Ultrahigh-pressure texture inheritance during retrogression: Evidence from magnetofabrics in eclogites and ultramafic rocks (Chinese Continental Scientific Drilling project)

In order to contribute to a better understanding of exhumation related retrogression processes ultrahigh-pressure (UHP) mafic and ultramafic rocks from the Chinese Continental Scientific Drilling (CCSD) in the Maobei eclogite body of the Sulu ultrahigh-pressure metamorphic belt in eastern China were studied for their magnetofabrics. Variably retrogressed eclogites and serpentinized ultramafic rocks were retrieved from the depth interval of 100 to 1000 m of the borehole. A vein network of irregular shaped veins with a retrograde metamorphic assemblage cuts across the eclogite foliation at both low and high angles. SEM imaging of the eclogites documents that magnetite associated with retrograde pargasitic amphiboles developed around shape-preferred garnet. SEM imaging of the serpentinized ultramafic rocks documents that magnetite rims grew around shape-preferred garnet and that magnetite formed within a mesh texture related to serpentinization. Syn-serpentinization magnetite growth increased bulk susceptibilities, but reduced anisotropy. Maximum susceptibility axes from both eclogites and serpentinized garnet-peridotites trend N-S, i.e. parallel with the stretching lineation as defined by olivine and omphacite grains. This implies that the magnetic fabric mimics the UHP fabric and survived retrogression and that the fabric is inherited from the UHP stage. As a consequence, retrogression was not associated with substantial ductile deformation and the mafic-ultramafic Maobei body behaved as a rigid body within a ductile deforming quartzo-feldspathic matrix during exhumation. Internal strain is restricted to brittle fracturing, associated fluid circulation and vein formation facilitating retrograde reactions in the mafic-ultramafic rocks.     

Mineralization of Catechol by Fenton and Photo‐Fenton Processes

Catechol is one of the most abundant phenolic components of olive mill wastewaters. In this article, the mineralization of this compound in synthetic aqueous solutions by the Fenton and photo‐Fenton processes is studied. It has been found that for 1.44 mM catechol, the total organic carbon of solutions is reduced about 94.4% at best after 60 min of Fenton treatment at optimized conditions of pH 3.0, 0.2 mM Fe²⁺, 7.09 mM H₂O₂, and 25°C. A faster and overall mineralization is attained by applying photo‐Fenton with UVA irradiation. o‐Benzoquinone, 1,2,3‐trihydroxybenzene and 1,2,4‐trihydroxybenzene were identified by GC–MS as primary quinonic and polyhydroxylated derivatives. Small amounts of generated carboxylic acids like muconic, maleic, malonic, acetic, oxalic, and formic acids were detected by ion‐exclusion chromatography. The Fe(III) complexes of these acids persist in the medium under Fenton conditions, while their photolysis by UVA light and that of other by‐products account for by the faster degradation and total mineralization achieved in the photo‐Fenton process. A reaction sequence for catechol mineralization by Fenton and photo‐Fenton involving all intermediates detected is proposed.     

Genesis of garnet peridotites in the Sulu UHP belt: Examples from the Chinese continental scientific drilling project-main hole, PP1 and PP3 drillholes

The main hole (MH), and pre-pilot holes PP1, and PP3 of the Chinese Continental Scientific Drilling Project (CCSD) penetrated three different garnet peridotite bodies in the Sulu ultrahigh pressure (UHP) metamorphic belt, which are 80 m, 120 m, and 430 m thick, respectively. The bodies occur as tectonic blocks hosted in eclogite (MH peridotite) and gneisses (PP1 and PP3 peridotites). The peridotites in the MH are garnet wehrlites, whose protoliths were ultramafic cumulates based on olivine compositions (Fo_79-89) and other geochemical features. Zoned garnet and omphacite (with 4-5 wt.% Na₂O) are typical metamorphic minerals in these rocks, and, along with P-T estimates based on mineral pairs, suggest that the rocks have undergone UHP metamorphism. SHRIMP U-Pb isotope dating of zircon from the garnet wehrlite yielded a Paleozoic protolith age (ca. 346-461 Ma), and a Mesozoic UHP metamorphic age (ca. 220-240 Ma). The peridotites in PP1 consist of interlayered garnet (Grt)-bearing and garnet-free (GF) peridotite. Both types of peridotite have depleted mantle compositions (Mg# = 90-92) and they display transitional geochemical features. The intercalated layers probably reflect variations in partial melting rather than pressure variations during metamorphism, and the garnets may have been formed by exsolution from orthopyroxene during exhumation. These peridotites were probably part of the mantle wedge above the subduction zone that produced the UHP metamorphism and thus belonged to the North China Block before its tectonic emplacement. The exhumation of the subducted Yangtze Block brought these mantle fragments to shallow crustal levels. The ultramafic rocks in PP3 are dominantly dunite with minor garnet dunite. Their high Mg# (92-93) and relatively uniform chemical compositions indicate that they are part of a depleted mantle sequence. The presence of garnet replacing spinel and enclosing pre-metamorphic minerals such as olivine, clinopyroxene and spinel suggests that these rocks have undergone progressive metamorphism. SHRIMP U-Pb isotope dating of zircon from these rocks yielded two age groups: 726 ± 56 Ma for relic magmatic zircon grains and 240 ± 2.7 Ma for the newly formed metamorphic zircon. The older group is similar in age to granitic intrusions within the Dabie-Sulu belt, suggesting that the PP3 garnet peridotite may record the early emplacement of the peridotite into the crust. The younger dates coincide with the age of UHP metamorphism during continent-continent collision between the Yangtze and North China Blocks, suggesting that these peridotites were subducted to depths equivalent to the coesite facies and later exhumed. Thus, the garnet peridotites in the CCSD cores include both ultramafic rocks that existed originally in the subducted plate and rocks from the mantle wedge above the subducted plate, i.e., part of the North China Block.     

Enhanced production of stratospheric OH from methane oxidation at elevated reactive chlorine levels in northern midlatitudes

Examination of odd-hydrogen production and loss processes in the lower stratosphere reveals that the large abundances of midlatitude ClO recently measured requires a reassessment of the OH yield from methane oxidation due to a more rapid initiation of the methane oxidation sequence by atomic chlorine. Using a steady state calculation for OH and an iterative procedure for evaluating odd-hydrogen production from the methane oxidation sequence, we demonstrate that both OH and reactive chlorine are amplified below 25 km. The amplified values of OH and ClO are found to be consistent with recent measurements of ClO concentrations and of OH column abundances.     

CCSD HP-UHP变质岩中石英脉和东海水晶流体包裹体惰性气体同位素组成及其成因指示意义

中国大陆科学钻探（CCSD）岩心中存在大量石英脉和长英质脉体，关于其成因目前存在板块折返过程中的减压和流体释放以及后期流体穿插等不同成因观点。本文利用高真空气相质谱系统分析了CCSD石英脉和东海水晶流体包裹体中惰性气体同位素组成，其He-Ar、Xe和Ne同位素体系均清楚显示它们主要由地壳变质流体和大气饱和水组成，而基本不含深源地幔流体。在CCSD900～1500m深度的石英脉流体包裹体出现^40Ar／^36Ar和δ^18O同步下降，且与前人对CCSD中HP-UHP岩石的矿物原位δ^18O测定结果变化趋势相似，说明该段原岩在板块俯冲前曾与大气降水发生较为充分的水／岩反应，石英脉继承了围岩的同位素组成特征。流体包裹体惰性气体同位素组成显示CCSD中石英脉和东海水晶可能具有相似的成因，它们均主要形成于HP-UHP岩石在板块折返到地壳中的压力降低和流体释放过程。CCSD HP-UHP岩石及其石英脉中基本不合地幔流体的原因在于本区印支期快速的俯冲和折返过程，被俯冲地壳物质无法与地幔进行充分的同位素交换。此外，退变质作用及其伴生的地壳流体也进一步减弱了HP-UHP岩石中的地幔流体信息。     

Acoustic Borehole Images for Fracture Extraction and Analysis in Second Pre-pilot Drillhole of CCSD

INTRODUCTIONThesecondpre pilotdrillholeofChineseContinentalScientificDrilling (CCSD PPⅡ)ProjectislocatedintheeastofDabie Suluultra highpressuremetamorphic (UHPM)belt,andthesouthofSuluareainthenorthofMaobeiVil lage ,DonghaiCounty ,JiangsuProvince ,China .PPⅡwasdrilleddownto 10 2 8.6 8mdepthwith 75 .5cmbits ,andcasedatadepthof 6 9.5m .TheinvestigationintodrillcoresrevealsthatPPⅡpenetratesmetamorphicformations .Fivemajorlithologicalunitsareidentifiedasfollows :parag neiss,ortho…     

剪切指向转换的韧性剪切带——中国大陆科学钻探工程(CCSD)主孔中韧性剪切带(深度2010～2145m)的EBSD特征及运动学研究

位于苏鲁超高压变质地体南部的中国大陆科学钻探工程(CCSD)主孔深度1596～2038m的榴辉岩段和2038～2500m的片麻岩段之间存在一条厚一百余米的韧性剪切带(深度2010～2145m).韧性剪切带由糜棱岩化退变榴辉岩、花岗质糜棱岩等强应变岩石组成,韧性剪切带的面理倾向SEE,倾角由上部平均52°向中、下部平均32°转变,拉伸线理产状与面理倾向近一致,是220～200Ma期间折返应变的产物.糜棱岩化退变榴辉岩和花岗质糜棱岩的显微构造与石英晶格优选方位显示了折返阶段早期自SEE向NWW逆冲剪切指向以及后期自NWW向SEE正滑剪切指向转化的应变行为.CCSD主孔2010～2145m韧性剪切带的形成与它位于以榴辉岩为主的岩性.构造单元与其下以片麻岩为主的岩性.构造单元的界线附近有密切联系.第一期超高压阶段南北向韧性剪切作用形成的叶理、拉伸线理产状及相关的岩石类型与第二期、第三期阶段SEE-NWW向折返变形明显不同.     

中国大陆科学钻探工程现场实验室采样及样品处理方法探讨

本文主要阐述了中国大陆科学钻探工程现场实验室采样和分析流程。介绍了现场气体分析方法和异常气体采集装置的使用及其对气体分析结果的影响情况,并比较了气体分析的准确度和精密度。对比了4种现场泥浆样品处理方法,特别是后两种方法,分别从准确度和精密度、上层清液放置时间和泥浆处理时间等不同因素对泥浆分析结果的影响进行了分析比较。