滇西思茅大平掌矿区火山岩特征及其构造环境

滇西大平掌铜多金属矿床的含矿建造(龙洞河组)主要由细碧岩-角斑岩-石英角斑岩和流纹岩-硅质岩组成,伴有部分火山角砾岩、凝灰岩,属双峰式火山岩组合。火山岩具明显的Na2O>K2O和Nb、Ta、Zr、Hf、Ti亏损。岩石化学和微量元素判别标志指示含矿建造形成于岛弧裂陷环境。结合区域构造古地理资料分析,它是滇西南古特提斯洋壳在晚石炭世-早二叠世由西向东俯冲过程中岩浆作用的结果。     

A mineral equilibria study of the hydrothermal alteration in mafic greenschist facies rocks at Kalgoorlie, Western Australia

The influx of a H₂O–CO₂‐dominated fluid into actinolite‐bearing metabasic rocks during greenschist facies metamorphism in the Kalgoorlie area of Western Australia resulted in a zoned alteration halo around inferred fluid conduits that contain gold mineralisation. The alteration halo is divided into two outer zones, the chlorite zone and the carbonate zone, and an inner pyrite zone adjacent to the inferred fluid conduits. Reaction between the fluid and the protolith resulted in the breakdown of actinolite and the development of chlorite, dolomite, calcite and siderite. In addition, rocks in the pyrite zone developed muscovite‐bearing assemblages as a consequence of the introduction of potassium by the fluid. Mineral equilibria calculations undertaken using the computer software thermocalc in the model system Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–CO₂ show that mineral assemblages in the outer zones of the alteration halo are consistent with equilibrium of the protoliths with a fluid of composition X_CO2 = CO₂/(CO₂ + H₂O) = 0.1–0.25 for temperatures of 315–320 °C. The inner zone of the alteration halo reflect equilibrium with a fluid of composition X_CO2≈ 0.25. Fluid‐rock buffering calculations show that the alteration halo is consistent with interaction with a single fluid composition and that the zoned structure of the halo reflects the volume of this fluid with which the rocks reacted. This fluid is likely to have also been the one responsible for the gold mineralisation at Kalgoorlie.     

Magnetotelluric Investigation of the Hydrothermal System and Heat Source in the Muine-Toyoha Geothermal Area, Hokkaido, Japan

Abstract. Magnetotelluric (MT) surveys were carried out around the Muine volcano, Hokkaido, Japan, where it is expected that the heat and metal source forming the polymetallic Ag-Pb-Zn-Cu-In Toyoha deposit is present at depth. Measurements were performed at 20 sites, 18 of which were located along a WSW-ENE profile traversing the north ridge of Mt. Muine. A resistivity model obtained from 2D inversion of the MT data shows subsurface specific conductive and resistive features. Conductive layers are present at the surface of Mt. Muine. The low resistivity is probably due to the clay-rich rocks associated with the hydrothermal alteration. A high resistivity layer, which corresponds to the pre-Tertiary Usubetsu Formation, crops out east of Mt. Muine and dips westward. At the west foot of Mt. Muine, relatively high resistive layers are widely exposed. The resistivity increases with depth and exceeds 1000 ohm-m. This fact indicates that this region is not influenced by the recent hydrothermal activity. An extremely conductive zone about 3–6 km wide and 6–9 km thick exists at a depth of 2 km below Mt. Muine. This zone mostly corresponds to an elastic wave attenuation zone detected by a seismic survey. It is interpreted as a large hydrothermal reservoir or melted magma, which is a heat source of the hydrothermal system in this area.     

Geology and Genesis of the Ta'ergou Skarn - Quartz Vein Tungsten Deposit in the North Qilian Caledonian Orogenic Belt, Northwest China

Abstract. The Ta'ergou tungsten deposit in Gansu province, northwestern China, is located in the western part of the North Qilian Caledonian orogen, and consists of scheelite skarn bodies and wolframite quartz veins. The tungsten‐bearing skarn developed by the replacement of carbonate layers intercalated in the Precambrian schist and amphibolite whereas wolframite‐quartz ore veins developed along a group of fractures that cut through horizontal skarns. The Ta'ergou tungsten deposit is genetically related to the Caledonian Yeniutan granodiorite intrusion and occurs ca. 500 m wide in the exo‐contact zone 300 ～ 500 m apart from the intrusion. The granodiorite displays a lower grade of differentiation, low content of SiO₂ and high contents of mafic components. There are three types of fluid inclusions in the wolframite‐quartz vein systems, i. e. aqueous, CO₂‐H₂O and CO₂‐rich. The homogenization temperature of aqueous inclusion ranges from 140 to 380d?C and their salinities from 6.4 to 17.4 equivalent wt% NaCl. Laser Raman spectroscopy shows that the inclusions contain a relatively high content of CO₂. The δ³⁴S values of skarn type sulfides range from +8.1 to +12.7 per mil and those of quartz vein sulfides from +9.3 to +14.9 per mil, similar to sulfides of the granodiorite with from +6.0 to +11.7 per mil. The δ¹⁸O values of quartz are between +10.5 and +13.3 per mil and those of wolframite between +3.4 and +5.1 per mil. The δ¹⁸O water values of ore forming fluids range from +0.6 to +6.4 per mil and suggest the mixture of magmatic fluids with meteoric water formed the ore‐forming fluids. It has been proved that Precambrian strata in the west sector of North Qilian region are enriched in tungsten. We propose the strata were remelted to be tungsten‐granitoid during subduction. The polymetallic tungsten was gradually accumulated into the roof pendants of the granite intrusion by fractional crystallization and then was deposited by hydrothermal fluids during metasomatism and infilling along fractures. On the other hand, the granite intrusion also acted as “heating machine” to make hydrothermal fluids leach out the metals from Precambrian strata and these metals joined the ore‐forming hydrothermal system.     

Copper-Polymetal Metallogenic Series and Prospecting Perspective of Eastern Section of Gangdise

Geological, geophysical, geochemical and remote sensing comprehensive studies show that big ore-prospecting potentiality is contained in the eastern section of the Gangdise Mountains, Tibet.There are various mineralization types with dominant types of porphyry and exhalation. According to their relations with tectonic evolution, they are divided into four kinds of metallogenic series as follows:magnmtic type (Cr, Pt, Cu, Ni) and exhalation type (Cu, Pb, Zn, Ag) ore deposit series related to Neo-Tethys oceanic crust subduction action (125-96 Ma); epithermai type (Au, Ag, Pb, Zn, Sb), altered fractured rock type (Cu, Mo) and skarn rock type (Cu) ore deposit series related to arc-continental collision; porphyry type (Cu, Mo), cryptoexplosion breccia type (Cu, Au, Pb, Zn), shear zone type (Au, Ag, Sb) and skarn rock type (Cu, Fe) ore deposit series with relation to post-orogenic extensional strike-slip. From subductive complex to the north, zoning appears to be crystallization differentiation type (segregation type)-shear zone type (altered rock type)-skarn rock type, epithermai type-porphyry type-porphyry type and exhalation type-exhalation type-hydrothermai filling-replacement type.The ore deposit is characterized by multi-places from the same source, parity and multi-stage, hypabyssal rock from the deep source and poly genetic compound as a whole.     

Pb同位素三维空间拓扑投影与化探评价

通过对数据集合的拓扑学分析，获得了Pb同位素三维空间拓扑投影特征值V1和V2。运用特征值可以定量地预测隐伏铜金矿床的埋藏深度和隐伏矿量，是隐伏矿预测评价的新方法，开创了同位素化探的新领域。     

冀北张麻井铀钼矿床黄铁矿化蚀变岩地球化学迁移特征及与成矿关系亲缘性的讨论

张麻井铀钼矿床是中国北方最大的与火山岩有关的热液铀矿床，围岩蚀变广泛发育，其中黄铁矿化在该矿床分布虽 较为局限，但是与铀钼成矿关系密切。为了研究黄铁矿化蚀变与铀、钼成矿的亲缘关系，文章对张麻井的黄铁矿化蚀变岩 进行主、微量元素分析，并选择Yb作为不活动组分，使用质量平衡迁移计算方法， 利用Grant公式对其组分迁移进行定量 计算。岩石地球化学特征显示，黄铁矿化蚀变岩的TFeO含量极高，介于11.24%~24.57%之间(平均18.45%)，其中Fe2O3含量 10.78%~25.25% （平均18.64%）、FeO含量1.43%~1.90% （平均1.69%），Fe2O3/FeO比值平均为10.99，有可能受到后期氧 化。黄铁矿化蚀变岩在Isocon图解上等浓度线斜率小于1，表明整体发生了组分的带入，带入的主要组分为大量的TFeO （131倍），成矿元素Mo（884倍）、Pb（11倍）、U（4.9倍）、V（2.8倍）、Ta（0.44倍）、Cu（0.64倍），碱金属Na2O（0.45 倍），以及Cd（424倍）、Bi（13倍） 等；带出的主要组分有碱金属Li（-0.73）、K2O（-0.17），成矿元素Zn（-0.38）、Cr （-0.37），以及Eu（-0.58）、Sc（-0.25） 等。其中SiO2略微减少（-0.03），带入的Mo含量远大于U的含量，据此认为黄铁 矿化与钼成矿关系更为密切。     

新疆哈图金矿微球粒的发现及其地质意义

采自新疆哈图金矿区各地层单元和含矿脉体中的基岩人工重砂样品普遍含有一种“微球粒”物质。通过“微球粒”的一般特征，表面、断面结构、矿物组成和化学成分的研究，认为属消融型宇宙尘。并据此提出区内玄武质母岩浆在形成玄武岩的过程中同化、熔融了含宇宙尘的局部老地层物质；为区内金矿化提供含矿热液的花岗岩属重熔型花岗岩。     

指示红土型金矿表征的遥感地质特征

红土风化壳中铁、锰质和粘土等矿物的含量高，存在大量的Ｆｅ３＋、Ｆｅ２＋、Ｍｎ２＋、Ｈ２Ｏ、（ＯＨ）１－、ＣＯ２３等离子，而这些离子团的含量决定了红土风化壳的发射波谱性状，应用ＴＭ波段对这些离子团的探测能力，就有可能识别到红土风化壳及与红土型金矿有关的地物目标。湘南地区的ＴＭ数据处理，表明了与已知红土型金矿对应的“ＫＬ特征标志色块”可作为红土型金矿成矿预测的最佳标志。