大别地体超高压变质岩石锆石Lu-Hf同位素研究

对大别山南部超高压变质带双河和黄镇地区的榴辉岩、片麻岩和硬玉石英岩中变质锆石进行了原位LA-MC-ICP- MS的Lu-Hf同位素分析。双河和黄镇的榴辉岩及双河的硬玉石英岩有低~(176)Lu/~(177)Hf和低~(176)Hf/~(177)Hf组成,两地的片麻岩有高~(176)Hf/~(177)Hf比和高且分散的~(176)Lu/~(177)Hf组成。锆石Hf同位素分布主要受变质原岩的形成时代控制,增生锆石基本上继承了原岩锆石的Hf同位素特征,既有增生锆石相对有低~(176)Lu/~(177)Hf和高~(176)Hf/~(177)Hf、继承重结晶锆石相对有高~(176)Lu/~(177)Hf和低~(176)Hf/~(177)Hf的特征,也有二者相互重叠没有区别的,它主要受原岩性质和变质过程中锆石遭受的溶蚀程度控制。增生锆石的低Lu/Hf是锆石在变质过程中Lu含量下降和Hf含量增高造成的,增生锆石的高~(176)Hf/~(177)Hf继承自岩石中其它高Lu/Hf比矿物的长期演化。继承锆石的初始Hf同位素组成ε_(Hf)值和亏损地幔模式年龄T_(DM)示踪表明,各超高压变质原岩的时代和成因是复杂的:双河榴辉岩原岩物质源自25亿年的亏损地幔和至少27亿年以上的古老晚太古地壳混合。双河片麻岩原岩年龄相同,但有不同的壳幔混合物源。黄镇榴辉岩原岩主要源于亏损幔源岩浆形成的初生地壳的重循环,很少的地壳混染。黄镇片麻岩和榴辉岩的物源区年龄相同。两地片麻岩原岩物源主要来自弱亏损地幔,存在古老地壳物质和地幔物质的混合。大别地区超高压变质岩锆石的Lu-Hf同位素特征主要反映了7～8亿年和18～19亿年时扬子克拉通北缘地区的岩浆活动特点和大地构造环境。     

Age constraints on the evolution of the Austroalpine basement to the south of the Tauern Window

The Austroalpine basement to the south of the Tauern Window once was part of the northern margin of Gondwana. It includes the “Altkristallin” and the phyllitic Thurntaler Complex. In the Altkristallin (AMU, MPU), suites of arc-related metamafic sequences occur together with calc-alkaline metagranite. SHRIMP U–Pb dating of zircon from calc-alkaline metagranite associated with an eclogitic amphibolite give an age of 470 ± 3 Ma interpreted as the age of protolith emplacement. In the Thurntaler Complex, metaporphyroids occur together with tholeiitic as well as alkaline within-plate basalt-type metabasite. The metaryholites of this association give a crystallization SHRIMP age of 477 ± 4 Ma, which suggests contemporaneity of arc-related and extensional settings in the Austroalpine basement units. The age data demonstrate widespread magmatic activity associated with the Early-Ordovician amalgamation at the end of the 550–470 Ma subduction–accretion–collision cycle. The Pb–Pb and U–Pb systematics of step-wise leached staurolite and kyanite from the peak-metamorphic assemblage of the Altkristallin indicate that (1) step-wise leaching of staurolite and kyanite yields the age of inclusions rather than the host; (2) zircon inclusions in staurolite suggest an Ordovician or older age for the precursor of the staurolite-schists; (3) the weighted average of the ²⁰⁶Pb/²³⁸U data of the various leaching steps yields a Variscan age for the inclusions (ilmenite, biotite, and andesine). Since these inclusions are part of the metamorphic mineral assemblage, this age provides a minimum estimate for staurolite growth, i.e., metamorphism. Thus, the Pb–Pb and U–Pb systematics of staurolite provide evidence for a Variscan metamorphism of the Austroalpine basement, e.g., MPU, AMU and Thurntaler Complex, to the south of the Tauern Window.     

非保守元素在苏鲁超高压榴辉岩退变质作用中有限迁移和近原地重新分布

中国大陆科学钻探工程主孔揭露的基性岩石包括新鲜榴辉岩和角闪岩.角闪岩是榴辉岩在折返过程中不同程度退变质作用的产物.全岩主量和痕量元素地球化学数据表明它们不仅在高场强元素(Ti,Zr,Nb,Ta),而且在高度活动元素(Rb,Cs,Sr,Ba)上化学特征相似.尽管从榴辉岩向角闪岩的退变质作用需要流体的参与,上述地球化学特征表明在榴辉岩快速折返过程中,流体仅仅有限地存在,在流体中高度活动的碱性元素仅作有限迁移和近乎原地重新分布.流体可能以高度局域化的管道流形式出现,是导致榴辉岩退变质作用和剪切变形高度局域化的主要因素.     

Variations in the transient prograde geothermal gradient from chloritoid-staurolite equilibria: a case study from the Barrovian and Buchan-type domains in the Bohemian Massif

Thermodynamic modelling of metamorphic rocks increases the possibilities of deciphering prograde paths that provide important insights into early orogenic evolution. It is shown that the chloritoid–staurolite transition is not only an indicator of temperature on prograde P–T paths, but also a useful indicator of pressure. The approach is applied to the Moravo‐Silesian eastern external belt of the Bohemian Massif, where metamorphic zones range from biotite to staurolite‐sillimanite. In the staurolite zone, inclusions of chloritoid occur in garnet cores, while staurolite is included at garnet rims and is widespread in the matrix. Chloritoid X_Fe = 0.91 indicates transition to staurolite at 5 kbar and 550 °C and consequently, an early transient prograde geothermal gradient of 29 °C km^?1. The overall elevated thermal evolution is then reflected in the prograde transition of staurolite to sillimanite and in the achievement of peak temperature of 660 °C at a relatively low pressure of 6.5 kbar. To the south and to the west of the studied area, high‐grade metamorphic zones record a prograde path evolution from staurolite to kyanite and development of sillimanite on decompression. Transition of chloritoid to staurolite was reported in two places, with chloritoid X_Fe = 0.75–0.80, occurring at 8–10 kbar and 560–580 °C, and indicating a transient prograde geothermal gradient of 16–18 °C km^?1. These data show variable barric evolutions along strike and across the Moravo‐Silesian domain. Elevated prograde geothermal gradient coincides with areas of Devonian sedimentation and volcanism, and syn‐ to late Carboniferous intrusions. Therefore, we interpret it as a result of heat inherited from Devonian rifting, further fuelled by syntectonic Carboniferous intrusions.     

Kyanite deformation in whiteschist of the ultrahigh-pressure metamorphic Kokchetav Massif, Kazakhstan

Microstructures in minerals from ultrahigh‐pressure metamorphic (UHPM) terranes are keys to understanding the rheological properties and the exhumation mechanisms of rocks from subduction zones. Kyanite‐bearing whiteschist, associated with eclogite lenses, is part of UHPM unit II located south‐west of Lake Zheltau in the Kulet region of the Kokchetav Massif. The equilibrium assemblage is kyanite + garnet + talc + phengite + coesite/quartz. Previously reported peak pressure–temperature (P–T) conditions are ～3.5 GPa at 750 °C. A strong foliation is defined by the talc and phengite, with a corresponding weak shape preferred alignment of kyanite. Crystallographic orientation maps and analysis of kyanite blades were performed using electron backscatter diffraction methods. The data are consistent with a (100)[001] slip system for the formation of undulose extinction and kink bands in kyanite. Rotations measured across individual kink bands are 10–50° about <010>, and rotations along kyanite with undulose extinction are up to 50° about <010> with variations between adjacent points typically <2°. The undulose extinction is interpreted to have developed through crystal plastic deformation by dislocation creep. Kink bands mark the development of high‐angle grain boundaries by dislocation climb. The deformation of kyanite occurred in the fault‐bounded terrane during the exhumation of the Kokchetav Massif.     

Rock relationships in the Mogok metamorphic belt, Tatkon to Mandalay, central Myanmar

The Mogok metamorphic belt (MMB), over 1450 km long and up to 40 km wide, consists of regionally metamorphosed rocks including kyanite and sillimanite schists and granites lying along the Western margin of the Shan Plateau in central Myanmar and continuing northwards to the eastern Himalayan syntaxis. Exposures in quarries allow correlation of Palaeozoic meta-sedimentary, early Mesozoic meta-igneous and late Mesozoic intrusive rocks within a 230 km long northerly-trending segment of the MMB, from Tatkon to Kyanigan north of Mandalay, and with the Mogok gemstone district 100 km to the northeast. Relationships among the metamorphic and intrusive rocks, with sparse published radiometric age controls, indicate at least two metamorphic events, one before and one after the intrusion of Late Jurassic to early Cretaceous calc-alkaline rocks. These relationships can be explained by either of two possible tectonic histories. One, constrained by correlation of mid-Permian limestones across Myanmar, requires early Permian and early Jurassic regional metamorphic events, prior to an early Tertiary metamorphism, in the western part of but within a Shan-Thai – western Myanmar block. The second, not compatible with a single laterally continuous Permian limestone, requires pre-Upper Jurassic regional metamorphism and orogenic gold mineralization in the Mergui Group and western Myanmar, early Cretaceous collision of an east-facing Mergui-western Myanmar island arc with the Shan Plateau, and early Tertiary metamorphism in the MMB related to reversal in tectonic polarity following the arc-Plateau collision.     

Geology of the Gorny Altai subduction–accretion complex, southern Siberia: Tectonic evolution of an Ediacaran–Cambrian intra-oceanic arc-trench system

The Gorny Altai region in southern Siberia is one of the key areas in reconstructing the tectonic evolution of the western segment of the Central Asian Orogenic Belt (CAOB). This region features various orogenic elements of Late Neoproterozoic–Early Paleozoic age, such as an accretionary complex (AC), high-P/T metamorphic (HP) rocks, and ophiolite (OP), all formed by ancient subduction–accretion processes. This study investigated the detailed geology of the Upper Neoproterozoic to Lower Paleozoic rocks in a traverse between Gorno-Altaisk city and Lake Teletskoy in the northern part of the region, and in the Kurai to Chagan-Uzun area in the southern part. The tectonic units of the studied areas consist of (1) the Ediacaran (=Vendian)–Early Cambrian AC, (2) ca. 630 Ma HP complex, (3) the Ediacaran–Early Cambrian OP complex, (4) the Cryogenian–Cambrian island arc complex, and (5) the Middle Paleozoic fore-arc sedimentary rocks. The AC consists mostly of paleo-atoll limestone and underlying oceanic island basalt with minor amount of chert and serpentinite. The basaltic lavas show petrochemistry similar to modern oceanic plateau basalt. The 630 Ma HP complex records a maximum peak metamorphism at 660 °C and 2.0 GPa that corresponds to 60 km-deep burial in a subduction zone, and exhumation at ca. 570 Ma. The Cryogenian island arc complex includes boninitic rocks that suggest an incipient stage of arc development. The Upper Neoproterozoic–Lower Paleozoic complexes in the Gorno-Altaisk city to Lake Teletskoy and the Kurai to Chagan-Uzun areas are totally involved in a subhorizontal piled-nappe structure, and overprinted by Late Paleozoic strike-slip faulting. The HP complex occurs as a nappe tectonically sandwiched between the non- to weakly metamorphosed AC and the OP complex. These lithologic assemblages and geologic structure newly documented in the Gorny Altai region are essentially similar to those of the circum-Pacific (Miyashiro-type) orogenic belts, such as the Japan Islands in East Asia and the Cordillera in western North America. The Cryogenian boninite-bearing arc volcanism indicates that the initial stage of arc development occurred in a transient setting from a transform zone to an incipient subduction zone. The less abundant of terrigenous clastics from mature continental crust and thick deep-sea chert in the Ediacaran–Early Cambrian AC may suggest that the southern Gorny Altai region evolved in an intra-oceanic arc-trench setting like the modern Mariana arc, rather than along the continental arc of a major continental margin. Based on geological, petrochemical, and geochronological data, we synthesize the Late Neoproterozoic to Early Paleozoic tectonic history of the Gorny Altai region in the western CAOB.     

Noble metal mineralization in carbonaceous rocks: A synthesis of data on the Russian Far East

The relationship between noble metal mineralization and carbonaceous rocks (black shales and brown coals) is considered. We have confirmed the previous conclusions of multistage syn- and epimetamorphic formation of gold-bearing deposits in black shales and syn- and epigenetic accumulation of noble metals in brown coals. The gold and PGE in the brown coals of the Verkhnii Amur region and Primorye were presumably derived by disintegration of adjacent ore sources in the Cenozoic. Addition studies and sampling are required at the coal and graphite objects of the Russian Far East to solve this problem.     

Metamorphism of the Central Anatolian Crystalline Complex, Turkey: influence of orogen-normal collision vs. wrench-dominated tectonics on P–T–t paths

The Central Anatolian Crystalline Complex (CACC) is a microcontinent in the Alpine–Himalayan belt. It has previously been considered as a coherent structural entity, but, although the entire CACC is comprised of similar rocks (primarily metasedimentary rocks and granitoids), it consists of at least four tectonic blocks characterized by different P–T–t paths. These blocks are the K?r?ehir (north‐west), Akda? (north‐east), Ni?de (south) and Aksaray (west) massifs. The northern massifs experienced thrusting and folding during collision and were slowly exhumed by erosion; metamorphic rocks are characterized by clockwise P–T paths at moderate P–T and local low‐P–high‐T (LP–HT) overprinting in the highest grade rocks. Apatite fission track ages are Eocene to Oligocene (47–32 Ma). The Aksaray block represents the hot, shallow mid‐crust of a Late Cretaceous–early Tertiary arc. It is dominated by intrusions; rare metapelitic rocks record low‐P (< 4 kbar) regional metamorphism overprinted by LP–HT contact metamorphism. Apatite fission track ages are 50–45 Ma. The Ni?de massif is different from the other CACC blocks because it evolved as a core complex in a wrench‐dominated setting. It is characterized by clockwise P–T paths at moderate P–T followed by widespread LP–HT metamorphism. Apatite fission track ages are Miocene (12–9 Ma), significantly younger than those in the northern massifs. Ni?de rocks resided in the mid‐crust at a time when the rest of the CACC was at or near the Earth's surface. Variations in P–T–t and tectonic histories — especially timing of exhumation — between the northern and southern CACC reflect the difference between head‐on collision vs. mid‐crustal wrenching.     

The Higo metamorphic complex in Kyushu, Japan as the fragment of Permo–Triassic metamorphic complexes in East Asia

The Higo terrane in west-central Kyushu Island, southwest Japan consists from north to south of the Manotani, Higo and Ryuhozan metamorphic complexes, which are intruded by the Higo plutonic complex (Miyanohara tonalite and Shiraishino granodiorite).The Higo and Manotani metamorphic complexes indicate an imbricate crustal section in which a sequence of metamorphic rocks with increasing metamorphic grade from high (northern part) to low (southern part) structural levels is exposed. The metamorphic rocks in these complexes can be divided into five metamorphic zones (zone A to zone E) from top to base (i.e., from north to south) on the basis of mineral parageneses of pelitic rocks. Greenschist-facies mineral assemblages in zone A (the Manotani metamorphic complex) give way to amphibolite-facies assemblages in zones B, C and D, which in turn are replaced by granulite-facies assemblages in zone E of the Higo metamorphic complex. The highest-grade part of the complex (zone E) indicates peak P–T conditions of ca. 720 MPa and ca. 870 °C. In addition highly aluminous Spr-bearing granulites and related high-temperature metamorphic rocks occur as blocks in peridotite intrusions and show UHT-metamorphic conditions of ca. 900 MPa and ca. 950 °C. The prograde and retrograde P–T evolution paths of the Higo and Manotani metamorphic complexes are estimated using reaction textures, mineral inclusion analyses and mineral chemistries, especially in zones A and D, which show a clockwise P–T path from Lws-including Pmp–Act field to Act–Chl–Epi field in zone A and St–Ky field to And field through Sil field in zone D.The Higo metamorphic complex has been traditionally considered to be the western-end of the Ryoke metamorphic belt in the Japanese Islands or part of the Kurosegawa–Paleo Ryoke terrane in south-west Japan. However, recent detailed studies including Permo–Triassic age (ca. 250 Ma) determinations from this complex indicate a close relationship with the high-grade metamorphic terranes in eastern-most Asia (e.g., north Dabie terrane) with similar metamorphic and igneous characteristics, protolith assembly, and metamorphic and igneous ages. The north Dabie high-grade terrane as a collisional metamorphic zone between the North China and the South China cratons could be extended to the N-NE along the transcurrent fault (Tan-Lu Fault) as the Sulu belt in Shandong Peninsula and the Imjingang belt in Korean Peninsula. The Higo and Manotani metamorphic complexes as well as the Hida–Oki terrane in Japan would also have belonged to this type of collisional terrane and then experienced a top-to-the-south displacement with forming a regional nappe structure before the intrusion of younger Shiraishino granodiorite (ca. 120 Ma).