A Hapke model implementation for compositional analysis of VNIR spectra of Mercury

An implementation of Hapke’s radiative transfer-based photometric model for light scattering in semi-transparent porous media is presented with special emphasis on the analysis of reflectance spectra of Mercury. The model allows intimate mixing of an arbitrary number of regolith components with varying modal abundances, modal chemistries and grain sizes, matured by microphase iron. Reflectance spectra of suites of silicates of varying grain sizes and chemistries are used to calculate the imaginary coefficient of the complex index of refraction as a function of chemistry, thus limiting the modeling effects of chemically atypical laboratory samples, and allowing controlled modeling of minerals with varying chemical compositions. The performance of the model in the visual to near-infrared wavelength range is evaluated for a range of chemically characterized silicate mixtures of terrestrial powders, meteorite powders, matured lunar return samples, and remotely sensed lunar spectra.     

Correlations between VIMS and RADAR data over the surface of Titan: Implications for Titan’s surface properties

We apply a multivariate statistical method to Titan data acquired by different instruments onboard the Cassini spacecraft. We have searched through Cassini/VIMS hyperspectral cubes, selecting those data with convenient viewing geometry and that overlap with Cassini/RADAR scatterometry footprints with a comparable spatial resolution. We look for correlations between the infrared and microwave ranges the two instruments cover. Where found, the normalized backscatter cross-section obtained from the scatterometer measurement, corrected for incidence angle, and the calibrated antenna temperature measured along with the scatterometry echoes, are combined with the infrared reflectances, with estimated errors, to produce an aggregate data set, that we process using a multivariate classification method to identify homogeneous taxonomic units in the multivariate space of the samples.In medium resolution data (from 20 to 100 km/pixel), sampling relatively large portions of the satellite’s surface, we find regional geophysical units matching both the major dark and bright features seen in the optical mosaic. Given the VIMS cubes and RADAR scatterometer passes considered in this work, the largest homogeneous type is associated with the dark equatorial basins, showing similar characteristics as each other on the basis of all the considered parameters.On the other hand, the major bright features seen in these data generally do not show the same characteristics as each other. Xanadu, the largest continental feature, is as bright as the other equatorial bright features, while showing the highest backscattering coefficient of the entire satellite. Tsegihi is very bright at 5 μm but it shows a low backscattering coefficient, so it could have a low roughness on a regional scale and/or a different composition. Another well-defined region, located southwest of Xanadu beyond the Tui Regio, seems to be detached from the surrounding terrains, being bright at 2.69, 2.78 and 5 μm but having a low radar brightness. In this way, other units can be found that show correlations or anti-correlations between the scatterometric response and the spectrophotometric behavior, not evident from the optical remote sensing data.     

Mid-infrared spectra of the shocked Murchison CM chondrite: Comparison with astronomical observations of dust in debris disks

We present laboratory mid-infrared transmission/absorption spectra obtained from matrix of the hydrated Murchison CM meteorite experimentally shocked at peak pressures of 10-49 GPa, and compare them to astronomical observations of circumstellar dust in different stages of the formation of planetary systems. The laboratory spectra of the Murchison samples exhibit characteristic changes in the infrared features. A weakly shocked sample (shocked at 10 GPa) shows almost no changes from the unshocked sample dominated by hydrous silicate (serpentine). Moderately shocked samples (21-34 GPa) have typical serpentine features gradually replaced by bands of amorphous material and olivine with increasing shock pressure. A strongly shocked sample (36 GPa) shows major changes due to decomposition of the serpentine and due to devolatilization. A shock melted sample (49 GPa) shows features of olivine recrystallized from melted material.The infrared spectra of the shocked Murchison samples show similarities to astronomical spectra of dust in various young stellar objects and debris disks. The spectra of highly shocked Murchison samples (36 and 49 GPa) are similar to those of dust in the debris disks of HD113766 and HD69830, and the transitional disk of HD100546. The moderately shocked samples (21-34 GPa) exhibit spectra similar to those of dust in the debris disks of Beta Pictoris and BD+20307, and the transitional disk of GM Aur. An average of the spectra of all Murchison samples (0-49 GPa) has a similarity to the spectrum of the older protoplanetary disk of SU Auriga. In the gas-rich transitional and protoplanetary disks, the abundances of amorphous silicates and gases have widely been considered to be a primary property. However, our study suggests that impact processing may play a significant role in generating secondary amorphous silicates and gases in those disks. Infrared spectra of the shocked Murchison samples also show similarities to the dust from comets (C/2002 V1, C/2001 RX14, 9P/Tempel 1, and Hale Bopp), suggesting that the comets also contain shocked Murchison-like material.     

Titan trace gaseous composition from CIRS at the end of the Cassini-Huygens prime mission

This paper reports on the results from an extensive study of all nadir-looking spectra acquired by Cassini/CIRS during the 44 flybys performed in the course of the nominal mission (2004-2008). With respect to the previous study (Coustenis, A., and 24 colleagues [2007]. Icarus 189, 35-62, on flybys TB-T10) we present here a significantly richer dataset with, in particular, more data at high northern and southern latitudes so that the abundances inferred here at these regions are more reliable. Our enhanced high-resolution dataset allows us to infer more precisely the chemical composition of Titan all over the disk. We also include improved spectroscopic data for some molecules and updated temperature profiles. The latitudinal distributions of all of the gaseous species are inferred. We furthermore test vertical distributions essentially for acetylene (C₂H₂) from CIRS limb-inferred data and from current General Circulation Models for Titan and compare our results on all the gaseous abundances with predictions from 1-D photochemical-radiative models to check the reliability of the chemical reactions and pathways.     

The light curve of asteroid 2867 Steins measured by VIRTIS-M during the Rosetta fly-by

On 5 September 2008, the Rosetta spacecraft encountered the asteroid 2867 Steins on its way to the comet 67P/Churyumov-Gerasimenko. This was the first of two planned asteroid fly-bys performed by the probe, the second fly-by being with the much larger asteroid 21 Lutetia in July 2010. The VIRTIS imaging spectrometer (IFOV 0.250 mrad, overall spectral range 0.25-5.1 μm) onboard Rosetta acquired data of Steins already before the closest approach phase, when the target was spatially unresolved, in order to obtain a light curve of the asteroid in the infrared spectral range extending up to 5 μm, that was never explored before. The VIRTIS light curve campaign started at 11:30 UTC onboard time, when the spacecraft was about 221,377 km away from the target, and ended at 17:58 UTC, at a distance of 20,741 km away from Steins. During this timeframe, the solar phase angle of the asteroid was roughly constant, ranging from 38.2° to 36.3°.Assuming the most recent value derived for the rotational period of Steins (Lamy et al., 2008), the VIRTIS observations covered slightly more than one rotation of the asteroid. In this interval, VIRTIS collected 8 hyperspectral cubes where Steins was captured 119 times, both in the visual and in the infrared range. Given the low signal and the unresolved appearance of the source, for which the instrument was not designed, only a small subset of wavelengths turned out to be suitable to sample the light curve. Nevertheless, in both the VIS and NIR ranges we find a similar trend, with two different maxima and minima during one rotational period, and amplitudes consistent with the results in the visual range obtained in previous works, including the data set acquired by the OSIRIS camera onboard Rosetta. We also report the presence of a new broad feature centered at approximately 0.81-0.82 μm, which is seen in the visual data throughout the rotation of the asteroid.     

Abundances of Jupiter's trace hydrocarbons from Voyager and Cassini

The flybys of Jupiter by the Voyager spacecraft in 1979, and over two decades later by Cassini in 2000, have provided us with unique datasets from two different epochs, allowing the investigation of seasonal change in the atmosphere. In this paper we model zonal averages of thermal infrared spectra from the two instruments, Voyager 1 IRIS and Cassini CIRS, to retrieve the vertical and meridional profiles of temperature, and the abundances of the two minor hydrocarbons, acetylene (C₂H₂) and ethane (C₂H₆). The spatial variation of these gases is controlled by both chemistry and dynamics, and therefore their observed distribution gives us an insight into both processes. We find that the two gases paint quite different pictures of seasonal change. Whilst the 2-D cross-section of C₂H₆ abundance is slightly increased and more symmetric in 2000 (northern summer solstice) compared to 1979 (northern fall equinox), the major trend of equator to pole increase remains. For C₂H₂ on the other hand, the Voyager epoch exhibits almost no latitudinal variation, whilst the Cassini era shows a marked decrease polewards in both hemispheres. At the present time, these experimental findings are in advance of interpretation, as there are no published models of 2-D Jovian seasonal chemical variation available for comparison.     

Oxygen and carbon isotope ratios in the martian atmosphere

Oxygen and carbon isotope ratios in the martian CO₂ are key values to study evolution of volatiles on Mars. The major problems in spectroscopic determinations of these ratios on Mars are uncertainties associated with: (1) equivalent widths of the observed absorption lines, (2) line strengths in spectroscopic databases, and (3) thermal structure of the martian atmosphere during the observation. We have made special efforts to reduce all these uncertainties. We observed Mars using the Fourier Transform Spectrometer at the Canada–France–Hawaii Telescope. While the oxygen and carbon isotope ratios on Mars were byproducts in the previous observations, our observation was specifically aimed at these isotope ratios. We covered a range of 6022 to 6308 cm⁻¹ with the highest resolving power of ν/δν=3.5×10⁵ and a signal-to-noise ratio of 180 in the middle of the spectrum. The chosen spectral range involves 475 lines of the main isotope, 184 lines of ¹³CO₂, 181 lines of CO¹⁸O, and 119 lines of CO¹⁷O. (Lines with strengths exceeding 10⁻²⁷ cm at 218 K are considered here.) Due to the high spectral resolution, most of the lines are not blended. Uncertainties of retrieved isotope abundances are in inverse proportion to resolving power, signal-to-noise ratio, and square root of the number of lines. Laboratory studies of the CO₂ isotope spectra in the range of our observation achieved an accuracy of 1% in the line strengths. Detailed observations of temperature profiles using MGS/TES and data on temperature variations with local time from two GCMs are used to simulate each absorption line at various heights in each part of the instrument field of view and then sum up the results. Thermal radiation of Mars' surface and atmosphere is negligible in the chosen spectral range, and this reduces errors associated with uncertainties in the thermal structure on Mars. Using a combination of all these factors, the highest accuracy has been achieved in measuring the CO₂ isotope ratios: ¹³C/¹²C = 0.978 ± 0.020 and ¹⁸O/¹⁶O = 1.018 ± 0.018 times the terrestrial standards. Heavy isotopes in the atmosphere are enriched by nonthermal escape and sputtering, and depleted by fractionation with solid-phase reservoirs. The retrieved ratios show that isotope fractionation between CO₂ and oxygen and carbon reservoirs in the solid phase is almost balanced by nonthermal escape and sputtering of O and C from Mars.     

Gemini-N mid-IR observations of the dust properties of the ejecta excavated from Comet 9P/Tempel 1 during Deep Impact

We present mid-infrared spectra and images from the Gemini-N (+MICHELLE) observational campaign of Comet 9P/Tempel 1 before, during, and after its encounter with Deep Impact. We use our thermal grain model to probe the 10 μm properties of the dust grains in the coma of the comet. Before impact (3 July 2005 UT), and more than 24 h after impact (5, 16, and 28 July 2005 UT), the comet dust grains were composed mostly of amorphous olivine, and were relatively large (peak of the grain size distribution ). For the night of impact, we extract spectra by centering on the nucleus, and offset 1″ from the nucleus in the direction of the impact ejecta plume. We find small dust grains (∼0.2 μm) of a diverse mineralogy (amorphous olivine, amorphous pyroxene, amorphous carbon, and crystalline olivine) populating the ejecta. The submicron sized dust grains move faster than the other, larger grains (?0.7 μm), with amorphous olivine and amorphous carbon traveling together, and amorphous pyroxene and crystalline olivine dispersing at a similar rate. Deriving a velocity law from a time-of-flight analysis, we find that the material traveled with a velocity law scaled by and with a power of p=0.5. This velocity power-law requires a sustained release of grains for the duration of 45-60 min after impact. Since the mineral species are traveling at different speeds, and there was a sustained release of grains due to a possible “gas-plume,” we conclude that the different minerals did not originate from grain aggregates destroyed by the impact, but instead arise from an inhomogeneous nucleus.     

直流电弧原子发射光谱法测定钛和钛合金中微量杂质元素

高纯度的钛及钛合金具有良好的可塑性,当有杂质存在时变得脆而硬而影响其性能,准确分析杂质元素的含量有利于对钛生产工艺进行质量控制。对于杂质元素的分析,现行国家标准方法是采用样品蒸发温度较高的直流电弧作为光源,摄谱仪测定,需要经过显影、定影、测量黑度等步骤,操作繁琐,流程长,测量误差较大。本文应用中阶梯光栅和电荷耦合器件(CCD)组成的直流电弧(DC Arc)原子发射光谱仪(波长范围200~800nm),谱线干扰分析和谱线强度测量可以同时进行,能更大限度地获取光谱信息,建立了快速测定钛及钛合金中10种微量杂质元素(锰锡铬镍铝钼钒铜锆钇)的分析方法。实验讨论了测定过程中的四类谱线干扰,包括钛作为基体元素的谱线干扰、钛合金中添加的化学成分元素干扰、铁谱线的干扰、杂质元素之间的干扰,确定了适当的分析线;并应用一种浅孔薄壁细颈杯形电极装入试样,提高了样品的蒸发效果;用氯化银和碳粉的混合物作缓冲剂,提高了待测元素的谱线强度。本方法的检测范围为0.001%~0.06%,精密度小于15%,回收率为90.0%~110.0%,适合于大批量钛及钛合金样品中杂质元素的同时检测。