剪切带流体与蚀变和金矿成矿作用

剪切带中流体与金矿中交代蚀变作用密切相关。剪切带中往往发育不同期次、不同类型的蚀变及交代蚀变岩 ,第二、三期交代蚀变岩的形成与金矿化关系密切。在含金断裂蚀变带中 ,由于剪切带流体的强烈交代作用 ,交代蚀变岩成为金矿的重要矿石类型。剪切带中的流体往往携带大量成矿物质而成为成矿流体 ,并在金矿形成过程中起着重要。在剪切带中 ,由于压力迅速降低 ,经常导致成矿流体发生沸腾作用 ,从而导致金矿的形成。成矿主要与脆性变形有关 ,韧性剪切变形向脆性剪切变形转变至关重要。从韧性剪切带向脆性剪切带转变的过程中 ,Au ,Ag ,Cu ,Pb发生大规模的活化迁移 ,并在较窄的脆性断裂中明显富集 ,形成矿体或矿化体。岩浆流体是剪切带成矿流体中最为重要的一种流体 ,许多金矿的成矿物质来源于岩浆流体     

Geology and Lead–Sulphur Isotope Compositions of the Tongyu Volcanic-Hosted Massive Sulphide Copper Deposit in the Western Part of the North Qinling Orogen, China

The Tongyu copper deposit, located in the western part of the North Qinling Orogen, China, is one of several volcanic-hosted massive sulphide(VHMS) deposits with industrial value and is also a typical example of mineralization related to the subduction and metallogenesis during the Caledonian orogeny. We conducted systematic lead-sulphur isotope geochemical analyses of the Tongyu deposit to understand the possible ore-forming material sources and tectonic settings. Twenty-six sulphide samples yielded clustered δ~(34)S_(CDT) values of 1.13‰-3.36‰, average 2.22‰, and show a tower-type distribution,implying that the sulphur of the Tongyu copper deposit mainly originated from a mantle source. The Pb isotope compositions of sulphides(~(206)Pb/~(204)Pb = 17.59225-18.56354, average 18.32020; ~(207)Pb/~(204)Pb =15.51770-15.69381, average 15.66217; ~(208)Pb/~(204)Pb= 37.99969-39.06953, average 38.52722) are close to the values of the volcanic host rocks(~(206)Pb/~(204)Pb= 18.10678-18.26293, average 18.21158; ~(207)Pb/~(204)Pb =15.63196-15.68188, average 15.65345; ~(208)Pb/~(204)Pb= 38.43676-38.56360, average 38.49171), thus consistent with the Pb in ores and volcanic host rocks having been derived from a common source that was island-arc Pb related to oceanic crust subduction. The northward subduction of the Palaeo-Qinling oceanic crust triggered dehydration of the slab, which generated a large amount of high-oxygen-fugacity aqueous hydrothermal fluid. The fluid rose into the mantle wedge, activated and extracted metallogenic material and promoted partial melting of the mantle wedge. The magma and ore-forming fluid welled up and precipitated, finally forming the Tongyu VHMS copper deposit.     

翁泉沟含铀硼铁矿床综合开发利用研究与对策

翁泉沟含铀硼铁矿中硼(B2O3)储量约占我国总储量的一半,矿床经勘探后一直没有很好得到利用。在综合利用资料积累与地质研究基础上,认为影响矿床利用的因素主要为矿石分解状况。研究认为矿床中硼镁铁矿-磁铁矿和硼镁石-磁铁矿两种主要类型矿石中绝大部分为可利用的变质后期热液作用产生的硼镁石-磁铁矿型矿石。这种热液作用形成的矿石是有规律可寻的。为达到综合利用的目的,有必要按不同类型矿石重新圈定矿体,根据不同矿体中硼镁铁矿分解率指标,选择两种不同综合利用方案。     

青海铜厂沟金矿床围岩蚀变特征与矿化

铜厂沟金矿床围岩蚀变强烈，并受构造脉动的控制，蚀变具不规则环形分带；蚀变作用划分为硅化－绿泥石化、硅化－碳酸盐化、黄铁矿化和硅化－黄铁矿化等四阶段，金矿化发生在黄铁矿化阶段。根据围岩蚀变特征，在已知矿体的下部，可以寻找构造－蚀变岩型金矿体。     

西藏曲水县达布斑岩铜(钼)矿床成岩成矿年代学研究

本文采用锆石LA-ICP-MS微区U-Pb测年技术,对冈底斯成矿带东段曲水县达布斑岩Cu(Mo)矿床北部达布矿区含矿斑岩体、南部显角囊含矿花岗闪长斑岩岩体进行了年代学研究,通过对3件岩体样品中单颗粒锆石的分析,达布主矿体花岗闪长斑岩样品206Pb/238U年龄加权平均值为16.5±0.05Ma(n=15,MSWD=3),达布主含矿体二长花岗斑岩样品年龄为16.1±0.13Ma(n=15,MSWD=1.03),南部显角囊矿体花岗闪长斑岩年龄为16.2±0.04Ma(n=13,MSWD=0.0064)。对达布矿床斑岩Cu(Mo)矿床主矿体中4件辉钼矿样品,显角囊矿体中6件辉钼矿样品,分别进行了Re-Os同位素测试,等时线年龄分别为14.6±0.50Ma(MSWD=0.35,主矿体)、14.8±0.23Ma(MSWD=1.3,显角囊)。结合前人研究以及本次测年结果认为:1)达布斑岩铜(钼)矿床岩体侵位的年龄应限定在16Ma左右,成矿时代为14Ma左右,成矿时间差小于0.86Ma,与区域上"成矿瞬时发生"的成矿规律是一致的;2)矿床产出于印度-亚洲大陆板块后碰撞伸展环境。     

西藏多龙矿集区地堡铜(金)矿床年代学、流体包裹体、地球化学特征及其成因类型研究

多龙矿集区位于班公湖-怒江成矿带西段北侧、羌塘地块南缘,是我国近年来发现的最大斑岩-浅成低温热液型Cu(Au)矿集区。地堡是多龙矿集区最西南边缘的矿床,资源潜力巨大,有望达到超大型规模,但研究程度薄弱。本次工作对地堡Cu(Au)矿开展了锆石U-Pb测年、流体包裹体、地球化学等方面的研究,为推动资源勘查和矿集区成矿规律的总结提供理论依据。含矿斑岩锆石206 Pb/238 U平均加权年龄为111.2±0.4Ma(MSWD=0.67),与矿集区成矿岩浆活动时限一致,是矿集区重要组成部分。石英脉流体包裹体显示矿床主成矿期成矿流体温度集中于140~382℃,主要集中在240~280℃。成岩阶段石英斑晶中Ⅰ型包裹体盐度范围为0.2%~20.7%NaCleqv.,含盐子晶包裹体盐度为33.6%NaCleqv.和43.9%NaCleqv.;成矿阶段不含石膏石英脉Ⅰ型包裹体盐度范围为0.2%~20.8%NaCleqv.,黄铁矿石英脉Ⅰ型包裹体盐度范围为1.1%~11.1%NaCleqv.,石膏中Ⅰ型包裹体盐度范围为0.5%~9.3%NaCleqv.。对钻孔DNZK6428样品进行主微量元素测试并进行因子分析计算,结果表明F1、F2、F3代表成岩阶段,因子主成分为Y-Ho-Er-Tm-Yb-Dy-Lu-Tb-Eu-Gd-Sm-La-Ce-Pr-Nd-SiO_2-Al_2O_3-CaO等,F4和F5代表铜金矿化阶段,因子主成分为Sn-Sb-Ba-Fe_2O_3-Sr-|SiO_2|-Ni-Cu-U-In-Cd-Au-Zn。黄铁矿δ34SV-CDT值总体较为集中,呈"双峰塔式"分布,变化范围为-7.8‰~4.1‰,均值为-4.23‰,为深源岩浆硫,硫的来源接近地幔硫。矿床粒状黄铁矿Co/Ni比值为0.207~10.775,平均值4.39,脉状黄铁矿Co/Ni比值为0.353~23.155,平均值3.802,均为热液成因。矿相学与岩相学研究结果显示矿床具明矾石和硫砷铜矿典型高硫化浅成低温热液矿床的矿物组合,地堡Cu(Au)矿为高硫型浅成低温热液矿床。     

云南老王寨金矿区煌斑岩的源区成分模拟

本文在总结云南老王寨金矿区煌斑岩的主要元素、过渡元素、亲石元素、稀土元素和同位素地球化学特征的基础上．利用岩石学混合计算方法对其源区成分进行了模拟，进而讨论了矿区这类岩石的成因。地球化学和模拟计算均表明，老王寨金矿区煌斑岩来源于交代富集地幔，板块俯冲（印度板块向欧亚板块俯冲）富含ALK、LREE及不相容元素的海底沉积物被带入地幔脱水形成的流体是引起本区地幔交代作用的主要因素。     

Magmatic‐Hydrothermal Mineralization Sequence in Xinlu Ore Field,Guangxi, South China: Constraints from Zircon U‐Pb,Molybdenite Re‐Os,and Muscovite Ar‐Ar Dating

The Xinlu Sn‐polymetallic ore field is located in the western Nanling Polymetallic Belt in northeastern Guangxi, South China, where a number of typical skarn‐, hydrothermal vein‐type tin deposits have developed. There are two types of Sn deposits: skarn‐type and sulfide‐quartz vein‐type. The tin mineralizations mainly occur on the south side of the Guposhan granitic complex pluton and within its outer contact zone. To constrain the Sn mineralization age and further understand its genetic links to the Guposhan granitic complex, a series of geochronological works has been conducted at the Liuheao deposit of the ore field using high‐precision zircon SHRIMP U‐Pb, molybdenite Re‐Os, and muscovite Ar‐Ar dating methods. The results show that the biotite‐monzogranite, which is part of the Xinlu intrusive unit of the Guposhan complex pluton, has a SHRIMP U‐Pb zircon age of 161.0 ± 1.5 Ma. The skarn‐type ore has a ⁴⁰Ar‐³⁹Ar muscovite plateau age of 160 ± 2 Ma (same as its isochron age), and the sulfide‐quartz vein‐type ore yields an Re‐Os molybdenite isochron age of 154.4 ± 3.5 Ma. The magmatic‐hydrothermal geochronological sequence demonstrated that the hydrothermal mineralization took place immediately following the emplacement of the monzogranite, with the skarn metasomatic mineralization stage predating the sulfide mineralization stage. Geochronologically, we have compared this ore field with 26 typical Sn deposits distributed along the Nanling Polymetallic Belt, leading to the suggestion of the magmatic‐metallogenic processes in the Xinlu ore field (ca. 161–154 Ma) as a component of the Early Yanshanian large‐scale Sn‐polymetallic mineralization event (peaked at 160–150 Ma) in the Nanling Range of South China. Petrogenesis of Sn‐producing granite and Sn‐polymetallic mineralization were probably caused by crust–mantle interaction as a result of significant lithospheric extension and thinning in South China in the Late Jurassic.     

共生黑钨矿与石英等多种矿物中流体包裹体的红外显微测温对比研究——以江西西华山石英脉钨矿床为例

西华山钨矿床是一个产于燕山期花岗岩中的大脉型钨矿床。已有百余年的开采史。但在矿床成矿条件和成矿流体性质等方面一直存在不同认识。作者利用红外显微镜及其它相关设备,对西华山矿床不同中段样品中的黑钨矿、锡石、绿柱石、黄铁矿、闪锌矿、石英和萤石中的流体包裹体进行了详细对比研究。结果显示,蚀变花岗岩中造岩石英只见次生气液包裹体,晶洞水晶中只有原生包裹体,而云英岩石英中原生、次生包裹体均较发育。黑钨矿中以原生气液包裹体为主,在早期结晶的黑钨矿中还有较多的硅酸盐熔融包裹体,而晶洞中的黑钨矿和水晶一样——只有原生气液包裹体。绿柱石中除了硅酸盐包裹体外,主要是气液包裹体(多为次生)。其它锡石、黄铁矿、闪锌矿和萤石等都只有气液包裹体(原生或次生)。研究结果表明,西华山钨矿床的初始成矿流体是一种岩浆——热液过渡性流体,尔后才演变成单一的热水溶液,在这一过程中黑钨矿、黄铁矿、闪锌矿、萤石和石英等矿物不断晶出。矿床总的成矿温度大致为700~200℃,压力约为160~200MPa。各种气液包裹体的盐度主要为5.0%~10%Na Cleqv。文中还对这些数据的地质意义以及对脉钨矿床流体包裹体研究和数据解释中的某些问题进行了较深入的讨论。     

广西昭平县湾岛金矿控矿条件调查研究与靶区预测

本文以桂东大瑶山金矿集区最新勘探发现的广西昭平湾岛金矿为例,对其开展控矿条件调查研究,发现该矿床的金矿体有两种类型,分别受到花岗斑岩体、构造破碎带控制,斑岩体锆石u-Th-Pb年龄(465Ma)与构造破碎带控制的含金石英脉Ar-Ar年龄(187.87～244.88Ma)的明显差异也说明多种矿化类型的存在.弄清以上两个控...