Oxygen and Carbon Isotope Study of Calcite and Dolomite in the Disseminated Au-Ag Telluride Bulawan Deposit, Negros Island, Philippines

Abstract: The disseminated Au‐Ag telluride Bulawan deposit, Negros island, Philippines, is hosted by dacite porphyry breccia pipes which formed in a Middle Miocene dacite porphyry stock. Electrum and Au‐Ag tellurides occur mostly as grains intergrown with or filling voids between sphalerite, pyrite, chalcopyrite, galena and tennantite. Calcite, quartz and rare dolomite are the principal gangue minerals. Four types of alteration were recognized in the deposit, namely; propylitic, K‐feldspar‐sericitic, sericitic and carbonate alteration. Carbonate alteration is correlatable to the gold deposition stage and occurs mostly along fault zones. The δ¹⁸O and δ¹³C compositions of calcite and dolomite in propylite zone and ore‐stage dacite porphyry breccia were determined. The δ¹⁸O values of calcite in propylitized andesite range from +12.2 to +14.7%, and their δ¹³C values range from ‐6.1 to ‐1.0%. The δ¹⁸O values of calcite and dolomite in sericite‐ and carbonate‐altered, mineralized dacite porphyry breccia and dacite porphyry rocks range from +15.1 to +23.1%, and the δ¹³C values of calcite and dolomite range from ‐3.9 to +0.9%. The δ¹⁸O and δ¹³C values of the hydrothermal fluids were estimated from inferred temperatures of formation on the basis of fluid inclusion microthermometry. The δ¹⁸O values of hydrothermal fluid for the propylitic alteration were calculated to be +8.5 ‐ +9.5%, assuming 375°C. On the other hand, the δ¹⁸O values of ore solutions for base metal and Au mineralization were computed to be +13.6 ‐ +14.6%, assuming 270°C. The hydrothermal fluids that formed the Bulawan deposit are dilute and ¹⁸O‐enriched fluids which reacted with ¹⁸O‐ and ¹³C‐rich wallrocks such as limestone.     

Correlation of hydraulic conductivity with stratigraphy in a fractured-dolomite aquifer, northeastern Wisconsin, USA

This study integrated surface and subsurface stratigraphic data with geophysical logs and hydrogeologic data in order to characterize the hydraulic properties of the Silurian dolomite in northeastern Wisconsin. Silurian stratigraphy consists of predictable alternations of characteristic facies associations. A vertical profile of hydraulic conductivity, obtained from short-interval packer tests in a core hole that penetrates a majority of the Silurian section, indicates that hydraulic conductivity ranges over five orders of magnitude (10^–1 to 10^–6 cm/s). Matrix conductivity is generally low and varies with texture; the finer-grained restricted-marine and transitional facies being less permeable than the coarser-grained open-marine facies. High-conductivity values are generally associated with bedding-plane fractures, and fracture frequency is greater in the restricted-marine facies. High-flow features in 16 wells were identified using fluid-temperature/resistivity and heat-pulse flowmeter logs. Natural-gamma logs were used to identify the stratigraphic position of flow features in each well and to correlate flow features to specific stratigraphic horizons. By combining stratigraphic, geophysical, and hydrogeologic data, 14 high-permeability zones within the Silurian aquifer have been identified and correlated in wells more than 16 km apart. These zones parallel bedding, appear most pronounced at contacts between contrasting lithologies, and are most abundant in restricted-marine lithologies. Electronic Publication     

论祁雨沟式金矿

祁雨沟金矿是典型的爆破角砾岩型金矿。系统地论述了其成矿地质背景、矿床地质、地球化学特征、及其成因意义。根据围岩蚀变和矿物包裹体温度、成分的研究,确定了矿床形成的物理化学条件及其各阶段的演变;通过氧同位素研究证明了成矿溶液的来源由早期岩浆水转变为晚期大气降水;用硫、碳和铅同位素组成说明成矿物质的复杂来源。以板块构造理论为指导,建立了矿床的形成模式,并指出找矿方向。     

Improving groundwater-flow modeling using optimal zoning methods

Hydraulic conductivity sometimes exhibits complicated spatial variation over a site. A thorough understanding of the spatial distributions of hydraulic conductivity helps to make deterministic models of groundwater more accurate. This study presents a novel procedure that combines simulated annealing algorithms (SA) and the shortest distance method (SD) with the modular three-dimensional groundwater flow model (MODFLOW). The procedure is applied to a hypothetical site with groundwater-monitoring wells to minimize the difference between simulated and observed hydraulic head for optimal zoning of the spatial distribution of hydraulic conductivity. The results of this optimal zoning method indicate that this new procedure not only improves the efficiency of optimization, but also increases the probability of finding the global optimum, minimizing the errors of the hydraulic head simulated by MODFLOW in two scenarios, one with known and the other with unknown hydraulic conductivity. The results also illustrated that the procedure can effectively determine and delineate hydrogeological zones.     

Hydraulic analysis of cell-network treatment wetlands

When individual cells of a multiple-cell treatment wetland are hydraulically connected, the wetland has a cell-network structure. The hydraulic performance of treatment wetlands is often characterized using tracer residence time distributions (RTDs) measured between the wetland inlet and outlet, such that the wetland is considered as a single hydraulic unit, regardless of the extent of networking between individual internal cells. This work extends the single hydraulic unit approach to enable the specification of moments and RTD parameters for individual cells, or clusters of cells, within the cell-network based on inert tracer tests with injection only at the network inlet. Hydraulic performance is quantified in terms of hydraulic efficiency and travel time dimensionless variance using both the method of moments and RTD modeling. Cell-network analysis was applied to a case study from the Orlando Easterly Wetland (OEW), demonstrating the improvement in hydraulic performance of individual wetland cells following wetland restoration activities. Furthermore, cell-network analysis indicated that the location of water quality sampling station locations within the cell network can significantly affect the accuracy of pollutant removal effectiveness estimation when the individual sample station RTD does not represent the hydraulic unit RTD. At the OEW, it was determined that historical nutrient removal effectiveness estimation may be underestimated for one area and overestimated for another, and recommendations were provided for sample station locations to minimize future performance estimation errors.     

The dynamics of a channel-fed lava flow on Pico Partido volcano, Lanzarote

A short length of channel on Pico Partido volcano, Lanzarote, provides us the opportunity to examine the dynamics of lava flowing in a channel that extends over a sudden break in slope. The 1–2-m-wide, 0.5–2-m-deep channel was built during the 1730–1736 eruptions on Lanzarote and exhibits a sinuous, well-formed channel over a steep (11° slope) 100-m-long proximal section. Over-flow units comprising smooth pahoehoe sheet flow, as well as evidence on the inner channel walls for multiple (at least 11) flow levels, attest to unsteady flow in the channel. In addition, superelevation is apparent at each of the six bends along the proximal channel section. Superelevation results from banking of the lava as it moves around the bend thus causing preferential construction of the outer bank. As a result, the channel profile at each bend is asymmetric with an outer bank that is higher than the inner bank. Analysis of superelevation indicates flow velocities of ~8 m s^–1. Our analysis of the superelevation features is based on an inertia-gravity balance, which we show is appropriate, even though the down-channel flow is in laminar flow. We use a viscosity-gravity balance model, together with the velocities calculated from superelevation, to obtain viscosities in the range 25–60 Pa s (assuming that the lava behaved as a Newtonian liquid). Estimated volume fluxes are in the range 7–12 m³ s^–1. An apparent down-flow increase in derived volume flux may have resulted from variable supply or bulking up of the flow due to vesiculation. Where the channel moves over a sharp break in slope and onto slopes of ~6°, the channel becomes less well defined and widens considerably. At the break of slope, an elongate ridge extends across the channel. We speculate that this ridge was formed as a result of a reduction in velocity immediately below the break of slope to allow deposition of entrained material or accretion of lava to the channel bed as a result of a change in flow regime or depth.     

广西桂林庙头上泥盆统融县组中的灰岩脉和角砾灰岩体及其成因

广西桂林庙头上泥盆统融县组台地边缘相具鸟眼或溶孔砂屑生屑藻粘结灰岩中发育了大量灰岩脉，灰岩脉呈岩墙状近直立地切过围岩，露头上可见连续垂直延伸长度达十余米，脉内仍是上泥盆统融县组灰岩组分，仅比围岩稍晚或同时代的：角砾状退白云石化藻粘结灰岩、角砾状藻粘结灰岩（快速堆积，角砾多数来自围岩）、细鲕粒颗粒灰岩、含钙球砂屑粒泥灰岩、藻砂屑腹足泥粒灰岩（正常沉积或液化变形软沉积流，均高于围岩层位）及大量栉壳状方解石脉（张性环境）等，灰岩脉内可见软沉积物变形痕迹及液化脉（地震液化），晚期灰岩脉可穿插早期灰岩脉；在其西侧同层位共生有一套楔状（地裂缝）、不规则状角砾灰岩体，角砾棱角状，大小不等，成分是灰色中厚层角砾状藻粘结灰岩、含钙球砂屑粒泥灰岩等。笔者等注意到灰岩脉均出露在北东向正断层的下盘（东侧），而角砾灰岩体则均出露在该断层的上盘（西侧），事实上，灰岩脉及角砾灰岩体分布走向与北东向断层走向一致，角砾灰岩体中的角砾成分显示其来自较灰岩脉围岩稍高层位，与灰岩脉内充填岩性相近，因此，是该断层控制了当时的沉积，此断层是晚泥盆世台地边缘同沉积正断层；灰岩脉是与断层伴生的张性裂隙被围岩角砾或稍晚时段的沉积物充填；角砾灰岩体是同沉积正断层形成的断层崖崩落角砾岩，指示一个消失殆尽的晚泥盆世碳酸盐岩同沉积正断层陡崖，因而，桂林台地，至少西段台地边缘，是与右江各孤立台地边缘一样——在地质图上应标示为同沉积正断层边界。其构造意义是：庙头地区的灰岩脉、角砾灰岩体及同沉积断层是桂林台地对晚泥盆世构造伸展作用的响应，从而说明广西晚古生代的板块拉张，不是从二叠纪才开始的，而是至少从晚泥盆世就开始了；晚古生代至早三叠世持续的孤立台地与深水盆地相间的古地理格局，是在晚泥盆世就奠定了基础。     

Hydraulic and compaction characteristics of leachate-contaminated lateritic soil

Large quantities of leachate-contaminated lateritic soil results from dump yards in the southwest coast of India. These dump yards receive large quantities of municipal solid waste which includes chemical, industrial and biomedical wastes. Large areas of land are currently being used for this purpose. An extensive laboratory testing program was carried out to determine the compaction characteristics and hydraulic conductivity of clean and contaminated lateritic soil. Batch tests were used to study the immediate effect of leachate contamination on the properties of lateritic soil. Contaminated specimens were prepared by mixing the lateritic soil with leachate in the amount of 5%, 10% and 20% by weight to vary the degree of contamination. The results indicated a small reduction in maximum dry density and an increase in hydraulic conductivity due to leachate-contamination. The change induced by chemical reaction in the microstructure of the soil was studied by scanning electron microscope before and after contamination of soil with leachate. The structure of the leachate contaminated soil sample appeared to be aggregated in scanning electron microscope analysis. The aggregated structure increases the effective pore space and thus increases the hydraulic conductivity. Fifty percent increase in hydraulic conductivity was observed for specimens prepared at standard Proctor density and mixed with 20% leachate. Compaction characteristics did not change much with the presence of leachate up to 10%. With 20% leachate the maximum dry density decreased slightly indicating excess leachate in the soil. However the changes are not significant.     

我国低钛月海型模拟月壤初始物质选择的地球化学依据

以Apollo14月壤样品和美国JSC-1模拟月壤的地球化学特征为基础,结合我国低钛玄武岩火山的分布,对我国不同地区新生代玄武岩的化学成分、年龄、储量等方面进行对比分析结果表明,滇西北金沙江地区和吉林辉南红旗林场-四海地区的玄武质火山喷发物的化学成分与Apollo14月壤样品和美国JSC-1模拟月壤相似,比较适合用于我国低钛月海玄武岩模拟月壤研制的初始物质。野外地质调查发现,吉林省辉南县金川镇红旗林场—四海一带产出的玄武质火山渣为距今1600 a的该玄武质火山岩的喷发物,其储量大、质地纯、粒度均匀,而且比滇西北金沙江地区最近一期的玄武质火山渣新鲜,最适合作为我国低钛月海玄武岩模拟月壤研制的初始物质。