Geochemical constraints on the modes of carbonate precipitation in peridotites from the Logatchev Hydrothermal Vent Field and Gakkel Ridge

The ultramafic-hosted Logatchev Hydrothermal Field (LHF) at 15°N on the Mid-Atlantic Ridge and the Arctic Gakkel Ridge (GR) feature carbonate precipitates (aragonite, calcite, and dolomite) in voids and fractures within different types of host rocks. We present chemical and Sr isotopic compositions of these different carbonates to examine the conditions that led to their formation. Our data reveal that different processes have led to the precipitation of carbonates in the various settings. Seawater-like ⁸⁷Sr/⁸⁶Sr ratios for aragonite in serpentinites (0.70909 to 0.70917) from the LHF are similar to those of aragonite from the GR (0.70912 to 0.70917) and indicate aragonite precipitation from seawater at ambient conditions at both sites. Aragonite veins in sulfide breccias from LHF also have seawater-like Sr isotope compositions (0.70909 to 0.70915), however, their rare earth element (REE) patterns show a clear positive europium (Eu) anomaly indicative of a small (< 1%) hydrothermal contribution. In contrast to aragonite, dolomite from the LHF has precipitated at much higher temperatures (~ 100 °C), and yet its ⁸⁷Sr/⁸⁶Sr ratios (0.70896 to 0.70907) are only slightly lower than those of aragonite. Even higher temperatures are calculated for the precipitation of deformed calcite veins in serpentine–talc fault schists form north of the LHF. These calcites show unradiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.70460 to 0.70499) indicative of precipitation from evolved hydrothermal fluids. A simple mixing model based on Sr mass balance and enthalpy conservation indicates strongly variable conditions of fluid mixing and heat transfers involved in carbonate formation. Dolomite precipitated from a mixture of 97% seawater and 3% hydrothermal fluid that should have had a temperature of approximately 14 °C assuming that no heat was transferred. The much higher apparent precipitation temperatures based on oxygen isotopes (~ 100 °C) may be indicative of conductive heating, probably of seawater prior to mixing. The hydrothermal calcite in the fault schist has precipitated from a mixture of 67% hydrothermal fluid and 33% seawater, which should have had an isenthalpic mixing temperature of ~ 250 °C. The significantly lower temperatures calculated from oxygen isotopes are likely due to conductive cooling of hydrothermal fluid discharging along faults. Rare earth element patterns corroborate the results of the mixing model, since the hydrothermal calcite, which formed from waters with the greatest hydrothermal contribution, has REE patterns that closely resemble those of vent fluids from the LHF. Our results demonstrate, for the first time, that (1) precipitation from pure seawater, (2) conductive heating of seawater, and (3) conductive cooling of hydrothermal fluids in the sub-seafloor all can lead to carbonate precipitation within a single ultramafic-hosted hydrothermal system.     

气候变化对陆地水循环影响研究的问题

简要地回顾了现存的由气候情景驱动水文模型研究气候变化对陆地水循环影响的方法。指出这种单向连接方法很难将气候变暖及人类活动引起的陆地水循环变化反馈给大气。这既影响对降雨的预测精度,又不能正确地描写陆地水循环的变化。近10年来气候学家对大气环流模型中陆面过程模型的改进以及水文气候学家对大尺度水文模型研究所取得的进展,展现了它们之间的互补性,以及未来用水文-气候耦合模型方法研究气候变化与人类活动对陆地水循环影响及水资源预测的可能性。     

Changes in run‐off and sediment load in the three parts of the Yellow River basin,in response to climate change and human activities

Hydrological regimes in the Yellow River have changed significantly because of climate change and intensive human interventions. These changes present severe challenges to water resource utilization and ecological development. Variation of run‐off, suspended sediment load (SSL), and eight precipitation indices (P1: 0–12 mm·day^?1, P12: 12–25 mm·day^?1, P25: 25–50 mm·day^?1, P50: P ≥ 50 mm·day^?1 and corresponding rainfall day: Pd1, Pd12, Pd25, Pd50 day year^?1) in three critical parts of the Yellow River basin (source region: SRYRB, upper reaches: URYRB, middle reaches: MRYRB) were investigated for the period from 1960 to 2015. The results show that run‐off and SSL significantly decreased (P < 0.01) in the URYRB and the MRYRB, whereas their decline in the SRYRB was insignificant (P > 0.05). Moreover, run‐off in the URYRB had one change point in 1987, and SSL in the URYRB as well as run‐off and SSL in the MRYRB had two change points (in the 1970s and the 1990s). Over the same period, only Pd1 and Pd12 in the SRYRB showed significant increasing trends, and an abrupt change appeared in 1981. The optimal precipitation indices for assessing the effects of precipitation on run‐off and SSL in the URYRB and MRYRB were Pd50 and P12, respectively. A double‐mass curve analysis showed that precipitation and human activities contributed to approximately 20% and 80% of the reduction in run‐off, respectively, for both the SRYRB and the MRYRB. However, the contribution rate of precipitation and human activities on SSL reduction was approximately 40% and 60% in the URYRB and 5% and 95% in the MRYRB, respectively. Human activities, primarily soil and water conservation measures and water extraction (diversion), were the main factors (>50%) that reduced the run‐off. However, the dominant driving factors for SSL reduction were soil and water conservation measures and reservoir interception, for which the contribution rate was higher than 70% in the MRYRB. This work strengthens the understanding of hydrological responses to precipitation change and provides a useful reference for regional water resource utilization.     

通勤时间、社区活动对社区社会资本的影响：基于北京26个社区的调查研究

城市扩张和郊区化显著增加居民的通勤时间,减少居民在社区内及周边开展的日常活动,进而可能对居民的社区社会资本产生消极影响。基于2017年北京市26个社区居民的社区融合与活动日志问卷调查数据,通过构建结构方程模型,探讨通勤时间、社区活动对社区社会资本的影响机制。结果发现,控制居民社会经济属性和社区区位后,长时间通勤会减少居民在社区及周边1 000 m范围内开展的活动,并进一步对社区社交网络结构、社会信任和共同价值等社区社会资本的不同维度产生负面影响。此外,社区活动中社交娱乐活动的中介效应显著,而个人和家庭事务活动中介效应不显著。最后,证实了促进职住平衡、减少职住分离的规划政策对于增加居民社区活动及培育社区社会资本的重要意义。     

多尺度视角下中国新能源汽车产业创新空间格局及网络特征

创新活动与创新网络的多尺度空间模式是创新经济地理学关注的焦点。论文选择在知识分类上兼具隐性和显性知识特征的新能源汽车产业作为研究对象,利用来自国家知识产权局的相关专利数据,分析了2001—2015年中国新能源汽车产业独立创新活动和合作创新网络在“区域—省域—市域”的多尺度空间特征,并对其进行空间分类。结果显示：① 创新活动在城市层面最具解释力度,中国新能源汽车产业技术创新活动主要集中在东部和北部沿海地区,市域尺度上的创新活动存在较大差异;② 内部创新网络和外部创新网络在区域层面最具解释力度,创新网络集中在东部和北部沿海地区,市域尺度上的创新网络变异明显;③ 在不同尺度上,创新网络与创新活动之间存在不同程度的差异。地方创新环境与创新主体性质是造成上述格局差异的重要原因。仅停留在空间上的分析很难深入解释创新网络格局,应从更微观的创新主体层面探究创新结网的过程和机理。此外,创新活动和创新网络分别具有“多尺度结构性嵌套”和“多尺度能动性交换”特征,未来研究应对两者之间的差别给予更多关注。     

中国城乡居民幸福感的差异及影响因素研究

2010年上海世界博览会提出“城市让生活更美好”。然而,当前对城乡居民幸福感的实证研究得出了不同的结论。本研究认为,城市并不必然会带来更美好的生活,而是更好的城市让生活更幸福。为此,本研究运用多层次线性回归模型,基于2014年中国劳动力动态调查（CLDS）数据对中国城乡居民的幸福感及其影响因素进行了分析。结果显示,中国城市居民的幸福感整体上高于乡村居民,这种差异主要源于城乡居民的生活水平、生活环境和生活节奏等方面的差异。因此,要实现“城市让生活更美好”的目标,需要在城市化的过程中不断提升城乡居民的获得感、推动城市住房政策改革、进一步加快城乡公共服务一体化进程、实现以家庭为单位的新型市民化模式以及推行更为健全的劳动政策。     

人类活动对济南某小区周边水文地质条件的影响分析

近20年来,随着经济的增长及人口压力的加剧,城市建筑越来越高,基坑开挖越来越深,大量的桩基施工不可避免地对地下水的补给、径流、排泄条件产生影响,而水文地质条件的改变又反过来影响制约人类的活动,甚至引发地质灾害。该文以济南某小区为例,通过水文地质调查、野外钻探、综合分析等手段,研究分析近年来该小区周边地下水位上升的原因及水文地质条件的变化特征。结果表明,由于人类活动的影响,该小区周边水文地质条件发生了较大变化,小区周围由原来的径流排泄区慢慢转变为一小型的"蓄水区",由此造成小区周边地下水位大幅上升,并对构筑物产生了不利影响。研究结果对该小区结构的后期处理、周边地块开发及类似工程水文地质问题具有一定的指导意义。     

居民日常活动对扒窃警情时空格局的影响

扒窃现象与居民的日常活动有较强的关系,已有文献研究了不同活动场所对扒窃的影响,但鲜有考虑不同类型居民活动出行量及其场所对扒窃影响的时间差异。本文基于日常活动理论,以南方某大城市为例,以派出所为分析单元,利用居民入户调查问卷、兴趣点（Point of Interest, POI）、扒窃报警数据,检验不同类型活动出行量与扒窃的时间相关性,并划分时间段,建立多个空间滞后负二项回归模型分析不同时段居民日常活动对应场所与扒窃的关系。研究发现,扒窃警情存在明显的时空集聚性,其中,凌晨和早上的集聚性最强,白天和晚上相对较弱;不同类型的日常活动对扒窃时空格局的作用存在差异。买菜活动出行量与扒窃的时间变化存在正相关关系,买菜场所在凌晨和早上容易吸引扒窃者;购物活动与扒窃亦存在较强的时间正相关,白天和晚上在购物场所附近被盗的风险较高;外出吃饭的出行量与扒窃行为无直接关系,但在凌晨和早上餐馆周边容易吸引扒窃者;娱乐活动与扒窃同样存在较强的时间正相关,不同类型的娱乐场所对扒窃的影响存在差异,电影院、酒吧在大部分时间段均会吸引犯罪者,凌晨时段KTV附近区域的被盗风险较高。场所对扒窃的影响主要与犯罪机会吸引（犯罪目标的丰富性、暴露性）及场所自身属性有关（是否为犯罪者的集聚地）。文中最后对时间地理学和犯罪地理学结合的可能性、研究的应用意义等方面进行了探讨。     

柴达木盆地盐湖锂矿床成矿过程及分布规律

柴达木盆地盐湖蕴藏230×10~4t锂,集中分布在别勒滩、东西台等4个盐湖,占我国卤水锂资源总量~80%,战略资源地位不言而喻。近年来提锂技术及工程化研究倍受重视,而对盐湖锂矿成因和分布规律的了解凸显不足,锂矿资源流失严重与之不无关联。研究查明,昆仑山高温热泉群含锂泉水长期注入洪—那河,流入终端盐湖,蒸发富集成矿;锂的年输入通量748.8 t,结合区内盐湖锂矿总储量保守估算,成矿期始于14 ka BP之后;洪—那河早期主要流向别勒滩,在山前冲积扇向北推进、扇前河改道北流后,方才形成含锂河水当前分配格局。据此,破解了别勒滩锂矿在研究区储量最大的原由。还查明了锂矿床仅存在于别勒滩,而在达布逊等3个区段不能成矿的原因。阐明了锂的来源与新生代火山喷发岩、深部岩浆房、昆仑大断裂活动有关,以及含锂热水持续远程输送至盐湖成矿的地貌和水文气候动因。企业应当根据锂的分布规律和矿床特征,迅速转变钾肥生产模式。