A radiometric survey on a sector of the Lipari volcanic island particularly affected by argillification due to hydrothermal processes was carried out. Preliminarily, on the basis of a wide set of field measurements over unaltered outcrops U and K distribution maps were obtained. The concentration of these radioelements increases with the degree of magma differentiation; the U and K content shows maxima (13.4 ppm and 3.7% on average, respectively) in the felsic materials, belonging to the youngest volcanic cycles, and minima (2.7 ppm and 2.0%) in the mafic rocks of the oldest cycles. The Th/U ratio insignificantly varies with magma differentiation and it equals 3.2. Laboratory measurements on volcanic products from altered zones were then used to identify radiometric anomalies related to hydrothermal processes. On the average, argillized rocks have radioactivity approximately five times lower than that measured in the unaltered volcanics. The Th/U ratio against U is rather uniform, whereas Th/K ratio is of the order of 3.6 in less altered rocks K > 0.2%) and it ranges from 7 to 11 in kaolin deposits having the largest depletion in potassium. 相似文献
The Mount Keith (MKD5) nickel sulfide deposit is one of the largest komatiite-hosted nickel sulfide deposits in the world;
it is hosted by a distinctive spinifex-free, cumulate-rich, ultramafic horizon/unit termed the Mount Keith Ultramafic (MKU).
The Mount Keith Ultramafic shows significant variation along its lateral extent. The internal architecture is made up of adcumulate-textured
pods and lenses, which are flanked by thinner meso- and orthocumulate-textured units, overlain by pyroxenitic and gabbroic
horizons. The lateral and vertical changes in the geometry and internal architecture reflect variations in the lithological
association and emplacement conditions along the strike extent of the belt. The chilled margins of the Mount Keith Ultramafic
unit contain ∼1,200 ppm Ni. Olivine cumulates average ∼2,500–3,500 ppm Ni, with few exceptions (Ni > 4,500 ppm) reflecting
occurrence of minor nickel sulfides, whereas pyroxenites and gabbros generally contain, respectively, ∼1,500–2,000 and ∼100–1,000 ppm
Ni. Olivine cumulates generally contain low Cr concentrations (<2,500 ppm Cr), with the rare presence of chromite-rich intervals
containing anomalously high values (>5,000 ppm Cr). The internal stratigraphy of the Mount Keith Ultramafic unit may be subdivided
into two groups based on rare earth element distribution. The chilled margins and the internal units of the Main Adcumulate
domain display LREE-enriched patterns [(La/Sm)n > 1–3] and negative Eu, Hf, Zr, Nb, and Ti anomalies. The internal units in the Western Mineralized Zone generally display
flat chondrite-normalized REE patterns and only minor negative Nb anomalies. The pattern of platinum-group element (PGE) distribution
varies greatly along the strike extent of the Mount Keith Ultramafic unit. The chilled margins display relatively low absolute
concentrations [PGE (excl. Os) ∼16 ppb] and relatively fractionated patterns, with subchondritic Pt/Pd ratios (∼1.5), and
superchondritic Pd/Ir ratios (∼3). The PGE trends in the thick adcumulate-textured pods containing widespread nickel sulfide
mineralization display positive correlation with sulfide abundance, whereas fractionated pyroxenites and gabbros in the thinner
domains display highly depleted PGE concentrations and generally show compatible PGE trends. The nickel sulfide ore typology
and style vary greatly along the strike extension of the Mount Keith Ultramafic unit. Basal massive nickel sulfide mineralization
(e.g., Sarah’s Find) occurs in the thinner meso- and orthocumulate-textured units, whereas stratabound disseminated nickel
sulfide mineralization (e.g., MKD5 Ni Deposit) is hosted in the adcumulate-textured pods. We hypothesize that the very low
PGE content of the initial liquid of the Mount Keith Ultramafic unit indicates that the initial magma pulse that penetrated
through the dacite host-rock had already equilibrated with sulfides at depth and/or carried entrained immiscible sulfide blebs.
We argue that upon emplacement, the intruding magma experienced a significant thermal shock at the contact with water-saturated
volcaniclastic breccias. The sudden chilling would have increased the viscosity of the magma, possibly to the point where
it was no longer able to sustain the suspension of the immiscible sulfide liquid. As a result, the sulfide blebs coalesced
and formed the basal massive sulfide nickel sulfide mineralization at the base of the sill (i.e., Sarah’s Find). Prolonged
focused high volume magma flow within the sill resulted in the emplacement of a thick, lens-shaped accumulation of olivine
adcumulate. Local variations in intensive parameters other than crustal assimilation (e.g., T, fO2, fS2) may be principally responsible for sulfide supersaturation and controlled the local distribution of stratabound disseminated
nickel sulfide mineralization (e.g., MKD5 Ni Deposit), generally localized within the core of the thicker dunite lenses. 相似文献
Geotechnical characterisation is undertaken for 3 broad units comprising the bulk of the stratigraphy identified on White Island Volcano, Bay of Plenty, New Zealand, an active island stratovolcano. Field and laboratory measurements were used to describe rock mass characteristics for jointed lava flow units, and ring shear tests were undertaken to derive residual strength parameters for joint infilling materials within the lavas. Rock Mass Rating (RMR) and Geological Strength Index (GSI) values were calculated and converted to Mohr-Coulomb strength parameters using the Hoek-Brown criterion. Backanalysis of known landslide scarps was used to derive strength parameters for brecciated rock masses and hydrothermally altered rock masses. Andesite lava flows have high intact strength (σci = 184 ± 50 MN m− 2; γ = 24.7 ± 0.3 kN m− 3) and typically 3 wide, infilled joint sets, one parallel to flow direction and two steeply inclined, with spacings of 0.3-1.7 m. Joints are rough, with estimated friction angles for clean joints of ?j = 42-47°. Joint infill materials are clayey silts derived from weathering of wall rocks and primary volcanic sources; they have low plastic (54%) and liquid (84%) limits and residual strength values of cr = 0 kN m− 2 and ?r = 23.9 ± 3.1°. RMR values range from 70 to 73, giving calculated strength parameters of c′ = 1161-3391 kN m− 2 and ?′ = 50.5-62.3°. Backanalysis suggests brecciated rock masses have c′ = 0 kN m− 2 and ?′ = 35.4°, whereas GSI observations in the field suggest higher cohesion (c′ = 306-719 kN m− 2) and a range of friction angles bracketing the backanalysed result (?′ = 30.6-41.7°). Hydrothermally altered rock masses have c′ = 369 kN m− 2 and ?′ = 14.9°, indicating considerable loss of strength, especially frictional resistance, compared with the fresh lava units. Values measured at outcrop scale in this study are in keeping with other published values for similar volcanic edifices; backanalysed data suggest weaker rock mass properties than those determined at outcrop. This is interpreted as a scale issue, whereby rock mass characteristics of a large rock mass (crater wall scale) are weaker than those of small outcrops, due in part to the overestimation of friction angle from measurements on small exposures. 相似文献
The lengthy comment by Von Herzen et al. does not address the most important conclusions of the paper by Hofmeister and Criss [Hofmeister, A.M., Criss, R.E., 2005, Earth's heat flux revisited and linked to chemistry. Tectonophys. 395, 159–177.]. These are 1) that actual measurements better describe the Earth than do simplistic models with demonstrably unrealistic boundary conditions that diverge markedly from the data; and 2) that the models are unconstrained, resulting in a series of papers proposing values for the global flux that have become increasingly disparate from the growing data base over time (Fig. 3 in our paper). We disagree strongly with penultimate concluding statement of Von Herzen et al., “that it is preferable to base surface heat flow analysis not only on the extensive measurements but also on well understood processes that are known to bias the values and statistics of the measurements,” as our Fig. 3 demonstrates that no consistent magnitude has been assigned to the alleged advective flux, so that neither the processes nor the correction are “well understood”. We do not deny the existence of submarine hydrothermal systems, but we disagree strongly with the scales over which they are alleged to operate, and with the large Rayleigh and Nusselt numbers Von Herzen et al. assign to them. 相似文献
The Rhodope Massif in southern Bulgaria and northern Greece hosts a range of Pb–Zn–Ag, Cu–Mo and Au–Ag deposits in high-grade metamorphic, continental sedimentary and igneous rocks. Following a protracted thrusting history as part of the Alpine–Himalayan collision, major late orogenic extension led to the formation of metamorphic core complexes, block faulting, sedimentary basin formation, acid to basic magmatism and hydrothermal activity within a relatively short period of time during the Early Tertiary. Large vein and carbonate replacement Pb–Zn deposits hosted by high-grade metamorphic rocks in the Central Rhodopean Dome (e.g., the Madan ore field) are spatially associated with low-angle detachment faults as well as local silicic dyke swarms and/or ignimbrites. Ore formation is essentially synchronous with post-extensional dome uplift and magmatism, which has a dominant crustal magma component according to Pb and Sr isotope data. Intermediate- and high-sulphidation Pb–Zn–Ag–Au deposits and minor porphyry Cu–Mo mineralization in the Eastern Rhodopes are predominantly hosted by veins in shoshonitic to high-K calc-alkaline volcanic rocks of closely similar age. Base-metal-poor, high-grade gold deposits of low sulphidation character occurring in continental sedimentary rocks of synextensional basins (e.g., Ada Tepe) show a close spatial and temporal relation to detachment faulting prior and during metamorphic core complex formation. Their formation predates local magmatism but may involve fluids from deep mantle magmas.The change in geochemical signatures of Palaeogene magmatic rocks, from predominantly silicic types in the Central Rhodopes to strongly fractionated shoshonitic (Bulgaria) to calc-alkaline and high-K calc-alkaline (Greece) magmas in the Eastern Rhodopes, coincides with the enrichment in Cu and Au relative to Pb and Zn of the associated ore deposits. This trend also correlates with a decrease in the radiogenic Pb and Sr isotope components of the magmatic rocks from west to east, reflecting a reduced crustal contamination of mantle magmas, which in turn correlates with a decreasing crustal thickness that can be observed today. Hydrogen and oxygen isotopic compositions of the related hydrothermal systems show a concomitant increase of magmatic relative to meteoric fluids, from the Pb–Zn–Ag deposits of the Central Rhodopes to the magmatic rock-hosted polymetallic gold deposits of the Eastern Rhodopes. 相似文献
The Sn–W mineralized Mole Granite in Eastern Australia hosts zircon populations that crystallized at several stages during a protracted magmatic to hydrothermal evolution. Thirty-four elements have been quantified by laser-ablation inductively-coupled-plasma mass-spectrometric microanalysis with the aim of relating the chemistry of zircon to its growth environment. Trace element contents are highly variable for all textural occurrences. Zircon inclusions in earliest quartz phenocryst suggest that zircon was a liquidus phase that crystallized probably deep in the crust. Trace element contents are conspicuously high, showing only a slight positive Ce anomaly but a pronounced negative Eu-anomaly. Successive crystallization stages of magmatic zircon are characterized by progressive depletion in trace element contents, notably the rare earth elements, with an increasingly important positive Ce-anomaly. This evolution reflects saturation of REE accepting minerals such as monazite, thorite, xenotime and possibly apatite and is affected little by the exsolution of a magmatic–hydrothermal fluid. Zircon that is interpreted to have precipitated from aqueous fluids in Sn–W-bearing quartz veins shows REE patterns indistinguishable from those of late magmatic zircon. When combined with experimental evidence on the fluid–melt partitioning of REE, it indicates that the REE distribution coefficients for zircon/melt and zircon/fluid are largely comparable.
The second example of hydrothermal zircon crystallized some 2 My after the host granite. These crystals reveal an intragranular zonation of increasing trace element concentrations from core to rim. Therefore, REE abundances and patterns alone are not conclusive indicators of the geological environment in which zircon crystallized. Nevertheless, variations in trace element contents of zircon that relate to the chemistry of the melt or fluid from which zircon crystallized, as measured in cogenetic melt and fluid inclusions, are promising for future petrogenetic modeling.
Lead and Cs are strongly incompatible in hydrothermal zircon, with estimated zircon–fluid distribution coefficients D ≤ 0.001, while Sn and Li are moderately incompatible, DSn 0.6 and DLi 0.1, and Ce is compatible, DCe 14. Moreover, hydrothermal zircon has a more pronounced negative Eu-anomaly and higher Ta/Nb and U/Th ratios than the magmatic zircons of the Mole Granite. 相似文献