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71.
72.
Sorption of heavy metal cations (Pb(II), Cr(III), Cd(II), Ni(II)) from aqueous solutions on natural Na-clinoptilolite was studied using atomic absorption spectrometry (AAS) and FT-IR spectroscopy. It was found that the sorption capacity of clinoptilolite decreases in the following order: Pb(II) (22,600 mg/kg), Cr(III) (21,200 mg/kg), Cd(II) (10,400 mg/kg) and Ni(II) (6,200 mg/kg). In the FT-IR spectra of the samples, in the region of pseudolattice vibrations (500–800 cm–1), systematic changes connected with the type of cation and its concentration in the initial solution were observed. The proportions of ion exchange and chemisorption in the whole process of sorption were also estimated. It was found that the amount of cations sorbed on clinoptilolite depended on the concentrations and pH of the solutions used as well as on the contact time of zeolite-solution system. After 120 min of the reaction, despite the metal type, 90–100% of the total amount of cations were immobilized. 相似文献
73.
Atomistic computer simulation techniques have been employed to model mechanisms of hydrogen incorporation in the clinopyroxenes diopside and jadeite. Calculation of solution reaction energies for the pure phases indicates that hydrogen is most easily incorporated via the formation of [VSi(OH)4]
x
hydrogarnet type defects. When components of the two phases are mixed, then solution energies can become exothermic. The substitution of Al for Si in diopside and of Mg or Ca for Al in jadeite, provides favourable routes for hydrogen incorporation, with exothermic values of solution energy. Thus the amount of water present in these minerals in the Earth’s upper mantle will vary with composition. Simulation of IR frequencies associated with O–H stretching at specific defect clusters has also been carried out. An analysis of hydrogen–oxygen bond lengths gives good agreement, although comparison of experimental and calculated IR frequencies are problematic. This is partly due to the complexity of experimental spectra, but may also be due in part to deficiencies in the ability of the model to accurately describe the O–H stretching frequency. 相似文献
74.
29Si,27Al MAS NMR and IR spectra of rnonophase K-feldspars (sanidine, orthoclase and microcline) and Na-feldspars (monalbite, anorthoclase
and low albite) in different structural states have been studied. The NMR and IR spectra of K-feldspars and Na-feldspars vary
regularly along with their degrees of Si/Al ordering evolution. Si in orthoclase occupiesT
2m,T2o andT1m, and the high-temperature Na-feldspar (monalbite and anorthoclase) coincides in29Si,27Al NMR and IR spectra. Moreover, all the high-temperature Na-feldspars and sanidine have the same27Al NMR and IR spectra.
Project supported by the Foundation of Laboratory of Magnetic Resonance and Atom and Molecular Physics, Wuhan Institute of
Physics, Chinese Academy of Sciences. 相似文献
75.
Peptides were released from organic matter fractions of three Italian soils (humin, humic and fulvic acids), when the samples were hydrolyzed in Ba(ON)2-saturated solution at 105°C for 2 hr. The peptides obtained were separated using electrophoresis and paper chromatography. The presence of polypeptides in the soil organic matter was indicated by: (1) their hydrolysis by pronase; (2) the amino acids released by 6 N HCl hydrolysis; (3) The comparison of i.r. spectra of humic fractions before and after hydrolysis with 6 N HCl.Attempts at isolating the native proteinaceous compounds using electrophoresis in polyacrylamide gel failed; additionally, our attempts to hydrolyze proteinaceous components enzymatically in unfractionated soil organic matter, as well as in its fractions, before and after methylation, with pepsin, papain and pronase, were unsuccessful. Pronase demonstrated a weak proteolytic activity only at very low substrate-enzyme ratios (20 : 1) in humic and fulvic fractions and in whole phyrophosphate extract. Deproteinated substrates treated with pronase also released free amino acids, suggesting autodigestion.In humin, humic and fulvic fractions we found a total amino acid content of 40–45%, 12–24% or 1–85, respectively. Amino acid recovery from single fractions was about 70–80% of the total content in the unfractionated soil. 相似文献
76.
Ian Mclean 《Experimental Astronomy》1994,3(1-4):235-238
In less than a decade, infrared array detectors have revolutionized infrared astronomy. Most of us remember using single element photometers in the early eighties, yet today, most of us are using 256×256 pixel arrays. At this meeting we have heard of plans to fabricate 1024×1024 arrays in the near infrared. From one to one million pixels in such a short period of time is amazing. The new array technology has also stimulated the development of many varieties of infrared cameras and spectrometers. At the UCLA Infrared Imaging Detector Lab we have commissioned two near infrared imaging systems (KCam and Gemini) based on 256×256 arrays and a spectrometer design study is in progress for 1024×1024 arrays. Performance of these cameras on the telescope will be reported briefly. 相似文献
77.
卫星热红外观测进行地震预报的可能性分析 总被引:2,自引:1,他引:2
阐述了低空大气卫星热红外增温的理论基础,及与其他异常的关系。简述了地震前低空大气卫星热红外增温的普遍性,卫星热红外观测技术的特点和问题,及利用低空大气卫星热红外增温预报地震的可能性。 相似文献
78.
IR properties of Compact Group (CG) galaxies are presented and compared with IR properties of isolated galaxies. Despite CGs
displaying more E-S0s and optically bright galaxies, no differences are retrieved concerning FIR emission. The observed lack
of strong FIR enhancement in the CG sample is not surprising when interpreting FIR sources in CGs as accordant redshift projections,
rather than as mergers in progress.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
79.
V.H. Tyne A. Evans B. Smalley T.R. Geballe S.P.S. Eyres 《Astrophysics and Space Science》2002,279(1-2):139-147
We follow the evolution of the infrared excess and the dustshell of Sakurai's Object by modelling the dust emission. The optical depth,dust temperature, and shell thickness parameters from the models are presented.Fits of DUSTY models to infrared spectra between 1997 May and 1999September illustrate the development of the dust from small grains to a rangeof grain sizes with an almost constant 60% graphite – 40% amorphous carbonmixture. The size of the infrared emitting region continues to growand may now be big enough to resolve. This may help to answerquestions such as the morphology of the dust shell, and whether the dustshell is `blobby' or smooth. 相似文献
80.
We report a V band photometry of the SU UMa star IR Gem at quiescence in January 2002. The observations were made with two telescopes spaced - 160° apart in longitude. Several photometric modulations have been found. One gives a period of 98.50(13) min, exactly equal to the orbital period determined spectroscopically. Two others occasionally strengthen and seem to be positive and negative superhumps with periods of 103.6(4) and 95.4(4) min, 5.2% longer and 3.1% shorter than the orbital period, respectively. A signal at - 0.6 c/d in the power spectrum is roughly consistent with the expected period of nodal precession of the disk. There is a puzzling peak at 0.21(3) c/d corresponding to the - 4.3 d sine wave seen in the raw light curve. We suspect it to be a beat frequency between the frequencies of apsidal and nodal precessions of the disk. Quasi-periodic cycles with amplitudes 0.15-0.6 mag can be seen in the light curve. The mechanism underlying this modulation is not clear. 相似文献