内蒙古黄岗梁铁锡矿床中红色萤石的地球化学特征及成因探讨

内蒙古黄岗梁萤石呈现稀有的红色特征,该颜色萤石全球产量稀少,本文利用LA-ICP-MS原位测试技术对其微量元素地球化学特征进行了系统分析,探讨黄岗梁铁锡矿床中红色萤石的成因。微量元素分析结果显示黄岗梁萤石样品中总稀土元素含量较低,并表现出左倾的富集重稀土特征,其中红色和粉色萤石的稀土元素配分曲线显示出Dy-Tm拱顶式凸起的配分模式,表明其结晶作用发生在成矿流体演化的最后阶段;Y/Ho比值104~197,与热液成因萤石一致,且La/Ho比值为0.027~0.126,具强的负异常,表明了黄岗梁萤石为热液成因;Ce/Ce^*比值0.57~0.98,Eu/Eu^*比值0.22~0.63,均表现出负异常,表明形成黄岗梁萤石的热液流体是在相对还原环境下形成且温度高于200℃。综合分析萤石的地球化学特征和其与围岩的接触关系,认为黄岗梁萤石主要分为两阶段结晶,一阶段为与石英同期结晶形成红色、粉色部分,二阶段为在石英形成后结晶形成的由阳起石他色致色的绿色部分,而黄岗梁萤石罕见的红色是由于Y元素较为富集且含量远高于其他稀土元素,从而形成YO₂色心并在萤石中作用而显色。     

南秦岭柞山地区铅银锌矿成矿规律及找矿模型

南秦岭柞水银洞子—山阳桐木沟铅银锌矿带地处陕西柞山地区中部,位于中秦岭晚古生代弧前盆地的柞水—山阳矿集区内。该带东西长约71 km,南北宽1～7 km。对带内银洞子（铜）铅银菱铁矿床、黑沟铅锌菱铁矿床、桐木沟锌矿床、南沟（银）铅矿床和松林沟铅矿点的地质、矿体、蚀变、矿化规律进行总结,发现矿体均严格产于中-上泥盆统青石垭组,具有明显的时控、层控、岩控及后期热液改造成矿特征,属典型的海底热水喷流沉积-热液改造层控矿床,构成与晚古生代海底热水喷流沉积-热液改造作用有关的铅锌银成矿系列。建立以层控+热液改造为主控矿条件,以青石垭组热水沉积岩+断裂+化探异常+硫化物、重晶石、菱铁矿蚀变分带为组合的找矿模型,对柞山地区金属矿的找矿突破具有重要的指导意义。     

Hydrothermal alteration processes in the giant Dahutang tungsten deposit,South China: Implications from litho-geochemistry and mass balance calculation

The giant Dahutang tungsten (W) deposit has a total reserve of more than 1.31 Mt WO₃. Veinlet-disseminated scheelite and vein type wolframite mineralization are developed in this deposit, which are related to Late Mesozoic biotite granite. Four major types of alterations, which include albitization, potassic-alteration, and greisenization, and overprinted silicification developed in contact zone. The mass balance calculate of the four alteration types were used to further understanding of the mineralization process. The fresh porphyritic biotite granite has high Nb, Ta, and W, but low Ca and Sr while the Jiuling granodiorite has high Ca and Sr, but low Nb, Ta, and W concentrations. The altered porphyritic biotite granite indicated that the Nb, Ta, and W were leached out from the fresh porphyritic biotite granite, especially by sodic alteration. The low Ca and Sr contents of the altered Neoproterozoic Jiuling granodiorite indicate that Ca and Sr had been leached out from the fresh granodiorite by the fluid from Mesozoic porphyritic biotite granites. The metal W of the Dahutang deposit was mainly derived from the fluid exsolution from the melt and alteration of W-bearing granites. This study of alteration presents a new hydrothermal circulation model to understand tungsten mineralization in the Dahutang deposit.     

云南香格里拉市热林铅锌银矿特征及找矿标志

云南香格里拉市热林铅锌银矿,矿体呈似层状赋存于三叠系上统曲嘎寺组三段(T3q3)之大理岩与板岩的层间构造破碎带中,矿体明显受断层构造及特定的岩性控制.该矿床属断层破碎带控制的热液型铅锌银矿床,断层破碎带和地球化学异常是直接的找矿标志,沿断层带出现的硅化、碳酸盐化、黄铁矿化和角岩化是间接的找矿标志.     

基于 MODIS 数据的吐鲁番盆地 2001—2017 年 植被变化及水热组合影响分析

中国西北干旱地区的气候变化及其对植被的影响一直备受关注。以地形特殊的吐鲁番盆 地为研究对象,利用实测气象站点数据、再分析气象格点数据以及 MODIS 卫星遥感植被指数,采用 趋势检验、线性回归、偏相关分析等方法,探究了该地区 2001—2017 年间的植被变化及其与水热组 合特征之间的关系。结果表明：（1）吐鲁番盆地降水量整体没有显著变化,但北部山区降水增长较 多,气温总体呈显著上升趋势,尤其是盆地底部中心区域增温较大。（2）全区域植被指数（NDVI）总 体呈极显著上升趋势,山区及中心区域 NDVI 增长率较大。（3）受水汽来源和日照时长的影响,吐鲁 番盆地周边山区高程 3 000 m 左右 NDVI 值最高,山区植被最好的坡向是西北坡。（4）吐鲁番盆地水 热组合复杂,水分条件是大部分地区植被生长的主要限制因素,降水与 NDVI 有较好的正相关,在 山区和荒漠区热量增加不利于植被生长,但中心区域受地下水和人类活动影响,水分的供给相对 稳定,热量增加利于植被生长。     

山东乳山英格庄金矿床地质特征及成因浅析

英格庄金矿为胶东牟平-乳山成矿带上的一个中型金矿床。该矿床矿体严格受金牛山断裂带控制,呈脉状、透镜状和囊状平行斜列式产出;矿体平均厚1．58～1．98m,平均品位3．96×10^-6～4．77×10^-6。矿石类型主要为黄铁矿石英脉型;矿石中金属矿物主要为银金矿、自然金、黄铁矿等。围岩蚀变包括绢云母化、硅化、绿泥石化、黄铁矿化等。研究表明,英格庄金矿床为一中低温热液脉型金矿,属Groves等提出的造山型金矿范畴。     

Distribution and spatial variation of hydrothermal faunal assemblages at Lucky Strike (Mid-Atlantic Ridge) revealed by high-resolution video image analysis

Whilst the fauna inhabiting hydrothermal vent structures in the Atlantic Ocean is reasonably well known, less is understood about the spatial distributions of the fauna in relation to abiotic and biotic factors. In this study, a major active hydrothermal edifice (Eiffel Tower, at 1690 m depth) on the Lucky Strike vent field (Mid-Atlantic Ridge (MAR)) was investigated. Video transects were carried out by ROV Victor 6000 and complete image coverage was acquired. Four distinct assemblages, ranging from dense larger-sized Bathymodiolus mussel beds to smaller-sized mussel clumps and alvinocaridid shrimps, and two types of substrata were defined based on high definition photographs and video imagery. To evaluate spatial variation, faunal distribution was mapped in three dimensions. A high degree of patchiness characterizes this 11 m high sulfide structure. The differences observed in assemblage and substratum distribution were related to habitat characteristics (fluid exits, depth and structure orientation). Gradients in community structure were observed, which coincided with an increasing distance from the fluid exits. A biological zonation model for the Eiffel Tower edifice was created in which faunal composition and distribution can be visually explained by the presence/absence of fluid exits.     

热液条件下CO2和H2反应产烃研究进展

热液条件下CO2和H2形成烷烃的反应,提供了自然条件下CO2转化为有机质的一条非生物途径。研究这一过程,对于油气费托非生物成因研究和海底热液生命起源的讨论具有重要意义。已有研究表明,热力学有利的温度、压强条件和合适的催化剂,是热液条件下CO2和H2发生反应形成烷烃的必需条件。在热力学有利的条件下,铬铁矿能够催化反应形成CH4、C2H6和C3H8,但还不清楚是否存在能够促使反应产生C4H10等长链烷烃的天然矿物催化剂。含一种或多种过渡金属元素的磁铁矿,可能是值得考察的对象。另外,研究热液条件下CO2和H2反应形成烷烃的过程和机理,建立反应所形成烷烃的C、H同位素综合判识指标,是今后值得探索的研究课题。     

Structurally controlled hydrothermal dolomites in Albian carbonates of the Asón valley,Basque Cantabrian Basin,Northern Spain

Shallow marine carbonate sedimentation dominated during the Albian in the western part of the Basque Cantabrian Basin in Northern Spain, forming the large Ramales Platform. This platform originated on a less subsiding tectonic block facing deeper and more subsiding areas to the south and east, which were created by tectonic activity in the Basin. Fracture-related hydrothermal dolomites hosted in these Albian carbonates are well exposed in the Asón valley area. Mapping in the studied area revealed several dolomite bodies related to main faults that cut the stratification almost at right angles. The bodies show a vertical development along fault-strike up to 900 m thick from which kilometre-scale branches expand following the stratification. Dolomitization is pervasive and independent of the limestone facies. Main dolomite facies are fine replacive, sucrosic and saddle. Petrography, C, O and Sr isotopes and fluid-inclusion analysis support a polyphase hydrothermal dolomitization at fluid temperatures between 75 °C and 240 °C and highly variable salinity of up to 22 wt.% NaCl. Fine dolomite replaced limestone first and then, sucrosic and saddle dolomites replaced part of the first dolomite and cemented newly created fracture porosity together with different calcite cements. Zebra dolomites and hydroclastic breccias are products of this later stage. Burial analysis of the host rock supports maximum burial temperatures of 80 °C and intense tectonic activity from the Albian to Turonian with a latest Albian peak subsidence. Albian stretching of the crust and subsequent ascent of the isotherms in the area is suggested to have produced sufficient heat to the dolomitizing fluids. The structural analysis indicates a strong transtensional tectonic activity in the studied area during Albian to Turonian time with the creation of an overstep between W–E trending and N–S trending faults. Fluids moved from subsiding areas to fractured uplifted parts of the Ramales Platform, enhanced by diapiric activity.     

大气降水热液成矿——西秦岭某硅、灰、泥岩型铀矿床成矿模式探讨

西秦岭某硅、灰、泥岩型层控铀矿床是在矿源层(中志留统)的基础上,由地下水热液渗滤改造而成。铀的工业富集发生在矿源层褶皱成陆之后,成矿高峰则发生在中、新生代交替时期。成矿溶液是受大气降水补给的地下水热液;成矿物质主要来自矿源层本身。矿源层长期遭受地下水热液作用,溶液中大量的铀酰离子形成稳定的碳酸铀酰络合物,并被运移至岩性和构造的圈闭部位,通过吸附和共沉淀等作用富集,或通过还原、水解和过饱和沉淀等作用形成沥青铀矿或再生铀黑。该层控铀矿床的整个成矿过程具有典型的逐级增量特点,属于塔式累积成矿的基本模式,后生富集是成矿的关键。