湖南川口岩体型钨矿赋矿花岗岩地球化学特征及LA-ICP-MS锆石U-Pb定年

川口矿田钨矿床产于湖南衡阳川口岩体的外接触带及岩体内部,矿床类型主要有岩浆热液石英细脉带型和石英大脉型。近年川口矿田取得了重大找矿突破,并发现了新类型的岩体型钨矿。本文对川口岩体型钨矿床的黑云母二长花岗岩及赋矿的白云母二长花岗岩分别进行了 LA-ICP-MS锆石U-Pb定年和岩石地球化学特征研究,获得川口岩体的成岩年龄为(223.1 ± 0.78)Ma,MSWD=0.98,n=24,岩体型钨矿成矿年龄为(224.6±1.31)Ma,MSWD=0.33,n=9,为印支期成岩成矿。川口花岗岩具有高SiO_2,富K_2O+Na_2O,低CaO、MgO的特点,属于过铝质高钾钙碱性系列S型花岗岩,形成于碰撞环境下弱挤压构造体制。川口岩体稀土总量(∑REE)整体较低,轻稀土相对较富集,具有强烈的负Eu异常,富集大离子亲石元素Ba、K和高场强元素Ta,而亏损大离子亲石元素Sr和相容元素P、Ti等,表明该岩体各阶段花岗岩来自同一岩浆源,且经历了高度演化。赋矿花岗岩更低的δEu值及(La/Yb)_N值,表明其结晶分异程度更高。     

The parnell quartz monzonite: A proterozoic zoned pluton in the archaean pilbara block,Western Australia

The Parnell Quartz Monzonite in the Pilbara Block of Western Australia is a Proterozoic (1731 ± 14 Ma) pluton characterized by high modal K‐feldspar and a greater abundance of hornblende relative to biotite, as is typical of Phanerozoic monzonitic rocks in eastern Australia. The only geochemical features reflecting its setting in an Archaean terrain are high Na2O, Ni and Cr. The pluton is zoned, with an increase in K‐feldspar, quartz and biotite and a decrease in plagioclase and hornblende from margin to core. Chemically, this zoning is reflected by systematic variation of CaO, K₂O, Na₂O, Sr and Rb, but ferromagnesian elements have irregular trends, implying preferential extraction of feldspars relative to mafic minerals during differentiation of the magma. The unusual geochemical trends are explained by a model involving ‘in situ’ feldspar fractionation of a K‐rich residual liquid from a mafic crystalline mush.

A parent magma similar to the average rock composition of the pluton is deduced because high ferromagnesian trace element abundances preclude extensive fractionation of mafic minerals. Geochemical and isotopic constraints suggest that the ultimate source was chemically similar to a shoshonitic basaltic andesite, that must have been emplaced beneath the eastern margin of the Pilbara Block in the Early Proterozoic. Subsequent partial melting of this postulated underplated source at ～ 1700 Ma to produce the Parnell Quartz Monzonite was probably associated with tectonism in the Gregory Range Complex.     

粤北竹山下岩体锆石U-Pb同位素定年及其地球化学特征

竹山下岩体锆石SHRI MP U-Pb年龄为161.0±3.0 Ma,属燕山早期岩浆活动产物。该岩体的主要元素显示富硅(Si O2=76.05%~79.16%)、富碱(K2O+Na2O=7.77%~8.40%)、强过铝质(A/CNK=1.08~1.26)和低CaO/Na2O值(0.04~0.06)等特征。微量元素富集大离子元素而亏损Ba,Sr,Ce和Ti;LREE轻微亏损(LREE/HREE=0.82~1.09),Eu亏损明显(δEu=0.06~0.11),且具有较明显的四分组效应(TE1,3=1.07~1.24)。上述特征表明,竹山下岩体属于典型的壳源型花岗岩,是在地壳伸展-减薄的构造背景下,由泥质变质岩经过低程度部分熔融的方式而形成。     

The evolution of the Huangling uplift and its control on the accumulation and preservation of shale gas

There are plenty of Sinian and Cambrian potential shale gas resources in South China, which is characterized by high thermal evolution degrees, poor drilling performances and only occurs in local areas. Taking the principle “high to find low” is the key issue to achieving a breakthrough in older shale. China Geological Survey drilled in the periphery of the Proterozoic basement, i.e. the Huangling anticline, in the western Hubei, and Hannan paleocontinent in the southern Shanxi. It received high-quality gas-bearing shale with relatively low Ro in the in Lower Cambrian Niutitang formation and Sinian Doushantuo formation. Based on geological conditions of shale gas reservoirs in the Huangling anticline, this paper puts forward the new model named “Control over reservoirs by periphery of basement” about shale gas accumulation, suggesting that the shale deposited in a deepwater continental shelf in the periphery of the basement is characterized by shallow burial, a short burial time, stable tectonics, relatively low thermal evolution degrees, and shale gas reservoirs in a good condition. The shale of the Sinian-Cambrian strata deposited in deepwater continental shelves in the periphery of Chuanzhong paleo-uplift in Sichuan, Hannan paleocontinent in the southern Shanxi, Huangling anticline in western Hubei and Jiangnang-Xuefeng paleo-uplift in Hunan and Guizhou province have good shale gas exploration potential.     

Age, Origin and Cooling History of the Coronel Joao Sa Pluton, Bahia, Brazil

In north-east Brazil, Archean and Paleoproterozoic cratonicblocks are enclosed within a network of Brasiliano-age (0·7–0·55Ga) metasedimentary foldbelts. The unfoliated Coronel JoãoSá granodiorite pluton, which contains magmatic epidoteand strongly resorbed clinopyroxene, intrudes the SergipanoFoldbelt. Zircons yield a concordant U–Pb crystallizationage of 625 ± 2 Ma; titanite ages are approximately 621Ma. Discordant zircons suggest inheritance from at least twomagma sources of ages <1·8 and >2·2 Ga.Model calculations based on diffusion parameters and Rb–Srisotope data from separated minerals indicate that the plutoncooled at a rate of 36°C/Myr. Whole-rock element compositionsand initial Sr–Nd isotopic compositions that are heterogeneouson all length scales suggest magma mixing. Trace-element concentrationsand Nd isotope data argue against a contribution from a contemporaneousmantle-derived magma. Values of magmatic _Nd (at 625 Ma) resemblecontemporary _Nd for local supracrustal rocks and basement, compatiblewith anatexis of a crustal source. In north-east Brazil, cratonicblocks could have amalgamated with foldbelts that originatedas: (1) a mosaic of island arcs and arc basins (traditionalallochthonous model), or as (2) extensional continental sedimentarybasins (but not oceanic crust) later involved in collision (autochthonousmodel). The Coronel João Sá isotopic and chemicaldata support an autochthonous origin. KEY WORDS: Brasiliano Orogeny; granodiorite pluton; Rb–Sr isotopes, Sm–Nd isotopes; U–Pb isotopes, magma cooling rate     

江南造山带东段旌德岩体锆石LA-ICPMS年龄和Nd-Sr-Hf同位素地球化学

提要：旌德花岗质杂岩体位于安徽南部,由花岗闪长岩和二长花岗岩组成。本研究得到岩体中锆石U-Pb年龄为(141.0±1.0) Ma,认为该年龄代表岩体的侵位年龄。岩体全岩主量元素特征显示出中偏酸性 (SiO2＝66.01%~70.87%),富Al (Al2O3＝14.91%~16.24%),富碱 (alk = 6.64%~8.01%),K2O/Na2O变化范围在0.78~1.04,镁、铁含量较低,MgO：0.68%~1.06%,TFe2O3 (2.0%~3.34%),以及低磷 (P2O5 =0.10%~0.14%)的特点;微量元素主要富集Sr (189×10-6~452×10-6),贫Nb、Ta、P、Ti、Y、Yb,高Sr/Y比值 (23~66)和 (La/Yb)N (13~58),Eu有轻微的负异常到弱的正异常 (δEu＝0.81~1.18)。旌德岩体的地球化学特征与中国东部中生代埃达克质岩相似。ISr＝0.7096~0.7101, εNd(t)＝-6.28~-7.32,εHf(t)值变化于-6.5~-1.1,两阶段模式年龄 tDM2=1.4~1.5 Ga。较年轻的Nd同位素模式年龄、较高的εNd(t)值和εHf(t)值,以及岩体中发育有岩浆混合成因的暗色包体,指示源区可能有地幔物质的贡献。幔源岩浆底侵使下地壳发生部分熔融,并发生了岩浆混合作用,形成了旌德岩体。     

南祁连化隆地区鲁满山花岗岩的岩石成因:地球化学、锆石U-Pb年代学及Hf同位素约束

位于南祁连化隆地区的鲁满山花岗岩体,岩石类型主体为黑云二长花岗岩。LA-ICP-MS锆石U-Pb定年测得其成岩年龄为(452.9±1.8)Ma,属于加里东期岩浆活动的产物。化学组成上,岩体具有高硅、富碱的特征,属于弱过铝质高钾钙碱性系列。微量和稀土元素组成上,岩体富集大离子亲石元素Rb、U、Th、K和Pb,亏损Ba、Sr、Ta、Nb、P、Ti,具明显轻稀土富集,重稀土亏损特征,显示较强烈的负Eu异常(δEu=0.06~0.55,平均0.31),综合地质地球化学资料指示该岩体应属于高分异的Ⅰ型花岗岩。锆石Hf同位素分析结果显示,岩体的εHf(t)为-7.4~0.1,二阶段模式年龄介于1425~1930 Ma,指示成岩过程中应有亏损地幔组分参与,其壳源源区很可能包括化隆岩群。结合区域构造演化,认为鲁满山花岗岩体形成于柴北缘洋壳与中南祁连陆壳俯冲碰撞的地球动力学背景下,由幔源岩浆与其诱发的地壳物质熔融产生的长英质岩浆在地壳深部混合后再经历分异演化形成。     

江西印支期蔡江岩体中暗色微粒包体的发现及其地质意义

文章报道了江西蔡江花岗质岩体中发现暗色微粒包体,以及这些包体的地质、岩相学、LA-ICP-MS锆石U-Pb年代学和元素地球化学特征。包体多呈椭圆状,显示淬冷边和反向脉,具有典型的岩浆结构并含有针状磷灰石,有的包体含有长石捕虏晶。包体具有相对较低的SiO₂（低至57.05 wt%）和较高的MgO+Fe₂O₃（高达14.21 wt%）含量。LA-ICP-MS锆石U-Pb定年数据表明,包体形成于晚三叠世（224 Ma）,与寄主花岗岩（230~228 Ma）在误差范围内基本一致。上述特征表明,包体是离散的幔源偏基性岩浆团或者是幔源与寄主岩浆混合的产物。原始包体岩浆属于超钾质岩浆,可能是通过岩石圈地幔中交代成因的金云母辉石岩脉发生部分熔融而形成的。暗色微粒包体的发现为幔源岩浆底侵提供了直接证据,从而为蔡江花岗质岩石形成于较高温度提供佐证。该研究对于进一步探讨华南印支期花岗岩形成的热源机制具有意义。     

大别山双河片麻状花岗岩岩体石英组构特征及应变分析

对大别山双河片麻状花岗岩岩体中的石英C轴组构、黑云母(001)解理极点和石英颗粒三维应变分别进行系统测量。结果显示,双河岩体在侵位和后期演化过程中以挤压变形为特点,岩体经过NW-SE向和NE-SW向两次挤压,NW-SE向挤压强度较大,奠定了岩体基本的构造形态。结合区域应力场特征分析得出,双河岩体在早三叠世至早侏罗世应力方位为NW-SE向挤压,中侏罗世及后期为NE-SW向挤压,应力场发生顺时针变化。      

胶东艾山岩体二长花岗岩地球化学、锆石U-Pb年代学及Lu-Hf同位素特征研究

胶东地区大规模金成矿作用发生于125～110 Ma,与金成矿作用同期的早白垩世晚期艾山岩体出露于华北克拉通东缘,由深成相的石英闪长岩-似斑状二长花岗岩类及浅成相的闪长玢岩、花岗斑岩等组成,岩体发育岩浆暗色包体.对艾山二长花岗岩开展了岩相学、岩石地球化学、锆石LA-ICP-MS年代学和Lu-Hf同位素测试和研究,探讨了该...