for all elements in the sub 10 ng g^-1 range within individual reference sample splits. Our results show that the PGE and Au are inhomogeneously distributed in the reference materials analysed here, where they are present in low concentrations, using 50 g test portions.     

Expected and observed conditions during the SAGE iron addition experiment in Subantarctic waters

The SAGE iron addition experiment was conducted from R.V. Tangaroa east of South Island, New Zealand, in late March-early April 2004. A desktop survey of climatological data was completed before the experiment, providing information to inform site selection and experiment design. The desktop survey is presented here in updated and enhanced form in order to explain the site selection and describe the conditions expected at the site during the experiment in comparison with those actually encountered.The experiment site was in Subantarctic waters between the Subtropical and Subantarctic Fronts. These waters are characterised by high surface macronutrient concentration, low iron concentration and low chlorophyll. The preferred site based on the desktop survey was in the vicinity of 173.5°E, 47.5°S, in Southern Bounty Trough. The actual release location was chosen immediately before the release and was 112 km to the northwest of this at 172°32′E, 46°44′S. The surface water here has typically come from the southwest (over the northern Campbell Plateau) or the southeast (through Pukaki Gap) and the mean current is directed towards ENE at ∼0.1 m s⁻¹. The release location is well removed from regions of high eddy kinetic energy to the east (where the Subantarctic Front reaches its northern limit) and the west (where fine-scale instabilities develop on the Southland Front, which flows along the continental shelf). Typical conditions at the release site at the end of March are: surface temperature 12 °C; mixed layer depth 40 m; surface chlorophyll concentration ∼0.3 mg m⁻³; surface photosynthetically active radiation (PAR) 23 E m⁻² d⁻¹; surface nutrient concentrations 8-10 mmol m⁻³ (nitrate), 0.5-0.8 mmol m⁻³ (phosphate), 1-2 mmol m⁻³ (silicate) and 0.1-0.5 nM (iron); 99th percentile wind speed 19-21 m s⁻¹. At this time of year, surface PAR is well below its summer maximum, the mixed layer is beginning its seasonal deepening and the silicate concentration is at its seasonal minimum. These factors may have limited the phytoplankton response to iron addition and were compounded in March-April 2004 by strong winds early in the experiment (substantially exceeding the 99th percentile in speed), lower than the average SST, larger than the average mixed layer depth, silicate concentration at the bottom end of the expected range and initially low PAR.     

Dissolved iron in the Australian sector of the Southern Ocean (CLIVAR SR3 section): Meridional and seasonal trends

We report measurements of dissolved iron (dFe, <0.4 μm) in seawater collected from the upper 300 m of the water column along the CLIVAR SR3 section south of Tasmania in March 1998 (between 42°S and 54°S) and November–December 2001 (between 47°S and 66°S). Results from both cruises indicate a general north-to-south decrease in mixed-layer dFe concentrations, from values as high as 0.76 nM in the Subtropical Front to uniformly low concentrations (<0.1 nM) between the Polar Front and the Antarctic continental shelf. Samples collected from the seasonal sea-ice zone in November–December 2001 provide no evidence of significant dFe inputs from the melting pack ice, which may explain the absence of pronounced ice-edge algal blooms in this sector of the Southern Ocean, as implied by satellite ocean-color images. Our data also allow us to infer changes in the dFe concentration of surface waters during the growing season. South of the Polar Front, a comparison of near-surface with subsurface (150 m depth) dFe concentrations in November–December 2001 suggests a net seasonal biological uptake of at least 0.14–0.18 nM dFe, of which 0.05–0.12 nM is depleted early in the growing season (before mid December). A comparison of our spring 2001 and fall 1998 data indicates a barely discernible seasonal depletion of dFe (0.03 nM) within the Polar Frontal Zone. Further north, most of our iron profiles do not exhibit near-surface depletions, and mixed-layer dFe concentrations are sometimes higher in samples from fall 1998 compared to spring 2001; here, the near-surface dFe distributions appear to be dominated by time-varying inputs of aerosol iron or advection of iron-rich subtropical waters from the north.     

深海6000 m拖曳式瞬变电磁系统及其应用

针对我国西南印度洋合同区热液硫化物矿快速、有效以及便捷地质勘探装备的要求,研发了由甲板控制系统、万米光电复合缆、仪器舱拖体和天线拖体组成的深海6000 m拖曳式瞬变电磁系统.为了便于拖体布放和快速发现异常,选择重叠回线收发装置类型;采用理论数值计算确定了在拖曳高度不大于50 m的前提下,观测1~100 ms窗范围内的二次场响应,可以发现近海底深海热液硫化物矿堆;另外,通过不同拖延深度海上试验,研究了拖曳深度对瞬变电磁的影响规律及仪器性能.大洋第30航次第二航段在西南印度洋脊热液区,应用该系统发现了明显的瞬变电磁异常.印证了系统的有效性.

     

Stratigraphic Correlation of the Malusok Volcanogenic Massive Sulfide Deposits, Southern Mindanao, Philippines

Abstract: Two adjacent volcanogenic massive sulfide (VMS) deposits, the Main Malusok and the Malusok Southeast, are delineated within Barangay Tabayo, Siocon, Zamboanga del Norte, Mindanao, Philippines. These deposits comprise massive to semi-massive sulfide lenses representing the down-dip equivalent of oxidized gossans. The massive sulfides have a primary mineral assemblage of pyrite-chalcopyrite-sphalerite with significant amounts of supergene copper in the form of chal-cocite. Owing to structural and metamorphic overprinting combined with intense alteration, primary textures are generally obliterated. Rock types are classified according to dominant mineral assemblages whereas the main lithologic units comprising the Malusok volcanic package are divided based on the position of each unit relative to the mineralized zone. The main lithologic units are designated as the hanging wall, the host, and the footwall sequences. In correlating the stratigraphy of the Main Malusok zone with that of the Malusok Southeast zone, a chlorite/epidote-rich interval located at the base of the hanging wall sequence serves as a distinct stratigraphic marker from which all lithologies are referred to. Comparisons between the stratigraphy of the two areas show that massive to semi-massive sulfide lenses are confined within a single stratigraphic interval representing the favorable horizon for the entire Malusok area. However, differences exist relative to style of mineralization and configuration of the altered interval between the Main Malusok and the Malusok Southeast VMS deposits. Based on characteristics exhibited by each individual deposit, it is inferred that the Main Malusok VMS deposit overlies a feeder zone whereas the Malusok Southeast sulfide lenses represent satellite deposits and transported blocks.     

我国一些铜镍硫化物矿床主要金属矿物的特征

镍、铜共生的铜镍硫化物矿床是镍矿也是铜矿的重要矿床类型。磁黄铁矿，镍黄铁矿、黄铜矿是这类矿床的主要金属矿物。它们的某些矿物学特征，特别是微量元素Ｃｏ／Ｎｉ比值，与其他铜矿类型明显不同，这三种矿物组成不同于任何其他铜矿类型的典型矿物共生组合， 形成特殊的海绵损铁状、球滴状构造。     

Studies on the Tolerating Mechanism for Sulfide in Urechis Unicinctus (Echiura:Urechidae)-cytological observation on Urechis Unicinctus in Different Hydrogen Sulfide Environment

This study on the cytological changes of the body wall ,aspiratory intestine and crissal bursa in Urechis unicincuts by light microscope(LM) and transmission electron microscope(TEM) showed that the difference between the body wall and the natural environment rich in H2S was not obvious,that the wall color of the aspiratory intestine in H2S rich environment changed from normal semitransparency to dark brown.that its epithelia were disassembled and the electron density of its cytoplasm matrix was lower;and that in H2S rich environment many basoplhilic granules occurred in the epithelia of the crissal bursa.Granules with single membrane and myelinefingure were found with TEM.