长江口悬沙颗粒的现场测量

我们利用自．行研制的“光学悬浮沙粒径谱仪”对长江口悬沙颗粒进行了现场测量,同时作了现场采样,经华东师范大学河口海岸国家重点实验室分析,分析结果与仪器现场测量结果进行了对比,结果表明,两种方法得到的平均粒径和悬沙浓度基本一致。     

Characterization of Estuarine Marine Clays for Coastal Reclamation in Pusan, Korea

Large scale reclamation works in coastal areas of the Nakdong River plain are at various stages of progress, since early 1990's on in-situ soft marine clay deposits. These deposits are of the order of 30 to 40 m thick. A realistic rapid characterization of soft ground would ensure success of any reclamation work in this area. In order to cope with the work carried out with different agencies, it is desirable to evolve a systematic methodology. In this study, engineering properties of clays at three coastal areas, Gadukdo, Noksan and Shinho, have been generated. The analysis of data has been done within the framework of classical developments in soil mechanics. Analysis has also been made by making use of the recent developments in dealing with soft clays. The dominant factors, namely, stress, time, and environment influencing the response of clay to loading are identified.     

吐哈盆地侏罗纪煤中主要组分结构特征与生烃性分析

在高纯度煤岩显微组分分离富集的基础上,应用透射式显微傅里叶红外光谱技术 (Micro FTIR),对吐哈盆地侏罗纪煤中的主要组分-镜质体、丝质体、角质体、藻类体的结构组成进行了测定。结果表明 :藻类体主要由长链脂族结构组成,芳香结构含量相对较少;角质体和基质镜质体中含有较丰富的芳香结构以及长链脂族结构;而丝质体则主要由芳香结构组成,脂族结构含量很少。显微组分的这种结构特征决定了藻类体具有很高的生烃潜力、角质体和镜质体的生烃潜力中等、而丝质体的生烃潜力则很低。对于吐哈盆地煤成油来说,由于藻类体主要由长链脂族结构组成,并且生烃潜力也高,因此其具有高的液态烃产率、丝质体的产油率最小、角质体和镜质体的液态烃产率中等。由于镜质体是本区煤中含量最高的组分。因此,对于吐哈盆地所形成的具有工业规模的油田来说,镜质体应该是主要的贡献组分之一。但对于富含藻类体的厚层状烛藻煤,由于它类型好,品质高、生烃潜力大、以中长链脂族结构为主,是煤成油最理想的源岩。     

Storm surge induced flux through multiple tidal passes of Lake Pontchartrain estuary during Hurricanes Gustav and Ike

In September 2008, Hurricanes Gustav and Ike generated major storm surges which impacted the Lake Pontchartrain estuary in Louisiana. This paper presents analyses of in situ measurements acquired during these storm events. The main data used in the analyses were from three bottom mounted moorings equipped with conductivity, temperature, and depth sensors, acoustic Doppler current profilers (ADCPs), and a semi-permanent laterally mounted horizontal acoustic Doppler profiler (ADP). These moorings were deployed in the three major tidal channels that connect Lake Pontchartrain with the coastal ocean. A process similar to tidal straining was observed: the vertical shear of the horizontal velocity was negligible during the inundation stage, but a shear of 0.8 m/s over a less than 5 m water column was recorded during the receding stage, 2–3 times the normal tidal oscillations. The surge reached its peak in the Industrial Canal 1.4–2.1 h before those in the other two channels. The inward flux of water lasted for a shorter time period than that of the outward flux. The inward flux was also observed to have much smaller magnitude than the outward flux (∼960–1200 vs. 2100–3100 million m³). The imbalance was believed to have been caused by the additional water into Lake Pontchartrain through some small rivers and inundation over the land plus rainfall from the hurricanes. The flux through the Industrial Canal was 8–12%, while the flux through the other two tidal passes ranged between 17% and 70% of the total, but mostly split roughly half-half of the remaining (∼88–92% of the total).     

继承性宇生核素对暴露测年结果影响的定量分析方法探讨

宇生核素暴露测年过程中,通常假设在样品最后一次暴露前,样品中的宇生核素（继承性宇生核素）浓度为0。然而,大量的测年数据研究发现,样品的暴露年代结果会受到继承性核素的影响从而高估地貌的真实年代。因此,如何降低继承性核素对暴露年代结果的影响或者定量分析继承性核素的影响程度不仅可为地貌演化提供准确的年代数据,而且对宇生核素暴露测年技术的研究具有重要意义。因此,本文以宇生核素暴露测年技术在冰川地貌中应用为例,通过分析继承性核素的研究概况,并结合宇生核素暴露测年原理,探讨继承性核素对测年结果影响的定量分析方法。研究结果表明： ① 通过样品中 n ( 26 Al)/ n ( 10 Be) 值\[即同一样品中宇生核素Al 26 与Be 10 浓度（单位为atom/g）的比值\]以及同一地貌位置多个的样品年代数据分布情况可初步判断测年结果是否受到继承性核素的影响;② 通过现代冰川冰碛物中宇生核素的浓度可以定量分析继承性核素对暴露测年结果的影响; ③ 通过计算冰碛垄顶部和一定深度（＞2~3 m）样品的宇生核素浓度差,可以减少继承性核素的影响。本研究内容对冰川地貌宇生核素暴露测年具有重要意义。     

芦山地震前后龙门山断裂带西南段地应力状态对比分析

2013年4月20日芦山Ms7.0级地震后,为研究龙门山断裂带西南段震后的地应力状态,应用水压致裂法和压磁应力解除法在该区开展了2个钻孔的原地应力测量工作。测量结果显示硗碛测点在128～188m深度范围内最小水平主应力的量值为10.47～18.47 MPa,最大水平主应力的量值为19.60～25.83 MPa,方向为N63°～85°W;天全测点在114～142m深度范围内最小水平主应力的量值为5.20～7.73 MPa,最大水平主应力的量值为8.21～9.31 MPa,方向为N59°W。两个测点水平主应力与垂直应力的关系均为σ_Hσ_hσ_v,其中硗碛测点最大、最小水平主应力与垂直应力比值的平均值分别为5.27和3.01,天全测点最大、最小水平主应力与垂直应力比值的平均值分别为2.60和1.76,表明有利于逆断层活动。通过比较该地区芦山地震前后实测地应力状态,发现芦山地震后,龙门山断裂带西南段的北段(即邛崃大邑西-宝兴北-汶川南一带)和南段(即天全-荥经-泸定-康定一带)应力积累量增加。相同深度范围内,北段硗碛测点震后的应力大小要比地震前有明显的提高,这也与硗碛测点地应力监测结果一致。实测应力方向与震前基本一致,都为NW-NWW。基于实测地应力资料,根据库伦破裂准则和Byerlee定律分析,位于北段的硗碛测点震前部分压裂段的最大水平主应力处于使断层滑动临界值的上下限之间,而地震后最大水平主应力则均已超过断层滑动临界值的上限。位于南段的飞仙关测点震前最大水平主应力均未达到断层滑动临界值的下限,而地震后天全测点的最大水平主应力则均处于使断层滑动临界值的上下限之间。采用最大剪应力(σ_1-σ_3)/2与平均应力(σ_1+σ_3)/2的比值μ_m(断层摩擦)参数评估研究区地应力的积累水平和地震危险性。震前硗碛测点μ_m的量值为0.16～0.72,平均为0.50,震后为0.71～0.81,平均为0.77。震前飞仙关测点μ_m的量值为0.31～0.35,平均值为0.32,震后天全测点μ_m的量值为0.53～0.57,平均值为0.55,两个研究区的μ_m的量值均变大。分析认为芦山地震后龙门山断裂带西南段的北段和南段的应力积累量增加,都有发生断层滑动的可能性,尤其是北段。     

FTIR studies of reactions between the nitrate radical and haloethenes

Products and mechanisms for the gas-phase reactions of NO₃ radicals with CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂,cis-CHCl=CHCl andtrans-CHCl=CHCl in air have been studied. The experiments were carried out at 295±2 K and 740±5 Torr in a 480-L Teflon-coated reaction chamber and at 295±2 K and 760±5 Torr in a 250-L stainless steel reactor. NO₃ was generated by the thermal dissociation of N₂O₅. Experiments with¹⁵NO₃ and CD₂CDCl have also been performed. The initially formed nitrate peroxynitrates decay into carbonyl compounds, nitrates, HCl and ClNO₂. In adidtion, there are indications of nitrooxy acid chlorides being produced. The reactions with CH₂=CCl₂ and CHCl=CCl₂ are more complex due to release of chlorine atoms which eventually lead to formation of chloroacid chlorides.A general reaction mechanism is proposed and the observed concentration-time profiles of reactants and products are simulated for each compound. The rate constants for the initial step of NO₃ addition to the chloroethenes are determined as: (2.6±0.5, 9.4±0.9, 2.0±0.4 and 1.4±0.4) × 10^–16 cm³ molecule^–1 s^–1 for CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂ andcis-CHCl=CHCl, respectively.     

考虑洞室岩体应力型破坏特征的局部地应力反演方法及应用

介绍了一种考虑地下洞室片帮、钻孔剥落等岩体应力型破坏特征为信息源,通过数值模拟智能反演方法预测高应力大型地下洞室群围岩局部应力场的新思路。该方法将地下洞室群片帮、钻孔剥落等应力型破坏的位置、深度或者宽度进行定量描述,以弹性模型计算获得的常偏应力大于岩体启裂强度的范围来表示应力型破坏范围,通过分析实测地应力数据约束部分地应力数量,然后采用智能数值反演方法得到其他的地应力分量。采用该方法预测了白鹤滩水电站右岸地下厂房0+76断面附近围岩地应力场,反演获得最大主应力在34 MPa左右。通过其他部位岩体破裂的数值模拟和观测结果对比,验证了地应力场预测的合理性。     

Evaluation of one-dimensional in situ leaching processes

A methodology to characterizing processes of in situ leaching is developed to investigate various parameters that may affect the recovery of a valuable mineral and assure a successful application of the in situ leaching technology. The governing equations of in situ leaching processes for the one-dimensional case are solved both analytically and numerically for both the consumption rate of a lixiviant and the production rate of a target mineral. A numerical simulator, which is developed to evaluate coupled effects among leaching kinetics, solution flow and transport of the dissolved mineral species in saturated ore deposits, is validated against the steady-state solutions and applied to investigate the transient effects of various parameters on the mineral recovery. Results from the evaluation indicate that there exists an optimal flow velocity range of leach solution for the effective leaching of a particular ore deposit. The determination of this optimal leaching velocity may become a key to the design of a real in situ leach mine. Results of the parameter sensitivity study illustrate the relative importance of other parameters such as porosity, ore grade, and reaction rate. Copyright © 1999 John Wiley & Sons, Ltd.     

中国大陆科学钻探主孔榴辉岩中石榴石和绿辉石原位激光探针分析及其成岩成矿指示意义

本文以中国大陆科学钻探主孔0～2000m岩芯中的榴辉岩为对象,运用EMPA和LA-ICP-MS技术,系统测定了榴辉岩中石榴石和绿辉石的主量与微量元素组成,并据此讨论了它们的成岩成矿意义.研究结果表明,CCSD主孔榴辉岩中石榴石富重稀土和Sc、Y、Co,而绿辉石则富中稀土和Pb、Sr、V,石榴石和绿辉石的高场强元素(特别是Nb、Ta)含量均很低.石榴石存在不同程度的Ce负异常,指示榴辉岩的形成过程中卷入有地表氧化条件下形成的风化沉积物.石榴石具有低的Zr/Y比值,绿辉石普遍具有高的Sr含量,这些特征说明榴辉岩(特别是高钛榴辉岩)的原岩可能为遭受过壳源物质混染与交代的富集地幔部分熔融的产物.高钛与低钛榴辉岩中石榴石和绿辉石在主量及微量元素组成上存在一定差别,总体而言,高钛榴辉岩中石榴石具高的MgO含量和较高的MgO/TFeO比值,以及较高的稀土和Sc含量,而绿辉石则相对富TFeO、MnO,并具有较高的Sr、Zr、Hf含量.高钛榴辉岩中石榴石和绿辉石常出现不同程度的Eu正异常,Cr含量均显著低于低钛榴辉岩.综合分析表明,高钛榴辉岩的原岩最可能为富斜长石的辉长质侵入岩,原岩组成的差异应是导致二类榴辉岩中石榴石和绿辉石矿物化学组成存在差异的主要原因.