简单海气耦合的线性和非线性Rossby波

采用忽略Ｒｅｙｌｅｉｇｈ摩擦和Ｎｏｗｔｏｎ冷却的定常，线性大气模式和地转动量近似下的非线性海洋模式。这里包含了大气通过线性风应力影响海洋，海洋通过加热过程影响大气的物理机制。用相平面理论讨论了海气耦合作用对简单耦合线Ｒｏｓｓｂｙ波和非线性Ｒｏｓｓｂｙ波的影响。     

用地面伽玛能谱资料估计地层(体)的含铀性和资源量

本文论述用地面伽玛能谱资料估计地层(体)含铀性和资源量方法,并提出富铀富集体、铀源富集体、尤其富铀源富集体是最有利于成矿的结论。     

A Coupled General Circulation Model for the Tropical Pacific Ocean and Global Atmosphere

On the basis of Zeng’s theoretical design, a coupled general circulation model (CGCM) is developed with its characteristics different from other CGCMs such as the unified vertical coordinates and subtraction of the standard stratification for both atmosphere and ocean, available energy consideration, and so on. The oceanic component is a free surface tropical Pacific Ocean GCM between 30oN and 30oS with horizontal grid spacing of 1o in latitude and 2o in longitude, and with 14 vertical layers. The atmospheric component it a global GCM with low-resolution of 4o in latitude and 5o in longitude, and two layers or equal man in the vertical between the surface and 200 hPa. The atmospheric GCM includes comprehensive physical processes. The coupled model is subjected to seasonally-varying cycle. Several coupling experiments, ranging from straight forward coupling without flux correction to one with flux correction, and to so-called predictor-corrector monthly coupling (PCMC), are conducted to show the existence and final controlling of the climate drift in the coupled system. After removing the climate drift with the PCMC scheme, the coupled model is integrated for more than twenty years. The results show reasonable simulations of the annual mean and its seasonal cycle of the atmospheric and oceanic circulation. The model also produces the coherent interannual variations of the climate system, manifesting the observed El Ni?o / Southern Oscillation (ENSO).     

The Interannual Variability of Climate in a Coupled Ocean-Atmosphere Model

In this paper, the interannual variability simulated by the coupled ocean-atmosphere general circulation model of the Institute of Atmospheric Physics (IAP CGCM) in 40 year integrations is analyzed, and compared with that by the corresponding IAP AGCM which uses the climatic sea surface temperature as the boundary condition in 25 year integrations.The mean climatic states of January and July simulated by IAP CGCM are in good agreement with that by IAP AGCM, i.e., no serious ‘climate drift’ occurs in the CGCM simulation. A comparison of the results from AGCM and CGCM indicates that the standard deviation of the monthly averaged sea level pressure simulated by IAP CGCM is much greater than that by IAP AGCM in tropical region. In addition, both Southern Oscillation (SO) and North Atlantic Oscillation (NAO) can be found in the CGCM simulation for January, but these two oscillations do not exist in the AGCM simulation.The interannual variability of climate may be classified into two types: one is the variation of the annual mean, another is the variation of the annual amplitude. The ocean-atmosphere interaction mainly increases the first type of variability. By means of the rotated EOF, the most important patterns corresponding to the two types of interannual variability are found to have different spatial and temporal characteristics.     

激光热透镜光谱法测定地质样品中微量钼的研究

作者对激光热透镜光谱法测定微量钼进行了研究．试验表明，在丙酮介质中，Ｍｏ６＋能被还原成Ｍｏ５＋并形成钼蓝同多酸，最大吸收彼长在６７０ｕｍ处，利用Ｈｅ－Ｎｅ激光器输出的６３２．８ｕｍ的激光作光源，进行微量钼的热透镜法分析测定．两酮的存在能增强热透镜信号强度。钼含量在０．０１—２．０μｇ／ｍＬ范围内与激光热透镜信号强度呈良好的线性关系，方法检出限为０．００５μｇ／ｍＬ钼，已用于地质样品中微量钼的高灵敏度测定．结果满意．     

X射线荧光光谱分析检出限问题的探讨与建议

对有关X射线荧光光谱分析低含量元素的检出限问题进行了多方面的探讨。从检出限的定义及其定义下的相对标准偏差到各种不同测量、校准与校正方法的检出限及其相对应的相对标准偏差进行计算。提出了以定义检出限的相对标准偏差为基准,对各种测量方法计算出的检出限进行重新界定,从而确认一个具有可比性的、精度一致的检出限。同时还讨论了仪器与X光管固有杂质元素谱线对该元素检出限的影响;测量仪器、测量条件与测量时间对检出限的影响;不同岩性试样对检出限的影响;检出限与测定限等问题。     

Analyses of trace elements on quartz surfaces in sulfidic mine tailings from Kristineberg (Sweden) a few years after remediation

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) has been applied to determine the elemental composition of the surface layer, as well as of the first interior layer, of quartz grains from the mine tailings from Kristineberg (northern Sweden) in order to determine concentration gradients between these two layers. The quartz grains were collected from the oxidized and unoxidized zones within the tailings. The aim of this study is to assess the role of quartz surfaces as sites for the attenuation of solutes from the mine-tailings porewater. Concentrations of Cu, Ag, Sb, Pb and Bi are highest near the surface of each grain and decrease towards the interior. The surface concentration of Cu, Zn and Pb is more pronounced within the unoxidized than within the oxidized zone of the tailings. Cu exhibits a distinct concentration peak at the surface of the quartz grains below the pre-remediation oxidation front. For Zn and Ce the trend of high surface concentration is less pronounced than for Cu or Pb. Silver, Bi and As are preferably adsorbed within the uppermost layers of the oxidized zone where the pH is as high as 6.2. The conversion of intensity signals of the elements to concentration values in ppm was done by using external standards (NIST silicate glass).     

高精度热电离质谱(TIMS)铀系法洞穴沉积物(石笋)年龄的研究

用高精度热电离质谱技术测定石笋的年龄,初步建立了热电离质谱铀系年龄的方法。 4个样品的测定结果复现性较好,铀含量、同位素比值及年龄值与标准值吻合,数据的精度大大提高,显示了质谱铀系年龄方法具有样品量少、时间短、精度高的优点。     

电感耦合等离子体发射光谱法测定键合用硅铝丝中硅铁铜

采用电感耦合等离子体发射光谱法测定硅铝丝（Al—1％Si）中Si及杂质元素Fe和Cu。确定了最少取样量和样品溶解方法，优化了元素分析谱线和仪器的测量条件。实验表明，方法的加标回收率为99％～1叭％，相对标准偏差（n=6）低于1．4％，Si、Fe、Cu的检出限分别为8．5、1．0和0．4μg／L。该方法应用于快速测定键合硅铝丝中的各种元素，结果满意。     

一种获取包裹体内压的新方法——二氧化碳拉曼光谱法

对CO2的拉曼光谱特征做了介绍，特别指出了CO2费米共振峰随温度和压力的变化特点。利用CO2费米共振峰与密度的关系，结合状态方程对山东昌乐一临朐地区的火山岩包裹体进行了研究，获得了该地区火山岩包裹体的现实内压。结果表明，该地区包裹体的现实内压主要集中在5．75—18．29MPa。简单恢复了包裹体的形成深度，经与前人研究成果对比，显示该方法具有一定的可靠性。这种方法可以作为获取合CO2包裹体内压的一种新方法。