Atomic oxygen distribution in the Venus mesosphere from observations of O2 infrared airglow by VIRTIS-Venus Express

This VIRTIS instrument on board Venus Express has collected spectrally resolved images of the Venus nightside limb that show the presence of the (0,0) band of the infrared atmospheric system of O₂ at 1.27 μm. The emission is produced by three-body recombination of oxygen atoms created by photodissociation of CO₂ on the dayside. It is consistently bright so that emission limb profiles can be extracted from the images. The vertical distribution of O₂() may be derived following Abel inversion of the radiance limb profiles. Assuming photochemical equilibrium, it is combined with the CO₂ vertical distribution to determine the atomic oxygen density. The uncertainties on the O density caused by the Abel inversion reach a few percent at the peak, increasing to about 50% near 120 km. We first analyze a case when the CO₂ density was derived from a stellar occultation observed with the SPICAV spectrometer simultaneously with an image of the O₂ limb airglow. In other cases, an average CO₂ profile deduced from a series of ultraviolet stellar occultations is used to derive the O profile, leading to uncertainties on the O density less than 30%. It is found that the maximum O density is generally located between 94 and 115 km with a mean value of 104 km. It ranges from less than 1×¹⁰¹¹ to about 5×¹⁰¹¹ cm⁻³ with a global mean of 2.2×¹⁰¹¹ cm⁻³. These values are in reasonable agreement with the VIRA midnight oxygen profile. The vertical O distribution is generally in good agreement with the oxygen profile calculated with a one-dimensional chemical-diffusive model. No statistical latitudinal dependence of the altitude of the oxygen peak is observed, but the maximum O density tends to decrease with increasing northern latitudes. The latitudinal distribution at a given time exhibits large variations in the O density profile and its vertical structure. The vertical oxygen distribution frequently shows multiple peaks possibly caused by waves or variations in the structure of turbulent transport. It is concluded that the O₂ infrared night airglow is a powerful tool to map the distribution of atomic oxygen in the mesosphere between 90 and 115 km and improve future Venus reference atmosphere models.     

Titan at 3 microns: Newly identified spectral features and an improved analysis of haze opacity

We have reanalyzed the high-resolution spectrum of Titan between 2.87 and 3.12 μm observed with NIRSPEC/Keck II on 2001 Nov. 21 in southern summer, using updated CH₃D and C₂H₆ line-by-line models. From new synthetic spectra, we identify all but a few of the previously unidentified significant absorption spectral features in this wavelength range as due to these two species, both of which had been previously detected by Voyager and ground-based observations at other wavelengths. We also derive opacities and reflectivities of haze particles as functions of altitude for the 2.87-2.92 μm wavelength range, where Titan's atmosphere is partially transparent down to the surface. The extinction per unit altitude is observed to increase from 100 km (∼8 mbar) toward lower altitude. The derived total optical depth is approximately 1.1 for the 2.87-2.92 μm range. At wavelengths increasing beyond 2.92 μm the haze layers become much more optically thick, and the surface is rapidly hidden from view. These conclusions apply to equatorial and southern-temperate regions on Titan, excluding polar regions. We also find it unlikely that there is a large enhancement of the tropospheric CH₄ mole fraction over the value reported from analysis of the Huygens/GCMS observations.     

Spectral properties of simulated impact glasses produced from martian soil analogue JSC Mars-1

To simulate the formation of impact glasses on Mars, an analogue of martian bright soil (altered volcanic soil JSC Mars-1) was melted at relevant oxygen fugacities using a pulsed laser and a resistance furnace. Reduction of Fe³⁺ to Fe²⁺ and in some cases formation of nanophase Fe⁰ in the glasses were documented by Mössbauer spectroscopy and TEM studies. Reflectance spectra for several size fractions of the JSC Mars-1 sample and the glasses were acquired between 0.3 and 25 μm. The glasses produced from the JSC Mars-1 soil show significant spectral variability depending on the method of production and the cooling rate. In general, they are dark and less red in the visible compared to the original JSC Mars-1 soil. Their spectra do not have absorption bands due to bound water and structural OH, have positive spectral slopes in the near-infrared range, and show two broad bands centered near 1.05 and 1.9 μm, typical of glasses rich in ferrous iron. The latter bands and low albedo partly mimic the spectral properties of martian dark regions, and may easily be confused with mafic materials containing olivine and low-Ca pyroxene. Due to their disordered structures and vesicular textures, the glasses show relatively weak absorption features from the visible to the thermal infrared. These weak absorption bands may be masked by the stronger bands of mafic minerals. Positive near-infrared spectral slopes typical of fresh iron-bearing impact or volcanic glasses may be masked either by oxide/dust coatings or by aerosols in the Mars' atmosphere. As a result, impact glasses may be present on the surface of Mars in significant quantities that have been either misidentified as other phases or masked by phases with stronger infrared features. Spectrometers with sufficient spatial resolution and wavelength coverage may detect impact glasses at certain locations, e.g., in the vicinity of fresh impact craters. Such dark materials are usually interpreted as accumulations of mafic volcanic sand, but the possibility of an impact melt origin of such materials also should be considered. In addition, our data suggest that high contents of feldspars or zeolites are not necessary to produce the transparency feature at 12.1 μm typical of martian dust spectra.     

Jupiter's hydrocarbon polar brightening: Discovery of 3-micron line emission from south polar CH4, C2H2, and C2H6

Jupiter exhibits bright H⁺₃ auroral arcs at 3-4 microns that cool the hot (>1000 K) ionosphere above the ∼¹⁰−7 bar level through the infrared bands of this trace constituent. Below the ¹⁰−7 bar level significant cooling proceeds through infrared active bands of CH₄, C₂H₂, and C₂H₆. We report the discovery of 3-micron line emission from these hydrocarbon species in spectra of the jovian south polar region obtained on April 18 and 20, 2006 (UT) with CGS4 on the United Kingdom Infrared Telescope. Estimated cooling rates through these molecules are 7.5×¹⁰−3, 1.4×¹⁰−3, and , respectively, for a total nearly half that of H⁺₃. We derive a temperature of 450 ± 50 K in the ¹⁰−7-¹⁰−5 bar region from the C₂H₂ lines.     

Detection of a southern peak in Mercury's sodium exosphere with the TNG in 2005

A long term plan of observations of the sodium exosphere of Mercury began in 2002 by using the high resolution echelle spectrograph SARG and a devoted sodium filter at the 3.5 m Galileo National Telescope (TNG) located in La Palma, Canary Islands. This program is meant to investigate the variations of the sodium exosphere appearance under different conditions of observations, namely Mercury's position along its orbit, phase angle and different solar conditions, as reported by previous observations in August 2002 and August 2003 [Barbieri, C., Verani, S., Cremonese, G., Sprague, A., Mendillo, M., Cosentino, R., Hunten, D., 2004. Planet. Space Sci. 52, 1169-1175; Leblanc, F., Barbieri, C., Cremonese, G., Verani, S., Cosentino, R., Mendillo, M., Sprague, A., Hunten, D., 2006. Icarus 185 (2), 395-402].Here we present the analysis of data taken in June 29th and 30th and in July 1st 2005, when Mercury's true anomaly angle (TAA) was in the range 124-130°. The spectra show particularly intense sodium lines with a distinctive peak in emission localized in the southern hemisphere at mid-latitudes. This seems to be a persistent feature related to consecutive favorable IMF conditions inducing localized enhancements of surface sodium density. The comparison with previous data taken by Potter et al. [Potter, A.E., Killen, R.M., Morgan, T.H., 2002. Meteorit. Planet. Sci. 37 (9), 1165-1172] evidences a surprising consistency of the anti-sunward component, which appears to remain constant regardless of the changing illumination and space weather conditions at Mercury.     

A survey of Karin cluster asteroids with the Spitzer Space Telescope

The Karin cluster is one of the youngest known families of main-belt asteroids, dating back to a collisional event only 5.8±0.2 Myr ago. Using the Spitzer Space Telescope we have photometrically sampled the thermal continua (3.5-22 μm) of 17 Karin cluster asteroids of different sizes, down to the smallest members discovered so far, in order to make the first direct measurements of their sizes and albedos and study the physical properties of their surfaces. Our targets are also amongst the smallest main-belt asteroids observed to date in the mid-infrared. The derived diameters range from 17.3 km for 832 Karin to 1.5 km for 75176, with typical uncertainties of 10%. The mean albedo is pv=0.215±0.015, compared to 0.20±0.07 for 832 Karin itself (for H=11.2±0.3), consistent with the view that the Karin asteroids are closely related physically as well as dynamically. The albedo distribution (0.12?pv?0.32) is consistent with the range associated with S-type asteroids but the variation from one object to another appears to be significant. Contrary to the case for near-Earth asteroids, our data show no evidence of an albedo dependence on size. However, the mean albedo is lower than expected for young, fresh “S-type” surfaces, suggesting that space weathering can darken main-belt asteroid surfaces on very short timescales. Our data are also suggestive of a connection between surface roughness and albedo, which may reflect rejuvenation of weathered surfaces by impact gardening. While the available data allow only estimates of lower limits for thermal inertia, we find no evidence for the relatively high values of thermal inertia reported for some similarly sized near-Earth asteroids. Our results constitute the first observational confirmation of the legitimacy of assumptions made in recent modeling of the formation of the Karin cluster via a single catastrophic collision 5.8±0.2 Myr ago.     

Yearly and seasonal variations of low albedo surfaces on Mars in the OMEGA/MEx dataset: Constraints on aerosols properties and dust deposits

The time variations of spectral properties of dark martian surface features are investigated using the OMEGA near-IR dataset. The analyzed period covers two Mars years, spanning from early 2004 to early 2008 (includes the 2007 global dust event). Radiative transfer modeling indicates that the apparent albedo variations of low to mid-latitude dark regions are consistent with those produced by the varying optical depth of atmospheric dust as measured simultaneously from the ground by the Mars Exploration Rovers. We observe only a few significant albedo changes that can be attributed to surface phenomena. They are small-scaled and located at the boundaries between bright and dark regions. We then investigate the variations of the mean particle size of aerosols using the evolution of the observed dark region spectra between 1 and 2.5 μm. Overall, we find that the observed changes in the spectral slope are consistent with a mean particle size of aerosols varying with time between 1 and 2 μm. Observations with different solar zenith angles make it possible to characterize the aerosol layer at different altitudes, revealing a decrease of the particle size of aerosols as altitude increases.     

Spectral properties and composition of potentially hazardous Asteroid (99942) Apophis

The known close approach of Asteroid (99942) Apophis in April 2029 provides the opportunity for the case study of a potentially hazardous asteroid in advance of its encounter. The visible to near-infrared (0.55 to 2.45 μm) reflectance spectrum of Apophis is compared and modeled with respect to the spectral and mineralogical characteristics of likely meteorite analogs. Apophis is found to be an Sq-class asteroid that most closely resembles LL ordinary chondrite meteorites in terms of spectral characteristics and interpreted olivine and pyroxene abundances, although we cannot rule out some degree of partial melting. A meteorite analog allows some estimates and conjectures of Apophis' possible range of physical properties such as the grain density and micro-porosity of its constituent material. Composition and size similarities of Apophis with (25143) Itokawa suggest a total porosity of 40% as a “current best guess” for Apophis. Applying these parameters to Apophis yields a mass estimate of 2×¹⁰¹⁰ kg with a corresponding energy estimate of 375 Mt for its potential hazard. Substantial unknowns, most notably the total porosity, allow uncertainties in these mass and energy estimates to be as large as factors of two or three.     

The haze and methane distributions on Uranus from HST-STIS spectroscopy

We analyzed a unique, three-dimensional data set of Uranus acquired with the STIS Hubble spectrograph on August 19, 2002. The data covered a full afternoon hemisphere at 0.1 arc-sec spatial resolution between 300 and 1000 nm wavelength at 1 nm resolution. Navigation was accurate to 0.002 arc-sec and 0.02 nm. We tested our calibration with WFPC2 images of Uranus and found good agreement. We constrained the vertical aerosol structure with radiative transfer calculations. The standard types of models for Uranus with condensation cloud layers did not fit our data as well as models with an extended haze layer. The dark albedo of Uranus at near-infrared methane windows could be explained by methane absorption alone using conservatively scattering aerosols. Ultraviolet absorption from small aerosols in the stratosphere was strongest at high southern latitudes. The uppermost troposphere was almost clear, but showed a remarkable narrow spike of opacity centered on the equator to 0.2° accuracy. This feature may have been related to influx from ring material. At lower altitudes, the feature was centered at 1-2° latitude, suggesting an equatorial circulation toward the north. Below the 1.2 bar level, the aerosol opacity increased some 100 fold. A comparison of methane and hydrogen absorptions contradicted the standard interpretation of methane band images, which assumes that the methane mixing ratio is independent of latitude and attributes reflectivity variations to variations in the aerosol opacity. The opposite was true for the main contrast between brighter high latitudes and darker low latitudes, probing the 1-3 bar region. The methane mixing ratio varied between 0.014 and 0.032 from high to low southern latitudes, while the aerosol opacity varied only moderately with latitude, except for an enhancement at −45° latitude and a decrease north of the equator. The latitudinal variation of methane had a similar shape as that of ammonia probed by microwave observations at deeper levels. The variability of methane challenges our understanding of Uranus and requires reconsideration of previous investigations based on a faulty assumption. Below the 2 bar level, the haze was thinning somewhat. Our global radiative transfer models with 1° latitude sampling fit the observed reflectivities to 2% rms. The observed spectra of two discrete clouds could be modeled by using the background model of the appropriate latitude and adding small amounts of additional opacity at levels near 1.2 bar (southern cloud) and levels as high as 0.1 bar (northern cloud). These clouds may have been methane condensation clouds of low optical depth (∼0.2).     

Water sorption on martian regolith analogs: Thermodynamics and near-infrared reflectance spectroscopy

The near-infrared reflectance spectra of the martian surface present strong absorption features attributed to hydration water present in the regolith. In order to characterize the relationships between this water and atmospheric vapor and decipher the physical state of water molecules in martian regolith analogs, we designed and built an experimental setup to measure near-IR reflectance spectra under martian atmospheric conditions. Six samples were studied that cover part of the diversity of Mars surface mineralogy: a hydrated ferric oxide (ferrihydrite), two igneous samples (volcanic tuff, and dunite sand), and three potential water rich soil materials (Mg-sulfate, smectite powder and a palagonitic soil, the JSC Mars-1 regolith stimulant). Sorption and desorption isotherms were measured at 243 K for water vapor pressure varying from 10⁻⁵ to ∼0.3 mbar (relative humidity: 10⁻⁴ to 75%). These measurements reveal a large diversity of behavior among the sample suite in terms of absolute amount of water adsorbed, shape of the isotherm and hysteresis between the adsorption and desorption branches. Simultaneous in situ spectroscopic observations permit a detailed analysis of the spectral signature of adsorbed water and also point to clear differences between the samples. Ferric (oxy)hydroxides like ferrihydrite or other phases present in palagonitic soils are very strong water adsorbent and may play an important role in the current martian water cycle by allowing large exchange of water between dust-covered regions and atmosphere at diurnal and seasonal scales.