北秦岭西段黄牛铺岩体锆石U Pb年代学、岩石地球化学特征及其地质意义

对北秦岭西段黄牛铺岩体进行了LA ICP MS锆石U Pb年代学与岩石地球化学分析。结果显示,黄牛铺岩体的锆石U Pb年龄为(4493±49) Ma,表明其形成时代为晚奥陶世。黄牛铺岩体属于准铝质高钾钙碱性系列,在成因类型上具有I型花岗岩的岩石矿物学与地球化学特征,其稀土元素配分曲线呈轻稀土元素富集、重稀土元素亏损(LREE/HREE=983~1155)、铕弱负异常(δEu=082~095)的右倾型,微量元素Rb、Th、U、Sm等富集,Ta、Nb、Ti、Hf等明显亏损,表现为岛弧岩浆岩的地球化学特征。结合区域地质资料,认为黄牛铺岩体形成于晚奥陶世商丹洋俯冲过程中的岛弧环境,是壳幔岩浆混合作用的产物,这为进一步研究北秦岭的构造演化过程提供了更加充分准确的岩浆活动证据。     

西准噶尔南部庙尔沟岩体晚石炭世花岗闪长斑岩岩石成因及其动力学背景

位于西准噶尔南部的庙尔沟岩体主体由碱长花岗岩和少量紫苏花岗岩组成。本文在前人工作基础上,以岩体东南边缘新发现的花岗闪长斑岩为研究对象,开展岩石学、年代学和Hf同位素以及全岩地球化学研究,确定花岗闪长斑岩形成时代、揭示岩石成因类型及源区属性、探讨其与碱长花岗岩和紫苏花岗岩岩浆演化成因联系及其形成的深部动力学过程。锆石U-Pb定年结果显示,花岗闪长斑岩形成于317.4±1.9Ma,为晚石炭世早期岩浆活动的产物,明显早于紫苏花岗岩(~307Ma)和碱长花岗岩(~303Ma)。岩石地球化学数据表明,花岗闪长斑岩具有较高硅、中等铝,贫钙、铁、镁,富集Rb、K、Th、U,强烈亏损Nb、Ta、Ti的特征,为钙碱性弱过铝质Ⅰ型花岗岩;紫苏花岗岩更多的表现出钙碱性-高钾钙碱性镁质Ⅰ型紫苏花岗岩特征;碱长花岗岩为碱性准铝质-弱过铝质A型花岗岩。锆石Hf同位素分析结果表明,花岗闪长斑岩、紫苏花岗岩和碱长花岗岩均具有高正的ε_Hf(t)值(+11.6~+15.8)和年轻的二阶段模式年龄(325~600Ma),表明其原始岩浆主要起源于亏损地幔新衍生的年轻地壳物质。综合分析认为,庙尔沟岩体花岗闪长斑岩形成于晚石炭世早期洋壳俯冲背景,由底侵的、受流体交代的幔源基性岩浆与其诱发的年轻下地壳酸性岩浆在深部混合而成。紫苏花岗岩和碱长花岗岩形成于弧后伸展背景,前者是伸展初期继续底侵于下地壳的幔源玄武质岩浆降温释放大量的水和热诱使早期侵位于下地壳的镁铁质岩石再次发生部分熔融的产物,后者是伸展后期大规模软流圈地幔上涌底垫加热年轻中下地壳使其部分熔融而成。

     

闽西南玮埔岩体和赣南菖蒲混合岩锆石La ICPMS U-Pb年代学

闽西玮埔岩体和赣南菖蒲混合岩位于武夷山构造带南部地区。对NNE向展布的闽西玮埔岩体两个样品进行了锆石LaICPMS U-Pb 测年,获得的年龄为447.1±4.7Ma和440.8±3.4Ma,证明这个岩体不是原来认为的印支期花岗岩,而属于加里东岩体。赣南菖蒲混合岩发育于罗浮岩体的北侧,早期将罗浮岩体归于燕山早期岩体。对混合岩进行的锆石LaICPMS U-Pb 测年,获得的年龄为445.9±3.8Ma,确定这个岩体为加里东期。这些新的高精度年龄学数据为武夷山加里东构造运动时限和性质提供了精确约束。     

皖南泾县榔桥岩体锆石U-Pb定年、Hf同位素和地球化学特征及其找矿指示意义

安徽泾县榔桥花岗闪长岩体为分布于皖南台褶带北缘壳幔同熔型复式岩体。该岩体主侵入期两个花岗闪长岩样品和侵入后期脉岩一个花岗斑岩样品的锆石U-Pb年龄分别为135.6±1.8Ma,137.6±2.0Ma,136.4±1.9Ma,显示岩体形成于早白垩世。锆石Hf同位素分析表明榔桥岩体可能由中元古代地壳物质部分熔融形成,同时混染有少量古元古代地壳物质。根据全岩Zr含量计算出榔桥岩体花岗闪长岩"锆石饱和温度"为749~781℃,脉岩花岗斑岩"锆石饱和温度"为722~745℃,指示岩浆在成岩过程中快速冷却;元素地球化学研究显示,本区岩石在成岩过程中发生斜长石、钾长石以及副矿物磷灰石、钛铁矿的分离结晶作用。锆石Ce(Ⅳ)/Ce(Ⅲ)比值计算表明榔桥岩体成岩过程中的高氧逸度有利于该区域发生Cu-Au矿化,而斜长石的分离结晶使得EuN/EuN*比值降低,为0.2~0.4。榔桥岩体具有富集大离子亲石元素以及Pb,亏损高场强元素(Nb、Ta、Zr,Ti),以及轻重稀土发生明显的分异,轻稀土相对重稀土明显富集的特征,与岛弧岩浆岩类似;大地构造背景判别表明该岩体的形成与古太平洋板块对欧亚大陆的俯冲碰撞作用密切相关。     

西天山喀拉达拉基性岩体及其构造背景

在中国西天山伊什基里克山一带,发育有一系列橄榄辉长岩、橄长岩、辉长岩、辉绿岩床和岩墙群,同位素年龄为２７７～２９７Ｍａ。其中哈拉达拉层状橄榄辉绿长岩－辉绿辉长岩体（又称大桥岩体）规模最大,约２５．５ｋｍ＾２。根据近年来的实地研究,认为该岩体形成于伊犁盆地石炭一二叠纪裂谷带发育的构造背景之下,既有大量碱性玄武岩和火山碎屑岩,又有一定数量的基性一超基性杂岩和层状辉长侵入体,经历了稳定－亚稳定－稳定的演     

Age, Origin and Cooling History of the Coronel Joao Sa Pluton, Bahia, Brazil

In north-east Brazil, Archean and Paleoproterozoic cratonicblocks are enclosed within a network of Brasiliano-age (0·7–0·55Ga) metasedimentary foldbelts. The unfoliated Coronel JoãoSá granodiorite pluton, which contains magmatic epidoteand strongly resorbed clinopyroxene, intrudes the SergipanoFoldbelt. Zircons yield a concordant U–Pb crystallizationage of 625 ± 2 Ma; titanite ages are approximately 621Ma. Discordant zircons suggest inheritance from at least twomagma sources of ages <1·8 and >2·2 Ga.Model calculations based on diffusion parameters and Rb–Srisotope data from separated minerals indicate that the plutoncooled at a rate of 36°C/Myr. Whole-rock element compositionsand initial Sr–Nd isotopic compositions that are heterogeneouson all length scales suggest magma mixing. Trace-element concentrationsand Nd isotope data argue against a contribution from a contemporaneousmantle-derived magma. Values of magmatic _Nd (at 625 Ma) resemblecontemporary _Nd for local supracrustal rocks and basement, compatiblewith anatexis of a crustal source. In north-east Brazil, cratonicblocks could have amalgamated with foldbelts that originatedas: (1) a mosaic of island arcs and arc basins (traditionalallochthonous model), or as (2) extensional continental sedimentarybasins (but not oceanic crust) later involved in collision (autochthonousmodel). The Coronel João Sá isotopic and chemicaldata support an autochthonous origin. KEY WORDS: Brasiliano Orogeny; granodiorite pluton; Rb–Sr isotopes, Sm–Nd isotopes; U–Pb isotopes, magma cooling rate     

Petrogenesis and geodynamic setting of the Triassic granitoid plutons in West Qinling,China: insights from LA-ICP-MS zircon U–Pb ages,Lu–Hf isotope signatures and geochemical characteristics of the Zhongchuan pluton

West Qinling is one of the most important parts of the Qinling orogenic belt and includes acidic–intermediate plutons and many types of ore deposits. In this article, we collected geochemical and geochronological data for the Triassic granitoid plutons of West Qinling and found that nearly all plutons share the similar features with the Zhongchuan pluton. We present new laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U–Pb ages, major and trace element geochemistry, and zircon Hf isotope systematics for the granites of the Zhongchuan pluton to elucidate the evolution of granitoid plutons in West Qinling during the Triassic. LA-ICP-MS zircon U–Pb dating indicates that the Xujiaba and Guandigou units formed at 220.1 ± 1.2 and 215.9 ± 0.85 Ma, respectively, reflecting the time of the Late Triassic. The rocks of the Zhongchuan pluton are metaluminous to weakly peraluminous and have a high-K calc-alkaline to shoshonite series with high SiO₂ (63.59–76.22%) and low P₂O₅ (0–0.2%) concentrations, a high K₂O/Na₂O ratio (1.18–17.92), a high differentiation index (78.45–93.04) and a medium A/CNK ratio (0.98–1.69). The zircon Hf isotope dating indicates that the Xujiaba and Guandigou units have an inhomogeneous ε_Hf(t) (?4.425 to 1.067 for Xujiaba and ?4.920 to 2.042 for Guandigou) and two-stage Hf model ages (1123–1531 Ma for Xujiaba and 1115–2342 Ma for Guandigou). The geochemical and isotopic data imply that the granites of each unit share the same origin. They probably derived from the partial melt of metagreywackes and then mixed with the mantle-derived magma. Based on the regional geological history, petrographic characteristics and new geochemical and isotopic data of the Zhongchuan pluton, we suggest that the Triassic magma was derived from the partial melts of metagreywackes and was influenced by the mantle-derived melt during the collision of the Yangtze and Qinling plates.     

黄陵矿区煤层底板异常涌出气体成因类型

黄陵矿区属于煤油气共生矿区,区内多个工作面发生底板气异常涌出。为探明底板异常涌出气体的成因类型,采集煤层底板气样44个、2号煤层气样12个,进行甲烷碳同位素(δ¹³C₁)、乙烷碳同位素(δ¹³C₂)及甲烷氢同位素(δD_CH4)等地球化学参数测试。测试分析结果表明,煤层底板异常涌出气不是来源于2号煤层,其甲烷碳同位素(δ¹³C₁)测值为-52.20‰~-42.80‰,乙烷碳同位素(δ¹³C₂)值为-37.20‰~-29.01‰,成因类型属油型气。通过对区域烃源岩分布及地层裂隙系统的分析,认为黄陵矿区底板异常涌出气可能来源于三叠系延长组烃源岩。     

Constraining the timing of porphyry mineralization in northwest Iran in relation to Lesser Caucasus and Central Iran; Re–Os age data for Sungun porphyry Cu–Mo deposit

The Neo-Tethyan subduction in Iran is characterized by the Urumieh–Dokhtar magmatic arc (UDMA), formed by northeast-ward subduction of the oceanic crust beneath the central Iran. This belt coincides with the porphyry copper metallogenic belt that comprises several metallogenic zones, including Ahar–Jolfa in northwest Iran. The Ahar–Jolfa metallogenic zone encompasses two main batholiths of Qaradagh and Sheyvardagh and numerous intrusive bodies of Cenozoic, which have produced many base and precious metal deposits and prospects. The former is considered as continuation of the Meghri–Ordubad pluton in South Armenian Block (SAB), which also hosts porphyry copper deposits (PCDs). The Sungun PCD is the largest occurrence in northwest Iran. Rhenium-Osmium ages of Sungun molybdenites are early Miocene and range between 22.9 ± 0.2 and 21.7 ± 0.2 Ma. Comparison of the ages obtained here with published ages for mineralization across the region suggests the following sequence. The earliest porphyry Cu–Mo mineralization event in northwest Iran is represented by Saheb Divan PCD of late Eocene age, which is followed by the second epoch of middle Oligocene, including the Cu–Mo–Au mineralization at Qarachilar and the Haftcheshmeh PCD. Mineralization in Sungun, Masjed Daghi, Kighal and Niaz deposits corresponds to the third mineralization event in northwest Iran. The first epoch in northwest Iran postdates all Eocene mineralizations in SAB, while the second epoch is coeval with Paragachay and the first-stage of Kadjaran PCDs. Its third epoch is younger than all mineralizations in SAB, except the second stage in Kadjaran PCD. Finally, the Cu mineralization epochs in northwest Iran are older than nearly all PCDs and prospects in Central Iran (except the Bondar Hanza PCD), altogether revealing an old to young trend along the UDMA and the porphyry Cu belt towards southeast, resulted from diachronous, later closure of the Neo-Tethyan oceanic basin in central and SE Iran.     

北秦岭中生代沙河湾岩体环斑结构特征及有关问题的讨论

该岩体的环斑结构主要发育于边部含巨斑状黑云角闪石英二长岩中 ,环斑长石粒径一般 2cm× 4cm。形态多呈自形、半自形 ,有些为卵形。环斑长石由核部钾长石和多层或单层斜长石外壳两部分构成。钾长石内核呈肉红色 ,一般是由单颗粒组成 ,具卡氏双晶 ,普遍发育规则的条纹结构 ;中心部分钾长石分子含量Or为 95 ,边部为 84。外壳斜长石牌号一般为An2 0± ,为奥长石。内核和外壳中均发育石英、斜长石、黑云母、角闪石等矿物的包裹体 ;包裹体在其边部较多 ,中部较少 ,钾长石斑晶中的石英包裹体呈不规则的凹面状和水滴状。岩石中主要矿物具有 2个世代。这些特征显示 ,沙河湾岩体中的环斑结构与典型的环斑结构是相同的。亦表明典型的环斑结构可以出现于不同的时代和构造环境。由于其形成时代和产出背景不同于典型环斑花岗岩 ,该岩体属典型环斑花岗岩还是一种新的似环斑花岗岩还有待于进一步研究。