On the dose dependency of the bleachable and non-bleachable components of IRSL from K-feldspar: Improved procedures for luminescence dating of Quaternary sediments

The infrared (IR) stimulated luminescence (IRSL) and post-IR IRSL (pIRIR) signals from K-feldspar can, for convenience, be divided into two components, bleachable and ‘non-bleachable’, where the latter corresponds to the ‘residual’ signal observed in sunlight-bleached samples. In this paper, we examine the non-bleachable component of IRSL of K-feldspar for several sedimentary samples from across Eurasia. We observed a large variability in the residual doses among these samples after prolonged exposure to sunlight. By employing multiple elevated temperature (MET) IR stimulations at 50–300 °C, we show that the residual dose increases systematically with stimulation temperature, attaining values as high as ∼50 Gy at 300 °C, even after several hours to tens of hours of exposure to unfiltered sunlight. We examined two samples in detail and found that the bleachable and non-bleachable components produced different dose response curves. Pulse annealing studies showed that the non-bleachable component is more stable than the bleachable component, suggesting that a preheat procedure cannot eliminate the non-bleachable component. Additional experiments revealed that the non-bleachable component is dose dependent. Owing to this dose dependency, we demonstrate mathematically and empirically that the simple subtraction of a residual dose from the measured equivalent dose (D_e) – which is the most common approach employed (if any residual dose is subtracted at all) – will result in underestimation of the actual D_e. We present a method to correct for the dose dependency of the residual dose, which can improve the accuracy of either MET-pIRIR or pIRIR age estimates for samples in which the non-bleachable component represents a significant fraction of the measured signals.     

Near-infrared light curve of Comet 9P/Tempel 1 during Deep Impact

On UT 2005 July 4 we observed Comet 9P/Tempel 1 during its encounter with the Deep Impact flyby spacecraft and impactor. Using the SpeX near-infrared spectrograph mounted on NASA's Infrared Telescope Facility, we obtained 0.8-to-2.5 μm flux-calibrated spectral light curves of the comet for 12 min before and 14 min after impact. Our cadence was just 1.1 s. The light curve shows constant flux before the impact and an overall brightening trend after the impact, but not at a constant rate. Within a 0.8-arcsec-radius circular aperture, the comet rapidly-brightened by 0.63 mag at 1.2 μm in the first minute. Thereafter, brightening was more modest, averaging about 0.091 mag/min at 1.2 μm, although apparently not quite constant. In addition we see a bluing in the spectrum over the post-impact period of about 0.07 mag in J-H and 0.35 mag in J-K. The majority of this bluing happened in the first minute, and the dust only marginally blued after that, in stark contrast to the continued brightening. The photometric behavior in the light curve is due to a combination of crater formation effects, expansion of the ejecta cloud, and evolution of liberated dust grains. The bluing is likely due to an icy component on those grains, and the icy grains would have had to have a devolatilization timescale longer than 14 min (unless they were shielded by the optical depth of the cloud). The bluing could also have been caused by the decrease in the “typical” size of the dust grains after impact. Ejecta dominated by submicron grains, as inferred from other observations, would have stronger scattering at shorter wavelengths than the much larger grains observed before impact.     

Assessing the limits of the Modified Gaussian Model for remote spectroscopic studies of pyroxenes on Mars

We investigate the ability to refine pyroxene composition and modal abundance from laboratory and remotely acquired spectra. Laboratory data including the martian meteorites, Shergotty, Zagami, MIL03346, and ALH84001 as well as additional pyroxene-rich spectra obtained from the OMEGA (Observatoire pour la Minéralogie, l'Eau, les Glaces, et l'Activité) spectrometer for Mars are characterized using the Modified Gaussian Model (MGM), a spectral deconvolution method developed by Sunshine et al. [Sunshine, J.M., Pieters, C.M., Pratt, S., 1990. J. Geophys. Res. 95, 6955-6966]. We develop two sensitivity tests to assess the extent to which the MGM can consistently predict (1) pyroxene composition and (2) modal abundance for a compositionally diverse suite of pyroxene spectra. Results of the sensitivity tests indicate that the MGM can be appropriately applied to remote spectroscopic measurements of extraterrestrial surfaces and can estimate pyroxene composition and relative abundance within a derived uncertainty. Deconvolved band positions for laboratory spectra of the meteorites Shergotty and Zagami are determined within ±17 nm while remotely acquired OMEGA spectra are defined within ±50 nm. These results suggest that absolute compositions can be uniquely derived from laboratory pyroxene-rich spectra and non-uniquely derived from the remote measurements of OMEGA at this time. While relative pyroxene chemistries are not assessed from OMEGA measurements at this time, relative pyroxene abundances are estimated using a normalized band strength ratio between the low-calcium (LCP) and high-calcium (HCP) endmember components and are constrained to ±10%. The fraction of LCP in a two-pyroxene mixture is the derived value from the normalized band strength ratio, LCP/(LCP + HCP). This calculation for relative abundance is robust in the presence of up to 10-15% olivine. Deconvolution results from the OMEGA spectra indicate that the ancient terrain in the Syrtis Major region is uniquely enriched in LCP (59±10% LCP) relative to HCP while the volcanics of Syrtis Major are uniquely enriched in HCP (39±10% LCP).     

Radio OH observations of 9P/Tempel 1 before and after Deep Impact

We observed 18-cm OH emission in Comet 9P/Tempel 1 before and after Deep Impact. Observations using the Arecibo Observatory 305 m telescope took place between 8 April and 9 June, 2005, followed by post-impact observations using the National Radio Astronomy Observatory 100 m Green Bank Telescope 4-12 July, 2005. The resulting spectra were analyzed with a kinematic Monte Carlo model which allows estimation of the OH production rate, neutral gas outflow velocity, and distribution of the out-gassing from the nucleus. We detected typically 24% variability from the overall OH production rate trend in the two months leading up to the impact, and no dramatic increase in OH production in the days post-impact. Generally, the coma is well-described, within uncertainties, by a symmetric model with OH production rates from 1.6 to , and mean water outflow velocity of . At these low production rates, collisional quenching is expected to occur only within 20,000 km of the nucleus. However, our best-fit average quenching radius is 64,200 ± 22,000 km in April and May.     

Carbon dioxide on planetary bodies: Theoretical and experimental studies of molecular complexes

An absorption band at ∼4.26 μm wavelength attributed to the asymmetric stretching mode of CO in CO₂ has been found on two satellites of Jupiter and several satellites of Saturn. The wavelength of pure CO₂ ice determined in the laboratory is 4.2675 μm, indicating that the CO₂ on the satellites occurs either trapped in a host material, or in a chemical or physical complex with other materials, resulting in a blue shift of the wavelength of the band. In frequency units, the shifts in the satellite spectra range from 3.7 to 11.3 cm⁻¹. We have performed ab initio quantum chemical calculations of CO₂ molecules chemically complexed with one, two, and more H₂O molecules and molecules of CH₃OH to explore the possibility that the blue shift of the band is caused by chemical complexing of CO₂ with other volatile materials. Our computations of the harmonic and anharmonic vibrational frequencies using high levels of theory show a frequency shift to the blue by 5 cm⁻¹ from pure CO₂ to CO-H₂O, and an additional 5 cm⁻¹ from CO₂-H₂O to CO₂-2H₂O. Complexing with more than two H₂O molecules does not increase the blue shift. Complexes of CO₂ with one molecule of CH₃OH and with one CH₃OH plus one H₂O molecule produce smaller shifts than the CO₂-2H₂O complex. Laboratory studies of CO₂:H₂O in a solid N₂ matrix also show a blue shift of the asymmetric stretching mode.     

Comet Hale-Bopp in outburst: Imaging the dynamics of icy particles with HST/NICMOS

Comet Hale-Bopp was imaged at wavelengths from 1.87 to 2.22 μm by HST/NICMOS in post-perihelion observations starting on UT 1997 August 27.95. Diffraction-limited (∼02) images were obtained at high signal-to-noise (∼1500) to probe the composition and dynamics of the inner coma and also the size and activity of the nucleus. The velocities of several unusual morphological features over a 1.7 h period, indicate that a significant outburst occurred 7.4 h prior to these images while the comet was at a heliocentric distance of 2.49 AU. Similar features are also apparent after re-analysis of pre-perihelion ground-based images. The inner coma (radius ?2500 km) is dominated by an “arc” feature, which expanded and became more diffuse with time. This feature can be modeled as the bright central portion of a “jet of outburst” from a near-equatorial region of the nucleus. Less prominent, time-variable linear and circular morphologies are also apparent. The expansion rates of both the arc feature and the circular morphologies imply a common origin and also suggest a grain size distribution with two broad maxima. In addition, several static linear features extend to the edge of the field of view (21,100 km). Radial brightness profiles are highly asymmetric and only approach a ρ⁻¹ decline at distances ?15,000 km. Images in a narrow-band filter at 2.04 μm exhibit a ∼4% absorption feature relative to nearly simultaneous images at wavelengths of 2.22, 1.90, and 1.87 μm. This absorption is attributed to H₂O ice in the coma grains. The spatial distribution and expansion velocity of the absorption at 2.04 μm indicate that these grains are associated with the outburst. The constancy of the absorption feature indicates no appreciable sublimation over 1.7 h. The unresolved nucleus has a flux density consistent with a 40±10 km diameter assuming a 4% geometric albedo.     

Thermal inertia of near-Earth asteroids and implications for the magnitude of the Yarkovsky effect

Thermal inertia determines the temperature distribution over the surface of an asteroid and therefore governs the magnitude the Yarkovsky effect. The latter causes gradual drifting of the orbits of km-sized asteroids and plays an important role in the delivery of near-Earth asteroids (NEAs) from the main belt and in the dynamical spreading of asteroid families. At present, very little is known about the thermal inertia of asteroids in the km size range. Here we show that the average thermal inertia of a sample of NEAs in the km-size range is . Furthermore, we identify a trend of increasing thermal inertia with decreasing asteroid diameter, D. This indicates that the dependence of the drift rate of the orbital semimajor axis on the size of asteroids due to the Yarkovsky effect is a more complex function than the generally adopted D⁻¹ dependence, and that the size distribution of objects injected by Yarkovsky-driven orbital mobility into the NEA source regions is less skewed to smaller sizes than generally assumed. We discuss how this fact may help to explain the small difference in the slope of the size distribution of km-sized NEAs and main-belt asteroids.     

Infrared micro-spectroscopy of the martian meteorite Zagami: Extraction of individual mineral phase spectra

Zagami, a well characterized SNC meteorite, represents a reference sample to verify the feasibility of the non-destructive infrared micro-spectroscopy technique to extract spectral signatures from individual mineral phases in a meteorite sample. For the first time individual infrared spectra of the major mineral phases, in the 6000-600 cm⁻¹ (1.67-16.7 μm) spectral interval, whose identification is confirmed by energy dispersive X-ray analysis and backscattered imaging, are measured. The signatures of the main mineral phases we identified in the Zagami chip are: (1) maskelynite characterized by broad and smooth SiO vibrational bands in the 1000 cm⁻¹ spectral region; (2) crystalline pyroxenes showing well defined fine structures; and (3) an oxide mineral phase with an almost featureless and flat spectrum. In the part of the spectrum centered around 2 μm, by analyzing the different positions of the Fe²⁺ bands, we were able to discern the high-Ca from the low-Ca pyroxene phases. This result demonstrates that by means of the infrared micro-spectroscopy technique it is possible to retrieve directly the composition of pyroxenes in the En-Fs-Wo system, without relying on the use of deconvolution techniques. In addition IR signatures due to water and aliphatic hydrocarbons were observed to be more abundant in the pyroxenes than in maskelynite. This could be an indication that the organic and water signatures are due to indigenous compounds in Zagami rather than laboratory contamination, however, further investigations are necessary before this conclusion can be confirmed.     

The first detection of propane on Saturn

We report the first detection of propane, C₃H₈, in Saturn's stratosphere. Observations taken on September 8, 2002 UT at NASA's IRTF using TEXES, show multiple emission lines due to the 748 cm⁻¹ν₂₁ band of C₃H₈. Using a line-by-line radiative transfer code, we are able to fit the data by scaling the propane vertical mixing ratio profile from the photochemical model of Moses et al. [2000. Icarus 143, 244-298]. Multiplicative factors of 0.7 and 0.65 are required to fit the −20° and −80° planetocentric latitude spectra. The resultant profiles are characterized by a 5 mbar mixing ratio of 2.7±0.8×¹⁰⁻⁸ at −20° and at −80° latitude. These results suggest that the time scale for meridional circulation lies between the net photochemical lifetimes of C₂H₂ and C₃H₈, ≈30-600 years.     

Structure of self-gravity wakes in Saturn's A ring as measured by Cassini CIRS

The CIRS infrared spectrometer onboard the Cassini spacecraft has scanned Saturn's A ring azimuthally from several viewing angles since its orbit insertion in 2004. A quadrupolar asymmetry has been detected in this ring at spacecraft elevations ranging between 16° to 37°. Its fractional amplitude decreases from 22% to 8% from 20° to 37° elevations. The patterns observed in two almost complete azimuthal scans at elevations 20° and 36° strongly favor the self-gravity wakes as the origin of the asymmetry. The elliptical, infinite cylinder model of Hedman et al. [Hedman, M.M., Nicholson, P.D., Salo, H., Wallis, B.D., Buratti, B.J., Baines, K.H., Brown, R.H., Clark, R.N., 2007. Astron. J. 133, 2624-2629] can reproduce the CIRS observations well. Such wakes are found to have an average height-to-spacing ratio H/λ=0.1607±0.0002, a width-over-spacing W/λ=0.3833±0.0008. Gaps between wakes, which are filled with particles, have an optical depth τG=0.1231±0.0005. The wakes mean pitch angle ΦW is 70.70°±0.07°, relative to the radial direction. The comparison of ground-based visible data with CIRS observations constrains the A ring to be a monolayer. For a surface mass density of 40 g cm⁻² [Tiscarino, M.S., Burns, J.A., Nicholson, P.D., Hedman, M.M., Porco, C.C., 2007. Icarus 189, 14-34], the expected spacing of wakes is λ≈60 m. Their height and width would then be H≈10 m and W≈24 m, values that match the maximum size of particles in this ring as determined from ground-based stellar occultations [French, R.G., Nicholson, P.D., 2000. Icarus 145, 502-523].