土体腐殖酸组分对水泥土强度影响效果试验

摘 要:工程实践发现水泥固化软土受土体腐殖酸成分的影响。当前,土体腐殖酸组分对水泥土固化影响已成为岩土工程研究的重要课题之一。通过在实际工程采样对水泥加固土腐殖酸组分进行定性、定量对比试验分析,以研究不同水泥掺量、不同地域水泥固化土腐殖酸组分的影响效果。试验结果表明:由红外光谱（IR）试验表现在水泥环境中胡敏酸组分的羧基量增多,水泥土阳离子交换量（CEC）随水泥掺量增加而增大;在5%、10%、20%水泥掺入比之水泥土中,由神经网络预测模型预测结果证实,富里酸组分对水泥土无侧限抗压强度影响效果较强。水泥土腐殖酸组分可与水泥产物Ca2+、AI3+反应,在水泥土环境生成钙、铝键等复合体,它们可能影响水泥水解水化反应,削减水泥所能达到的固化效果。 关键词:腐殖酸组分;红外光谱（IR）;电子扫描显微镜（SEM）;阳离子交换量（CEC）;水泥土。     

Detection and discrimination of sulfate minerals using reflectance spectroscopy

A suite of sulfate minerals were characterized spectrally, compositionally, and structurally in order to develop spectral reflectance-compositional-structural relations for this group of minerals. Sulfates exhibit diverse spectral properties, and absorption-band assignments have been developed for the 0.3-26 μm range. Sulfate absorption features can be related to the presence of transition elements, OH, H₂O, and SO₄ groups. The number, wavelength position, and intensity of these bands are a function of both composition and structure. Cation substitutions can affect the wavelength positions of all major absorption bands. Hydroxo-bridged Fe³⁺ results in absorption bands in the 0.43, 0.5, and 0.9 μm regions, while the presence of Fe²⁺ results in absorption features in the 0.9-1.2 μm interval. Fundamental SO bending and stretching vibration absorption bands occur in the 8-10, 13-18, and 19-24 μm regions (1000-1250, 550-770, and 420-530 cm⁻¹). The most intense combinations and overtones of these fundamentals are found in the 4-5 μm (2000-2500 cm⁻¹) region. Absorption features seen in the 1.7-1.85 μm interval are attributable to HOH/OH bending and translation/rotation combinations, while bands in the 2.1-2.7 μm regions can be attributed to H₂O- and OH-combinations as well as overtones of SO bending fundamentals. OH- and H₂O-bearing sulfate spectra are fundamentally different from each other at wavelengths below ∼6 μm. Changes in H₂O/OH content can shift SO band positions due to change in bond lengths and structural rearrangement. Differences in absorption band wavelength positions enable discrimination of all the sulfate minerals used in this study in a number of wavelength intervals. Of the major absorption band regions, the 4-5 μm region seems best for identifying and discriminating sulfates in the presence of other major rock-forming minerals.     

A sensitive search for nitric oxide in the lower atmospheres of Venus and Mars: Detection on Venus and upper limit for Mars

High-resolution spectra of Venus and Mars at the NO fundamental band at 5.3 μm with resolving power ν/δν=76,000 were acquired using the TEXES spectrograph at NASA IRTF on Mauna Kea, Hawaii. The observed spectrum of Venus covered three NO lines of the P-branch. One of the lines is strongly contaminated, and the other two lines reveal NO in the lower atmosphere at a detection level of 9 sigma. A simple photochemical model for NO and N at 50-112 km was coupled with a radiative transfer code to simulate the observed equivalent widths of the NO and some CO₂ lines. The derived NO mixing ratio is 5.5±1.5 ppb below 60 km and its flux is . Predissociation of NO at the (0-0) 191 nm and (1-0) 183 nm bands of the δ-system and the reaction with N are the only important loss processes for NO in the lower atmosphere of Venus. The photochemical impact of the measured NO abundance is significant and should be taken into account in photochemical modeling of the Venus atmosphere. Lightning is the only known source of NO in the lower atmosphere of Venus, and the detection of NO is a convincing and independent proof of lightning on Venus. The required flux of NO is corrected for the production of NO and N by the cosmic ray ionization and corresponds to the lightning energy deposition of . For a flash energy on Venus similar to that on the Earth (∼¹⁰⁹ J), the global flashing rate is ∼90 s⁻¹ and ∼6 km⁻² y⁻¹ which is in reasonable agreement with the existing optical observations. The observed spectrum of Mars covered three NO lines of the R-branch. Two of these lines are contaminated by CO₂ lines, and the line at 1900.076 cm⁻¹ is clean and shows some excess over the continuum. Some photochemical reactions may result in a significant excitation of NO (v=1) in the lowest 20 km on Mars. However, quenching of NO (v=1) by CO₂ is very effective below 40 km. Excitation of NO (v=1) in the collisions with atomic oxygen is weak because of the low temperature in the martian atmosphere, and we do not see any explanation of a possible emission of NO at 5.3 μm. Therefore the data are treated as the lack of absorption with a 2 sigma upper limit of 1.7 ppb to the NO abundance in the lower atmosphere of Mars. This limit is above the predictions of photochemical models by a factor of 3.     

A powerful new infrared array camera for the NASA Infrared Telescope Facility

We have just finished building a 1.0–5.5 m infrared array camera for the NASA Infrared Telescope Facility based upon the SBRC 256×256 InSb array. After a brief overview of the capabilities of the camera (named NSFCAM), we present some of the first images obtained with this new camera, including results obtained with our realtime shift & add speckle imaging mode.     

Refractive optical systems for astronomical instruments using infrared arrays in the 0.8 to 2.5 micron bands

As modern infrared arrays evolve towards larger formats and smaller pixel sizes, their use in instruments requires optics of increasingly higher performance. Refractive systems are attractive for many applications because they can accommodate wide fields of view or fast focal ratios while permitting a compact, unobscured layout. We examine design considerations for lenses which can address the entire near-infrared spectral region of 0.8 to 2.5 m. Achromatization over this broad range is a particular challenge. We discuss a systematic study of candidate materials and combinations of materials having useful chromatic properties, with particular emphasis on alkaline earth halides and metallic oxides. We present an example of a practical design being incorporated into an instrument currently under construction.     

Astronomy with a mid-infrared echelle spectrograph

Irshell, a mid-infrared echelle spectrograph developed through a collaboration between the University of Texas, the University of California Space Sciences Laboratory, and Hughes Aircraft, has been in regular use for astronomical observations for about five years. It is optimized for high spectral resolution (R10,000) observations of narrow spectral regions (/1/300) and compact sources (a few arcsec), and is sensitive in the 5–25 m region. A wide variety of astronomical objects have been studied. Observing techniques have been developed to achieve maximum sensitivity in those observations for which Irshell is best suited and to allow observations of wide spectral regions and extended objects. We discuss the observing techniques and show some of the data obtained.     

镁铝榴石中的结构水的研究

通过对34个取自金伯利岩管中的粗晶镁铝榴石及碱性玄武岩中镁铝榴石巨晶样品的红外光谱分析发现,金伯利岩中部分镁铝榴石粗晶含有结构水,但不同颗粒之间含量差异很大,含量较高者约0.07wt%,而所研究的碱性玄武岩中的镁铝榴石不含结构水。分析发现,结构水在同一样品内分布基本均匀。在红外光谱3800—3500cm~(-1)波长范围内,分别记录到三峰谱和单峰谱两种类型,其中位于3570cm~(-1)±的吸收峰峰位明显受镁铝榴石结构中八配位阳离子(Mg~(2+)、Fe~(2+))影响,而六配位阳离子(Cr~(3+)、Al~(3+))的影响不明显。结构水在镁铝榴石晶格中的存在形式是多样的。     

应用彩色红外航空像片进行城市居民生活条件调查和分析

本文介绍了应用彩红外航片对城市居民生活条件进行调查和分析,其基本方法是:首先通过直接和间接判读标志,对居民物质生活条件和精神生活条件进行解译,然后从方便度和舒适度两项评价指标入手,选取八项评价因子,进行定量的综合评价和空间分析,最后提出改善实验区居民生活条件的建议。     

Changes in plant defense chemistry (pyrrolizidine alkaloids) revealed through high-resolution spectroscopy

Plant toxic biochemicals play an important role in defense against natural enemies and often are toxic to humans and livestock. Hyperspectral reflectance is an established method for primary chemical detection and could be further used to determine plant toxicity in the field. In order to make a first step for pyrrolizidine alkaloids detection (toxic defense compound against mammals and many insects) we studied how such spectral data can estimate plant defense chemistry under controlled conditions.In a greenhouse, we grew three related plant species that defend against generalist herbivores through pyrrolizidine alkaloids: Jacobaea vulgaris, Jacobaea erucifolia and Senecio inaequidens, and analyzed the relation between spectral measurements and chemical concentrations using multivariate statistics.Nutrient addition enhanced tertiary-amine pyrrolizidine alkaloids contents of J. vulgaris and J. erucifolia and decreased N-oxide contents in S. inaequidens and J. vulgaris. Pyrrolizidine alkaloids could be predicted with a moderate accuracy. Pyrrolizidine alkaloid forms tertiary-amines and epoxides were predicted with 63% and 56% of the variation explained, respectively. The most relevant spectral regions selected for prediction were associated with electron transitions and CH, OH, and NH bonds in the 1530 and 2100 nm regions.Given the relatively low concentration in pyrrolizidine alkaloids concentration (in the order of mg g⁻¹) and resultant predictions, it is promising that pyrrolizidine alkaloids interact with incident light. Further studies should be considered to determine if such a non-destructive method may predict changes in PA concentration in relation to plant natural enemies. Spectroscopy may be used to study plant defenses in intact plant tissues, and may provide managers of toxic plants, food industry and multitrophic-interaction researchers with faster and larger monitoring possibilities.