Chronology, Geochemistry and Tectonic Settings of the Hadamiao Granodiorite on the Northern Margin of the North China Platform

<正>The Hadamiao granodiorite,located on the northern margin of the North China platform and acting as the country rock of gold deposits in the Hadamiao region,was formed in the same age and similar tectonic settings with the Hadamiao gold deposit and the large-scale Bilihe gold deposit in the same area.By using the LA-ICP-MS method,the U-Pb age obtained is 267±1.3 Ma,which represents the crystallized age of the granodiorite,and that of the xenolithic zircon is 442.8±5 Ma. Base on the main elements,it exhibits the features of calc-alkaline to high-potassium calc-alkaline series,low silicon,and quasi-aluminous I-type granites,and with high magnesium(Mg~#=0.45-0.57) and high sodium contents(Na_2O/K_2O=0.98-2.29).The SREE values(81.6-110.15 ppm) are relatively low,the fractionations between LREE and HREE are obvious,showing a right-inclined dispersion in the REE distribution diagram.Compared with the primitive mantle,the rock is relatively rich in LREE(La and Ce),LILE(K,Sr,and Th),and intensively depleted in HFSE(Ti,P,Nb and Ta).The ratios of Sr/Y and(La/Yb)_N and the contents of Rb,Nb and Y are relatively low,the Sr values are high (436.35-567.26 ppm),and the Yb contents of most samples are low(1.25-1.8),which indicate the features of typical continental margin arc and adakitic rocks.According to the values ofε_(Nd)(t)(-2.4 to +0.2) and I_(Sr)(0.7028-0.7083),and variations of the La/Sm ratios,the Hadamiao granodiorite was formed from mixing of the thickened molten lower crust and the mantle wedge substances.The rock was related to the southward subduction and accretion of the Paleo-Asia Ocean in the Late Paleozoic, being Late Paleozoic magma of the continental margin arc formed on the basement of the Early Paleozoic accretion complexes,and showing a trend of turning into adakitic rocks,which indicates their great metallogenic(Au) potential.     

Calcium,Na, K and Mg Concentrations in Seawater by Inductively Coupled Plasma‐Atomic Emission Spectrometry: Applications to IAPSO Seawater Reference Material,Hydrothermal Fluids and Synthetic Seawater Solutions

We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q^® water. We obtained an average reference value r_K (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg^?1)/(g kg^?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to r_Na, r_Ca and r_Mg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.     

Sulfur Concentration in Geochemical Reference Materials by Solution Inductively Coupled Plasma‐Mass Spectrometry

With implications for the origin of ore deposits, redox state of the atmosphere, and effects of volcanic outgassing, understanding the sulfur cycle is vital to our investigation of Earth processes. However, the paucity of sulfur concentration measurements in silicate rocks and the lack of well‐calibrated reference materials with concentrations relevant to the rocks of interest have hindered such investigations. To aid in this endeavour, this study details a new method to determine sulfur concentration via high mass resolution solution inductively coupled plasma‐mass spectrometry (ICP‐MS). The method is based on an aqua regia leach, involving relatively rapid sample preparation and analysis, and uses small test portion masses (< 50 mg). We utilised two independently prepared standard solutions to calibrate the analyses, resulting in 4% accuracy, and applied the method to eight geochemical reference materials. Measurements were reproducible to within ~ 10%. Sulfur concentrations and isotopes of six reference materials were measured additionally by elemental analyser‐combustion‐isotope ratio mass spectrometry to independently evaluate the accuracy of the ICP‐MS method. Reference materials that yielded reproducible measurements identical to published values from other laboratories (JGb‐1, JGb‐2 and MAG‐1) are considered useful materials for the measurement of sulfur. Reference materials that varied between studies but were reproducible for a given test portion perhaps suffer from sample heterogeneity and are not recommended as sulfur reference materials.     

Precise and Accurate In Situ Determination of Lead Isotope Ratios in NIST,USGS, MPI‐DING and CGSG Glass Reference Materials using Femtosecond Laser Ablation MC‐ICP‐MS

Lead isotope ratio data were obtained with good precision and accuracy using a 266 nm femtosecond laser ablation (fLA) system connected to a multi‐collector ICP‐MS (MC‐ICP‐MS) and through careful control of analytical procedures. The mass fractionation coefficient induced by 266 nm femtosecond laser ablation was approximately 28% lower than that by 193 nm excimer laser ablation (eLA) with helium carrier gas. The exponential law correction method for Tl normalisation with optimum adjusted Tl ratio was utilised to obtain Pb isotopic data with good precision and accuracy. The Pb isotopic ratios of the glass reference materials NIST SRM 610, 612, 614; USGS BHVO‐2G, BCR‐2G, GSD‐1G, BIR‐1G; and MPI‐DING GOR132‐G, KL2‐G, T1‐G, StHs60/80‐G, ATHO‐G and ML3B‐G were determined using fLA‐MC‐ICP‐MS. The measured Pb isotopic ratios were in good agreement with the reference or published values within 2s measurement uncertainties. We also present the first high‐precision Pb isotopic data for GSE‐1G, GSC‐1G, GSA‐1G and CGSG‐1, CGSG‐2, CGSG‐4 and CGSG‐5 glass reference materials obtained using the femtosecond laser ablation MC‐ICP‐MS analysis technique.     

Geochemistry,and zircon U–Pb and molybdenite Re–Os geochronology of Jilongshan Cu–Au deposit,southeastern Hubei Province,China

The Jilongshan skarn Cu–Au deposit is located at the Jiurui ore cluster region in the southwestern part of the Middle–Lower Yangtze River valley metallogenic belt. The region is characterized by NW‐, NNW‐ and EW‐trending faults and the mineralization occurs at the contact of lower Triassic carbonate rocks and Jurassic granodiorite porphyry intrusions. The intrusives are characterized by SiO₂, K₂O, and Na₂O concentrations ranging from 61.66 to 67.8 wt.%, 3.29 to 5.65 wt.%, and 2.83 to 3.9 wt.%, respectively. Their A/CNK (A/CNK = n(Al₂O₃)/[n(CaO) + n(Na₂O) + n(K₂O)]) ratio, δEu, and δCe vary from 0.77 to 1.17, 0.86 to 1, and 0.88 to 0.96, respectively. The rocks show enrichment in light rare earth elements ((La/Yb)_N = 7.61–12.94) and large ion lithophile elements (LILE), and depletion in high field strength elements (HFSE), such as Zr, Ti. They also display a peraluminous, high‐K calc‐alkaline signature typical of intrusives associated with skarn and porphyry Cu–Au–Mo polymetallic deposits. Laser ablation inductively coupled plasma spectrometry (LA‐ICP‐MS) zircon U–Pb age indicates that the granodiorite porphyry formed at 151.75 ± 0.70 Ma. A few inherited zircons with older ages (677 ± 10 Ma, 848 ± 11 Ma, 2645 ± 38 Ma, and 3411 ± 36 Ma) suggest the existence of an Archaean basement beneath the Middle–Lower Yangtze River region. The temperature of crystallization of the porphyry estimated from zircon thermometer ranges from 744.3 °C to 751.5 °C, and 634.04 °C to 823.8 °C. Molybdenite Re–Os dating shows that the Jilongshan deposit formed at 150.79 ± 0.82 Ma. The metallogeny and magmatism are correlated to mantle–crust interaction, associated with the subduction of the Pacific Plate from the east. Copyright © 2013 John Wiley & Sons, Ltd.     

顾及城区机载LiDAR数据特征的配准算法

条带配准是点云数据处理的一个重要环节.文章介绍了经典ICP配准算法的基本原理;考虑到城区机载LiDAR数据中地物的组成、空间分布等特征,提出了一种ICP算法中对应点集的选择策略,并建立了城区机载LiDAR数据的自动配准流程.利用河南安阳试验场的真实点云数据进行配准实验,结果表明在不需要人工干预的情况下,可以很好地将条带数据拼接在一起,建立无缝点云数据.     

2021年滦州MS4.3地震和2015年昌黎MS4.2地震震源参数及构造意义研究

基于京津冀地震台网观测资料,利用CAP方法反演滦州M_S4.3地震、昌黎M_S4.2地震及其M_S3.3余震的震源机制,并利用近震深度震相获得更为准确的震源深度,结合双差定位法获得2个地震序列的震源分布结果,对发震构造及成因关联开展分析研究。结果显示：1）滦州M_S4.3地震的节面Ⅰ走向、倾角、滑动角分别为211°、85°、168°,节面Ⅱ分别为302°、78°、5°,震源错动类型为走滑型,震源深度为8 km,地震序列的震源分布呈NNE向,短轴剖面显示断层面倾角近垂直,认为其发震断层面为节面Ⅰ;昌黎M_S4.2地震及M_S3.3余震的节面Ⅰ分别为189°、68°、161°及190°、61°、170°,节面Ⅱ分别为286°、72°、23°及285°、81°、29°,震源错动类型同为走滑型,震源深度为10.5 km,地震序列的震源分布呈NNE向,短轴剖面显示断层面倾角近垂直,认为其发震断层面为节面Ⅰ;2）基于滦州M_S4.3地震、昌黎M_S4.2地震及滦州M_S7.1地震的震源参数结果,结合区域地质构造等资料分析认为,3次地震的发震构造不是上地壳先存断裂,而可能与震源区的深部构造背景密切相关,即壳内包体现象是孕育这些地震的共同基础。     

Changes in the Chemical Components of Light Crude Off During Simulated Short Term Weathering

To unambiguously identify spilled oils and to link them to the known sources are extremely important in settling questions of environmental impact and legal liability. The fate and behavior of spilled oils in the environment depend on a number of physicochemical and biological factors. This paper presents the results regarding changes in chemical composition of light crude oil during simulated short-term weathering based on natural environmental conditions. The results show that the saturated hydrocarbons of the light crude oil mainly distribute between n-C8 and n-C23 and the most abundant n-alkanes are found in the n-C10 to n-C16. The main chemical components of the light crude oil are n-alkanes and isoprenoids. The aromatic compounds are subordinate chemical components. Under the conditions of the weathering simulation experiment,n-alkanes less than n-C12,toluene and 1,3-dimethyl benzene are lost after 1 d weathering,the n-C13,n-C14,naphthalene and 2-methyl-naphthalene are lost on the fifth day of weathering,and n-C15 alkane components show certain weatherproof capability. The ratios n-C17/pristane and n-C18/phytane are unaltered and can be used to identify the source of the light crude oil during the first 8 d of weathering. After 21 d,the ratio pristine/phytane can not provide much information on the source of the spilled light crude oil. Triterpanes（m/z 191） as biomarker compounds of light crude oil are more valuable.     

中祁连地块西段青白口系其它大坂组英安质凝灰岩LA- ICP- MS锆石U- Pb年龄及其地质意义

新元古界青白口系其它大坂组是中祁连地块西段基底岩系之一,对研究中祁连地块元古宙地质构造演化具有重要意义。笔者等通过1∶5万区调工作在其它大坂组中发现了英安质晶屑岩屑凝灰岩夹层,并对凝灰岩进行了锆石U-Pb年代学、岩石地球化学研究。测年结果表明样品中锆石年龄主要分3组。结合区域地质资料,笔者等认为第一组锆石(1456～1524 Ma)和第二组锆石(1018～1021 M)为外来锆石或/碎屑锆石,分别为物源区中元古代早期Columbia超大陆裂解事件和Rodinia大陆聚合事件(格林威尔造山作用)在中祁连地块中的响应;第三组锆石(946～964 Ma)的n(²⁰⁶Pb)/n(²³⁸U)加权年龄为958±3 Ma(MSWD=1.4),代表英安质凝灰岩的形成时代。岩石地球化学分析表明,其它大坂组英安质晶屑岩屑凝灰岩样品属于过铝质(A/CNK=1.37～1.75)、高钾(K₂O>Na₂O,K₂O=4.48%～4.86%)、钙碱性(σ=0.89～1.26)火山岩,稀土总量为(149....     

基于气枪震源信号的云南漾濞MS6.4地震前后波速变化

本文基于宾川气枪地震信号发射台激发的地震波信号,利用线性叠加和时频域相位加权叠加方法提高信噪比,通过反褶积、插值拟合和波形互相关等方法,获得2021年漾濞M;6.4地震前后气枪震源初至波信号走时变化特征.结果表明两种叠加方法得到的走时变化趋势基本一致,在沿发震断裂带附近的3个台站观测到的初至波走时延迟为7.3~14.4 ms,在射线路径上平均波速降低了0.08%~0.12%,距离震中位置较远的台站走时延迟为2~6 ms.分析认为,观测到的走时变化主要是漾濞M;6.4地震引起强地面运动造成浅层介质疏松、同震破裂导致震源区地下介质裂隙增加和地下流体侵入等共同作用造成,相关研究成果有助于加深和促进对此次地震震源物理过程的认识和了解.