A multi‐technique study of the glacial stratigraphy of Co. Clare and Co. Kerry,southwest Ireland

A multi‐technique approach has been adopted in a study of the lithostratigraphy of glacial deposits in southwestern Ireland, including clast lithological analysis, fine sand geochemistry, low frequency mass specific susceptibility and fine sand calcium carbonate (equivalent) content. A revised lithostratigraphical scheme is suggested for the Quaternary glacial deposits of the region, together with a simple strategy that may be adopted for stratigraphical studies in other regions of southern Ireland. It appears that geochemical determinations via inductively coupled plasma–atomic absorption spectrometry are particularly useful in characterising and discriminating between till units within local stratigraphical studies and may be used to inform the applicability of other utilitarian techniques for use on a regional scale. Copyright © 2002 John Wiley & Sons, Ltd.     

Thermal expansion of gehlenite, Ca2Al[AlSiO7], and the related aluminates LnCaAl[Al2O7] with Ln=Tb, Sm

The thermal expansion of gehlenite, Ca₂Al[AlSiO₇], (up to T=830 K), TbCaAl[Al₂O₇] (up to T=1,100 K) and SmCaAl[Al₂O₇] (up to T=1,024 K) has been determined. All compounds are of the melilite structure type with space group Thermal expansion data was obtained from in situ X-ray powder diffraction experiments in-house and at HASYLAB at the Deutsches Elektronen Synchrotron (DESY) in Hamburg (Germany). The thermal expansion coefficients for gehlenite were found to be: α₁=7.2(4)×10⁻⁶ K⁻¹+3.6(7)×10⁻⁹ΔT K⁻² and α₃=15.0(1)×10⁻⁶ K⁻¹. For TbCaAl[Al₂O₇] the respective values are: α₁=7.0(2)×10⁻⁶ K⁻¹+2.0(2)×10⁻⁹ΔT K⁻² and α₃=8.5(2)×10⁻⁶ K⁻¹+2.0(3)×10⁻⁹ΔT K⁻², and the thermal expansion coefficients for SmCaAl[Al₂O₇] are: α₁=6.9(2)× 10⁻⁶ K⁻¹+1.7(2)×10⁻⁹ΔT K⁻² and α₃=9.344(5)×10⁻⁶ K⁻¹. The expansion-mechanisms of the three compounds are explained in terms of structural trends obtained from Rietveld refinements of the crystal structures of the compounds against the powder diffraction patterns. No structural phase transitions have been observed. While gehlenite behaves like a ’proper’ layer structure, the aluminates show increased framework structure behaviour. This is most probably explained by stronger coulombic interactions between the tetrahedral conformation and the layer-bridging cations due to the coupled substitution (Ca²⁺+Si⁴⁺)-(Ln ³⁺+Al³⁺) in the melilite-type structure. Electronic Supplementary Material Supplementary material is available for this article at     

Anthropogenic iodine-129 in seawater along a transect from the Norwegian coastal current to the North Pole

Variation in the concentrations of iodine-129 (129I, T1/2=15.7 Myr), a low-level radioactive component of nuclear fuel waste, is documented in surface waters and depth profiles collected during 2001 along a transect from the Norwegian Coastal Current to the North Pole. The surface waters near the Norwegian coast are found to have 20 times higher 129I concentration than the surface waters of the Arctic Ocean. The depth profiles of 129I taken in the Arctic Ocean reveal a sharp decline in the concentration to a depth of about 300-500 m followed by a weaker gradient extending down to the bottom. A twofold increase in the 129I concentration is observed in the upper 1000 m since 1996. Based on known estimates of marine transient time from the release sources (the nuclear reprocessing facilities at La Hague, France, and Sellafield, UK), a doubling in the 129I inventory of the top 1000 m of the Arctic Ocean is expected to occur between the years 2001 and 2006. As 129I of polar mixed layer and Atlantic layer of the Arctic Ocean is ventilated by the East Greenland Current into the Nordic Seas and North Atlantic Ocean, further dispersal and increase of the isotope concentration in these regions will be encountered in the near future.     

First observations of the Na exosphere of Mercury with the high-resolution spectrograph of the 3.5M Telescopio Nazionale Galileo

Analysis of three spectra of the exosphere of Mercury in the Na-D lines are presented. Spectra were secured with the high-resolution spectrograph (SARG) of the 3.5 M Telescopio Nazionale Galileo (TNG, located on the Roque de los Muchachos, Canaries) on the evenings of August 23 and 24, 2002. Spectra have resolution ; the slit length was 26.7”. The Na column abundances range from 4.3 to with the highest abundances being close to the illuminated limb. Our observations at true anomaly angles (TAA) from 171°to 174°show the traces of the emission lines to be strongly peaked at the illuminated limb, supportive of recent modeling that shows thermal desorption to be a strong factor in determining the distribution of Na about the planet.     

CBERS-02B卫星遥感影像的区域网平差

针对中巴资源一号卫星(CBERS-02B)卫星遥感影像姿态角误差较大的特点,提出了利用区域网平差方法提高其对地目标定位精度的策略和具体计算过程。首先对参与平差的每景影像选取4个地面控制点进行影像姿态角常差检校,然后采用与地形无关方案解求各自的RPC参数,最后选取带仿射变换项的有理函数模型(RFM)进行多重覆盖影像的区域网平差。对两个地区的0级CBERS-02B单条CCD立体影像对的区域网平差试验表明,对地目标定位的平面和高程精度均达到了±3个像元的水平,且高程精度明显优于平面精度。相对于常规的卫星遥感影像区域网平差方法,平面和高程精度均有明显提升,几乎达到国外同等高分辨率卫星遥感影像的几何定位精度。这说明中国卫星遥感影像亦具有较好的几何定位潜力,在区域网平差之前进行系统误差预改正是必要和可行的。     

Simulation of Precipitation in Monsoon Regions of China by CMIP3 Models

The output of 25 models used in the Coupled Model Intercomparison Project phase 3 （CMIP3） were evaluated, with a focus on summer precipitation in eastern China for the last 40 years of the 20th century. Most models failed to reproduce rainfall associated with the East Asian summer monsoon （EASM）, and hence the seasonal cycle in eastern China, but provided reasonable results in Southwest （SW） and Northeast China （NE）. The simulations produced reasonable results for the Yangtze-Huai （YH） Basin area, although the Meiyu phenomenon was underestimated in general. One typical regional phenomenon, a seasonal northward shift in the rain belt from early to late summer, was completely missed by most models. The long-term climate trends in rainfall over eastern China were largely underestimated, and the observed geographical pattern of rainfall changes was not reproduced by most models. Precipitation extremes were evaluated via parameters of fitted GEV （Generalized Ex- treme Values） distributions. The annual extremes were grossly underestimated in the monsoon-dominated YH and SW regions, but reasonable values were calculated for the North China （NC） and NE regions. These results suggest a general failure to capture the dynamics of the EASM in current coupled climate models. Nonetheless, models with higher resolution tend to reproduce larger decadal trends and annual extremes of precipitation in the regions studied.     

GLDAS和CMIP5产品的中国土壤湿度-降水耦合分析及变化趋势

利用GLDAS同化产品和12个CMIP5模式的输出结果,从土壤湿度对降水影响的两个中间环节出发,通过分析陆面耦合指数ILH、潜热通量—抬升凝结高度耦合指数ILCL以及抬升凝结高度ZLCL间接研究中国区域土壤湿度与降水间耦合特征,并对1958~2013年及RCP4.5辐射强迫情景下50年(2006~2055年)的4个代表性区域夏季耦合强度的年代际变化特征进行分析。研究发现:1958~2013年期间,内蒙古阴山山脉附近、新疆和青海的部分地区为夏季中国土壤湿度与降水耦合的最强区域;陆面耦合指数ILH变化幅度从高到低依次出现在华北、华南、内蒙古中部和西北地区,并在20世纪70年代中到80年代中发生转折。2006~2055年的平均而言,预估内蒙古阴山山脉附近仍为耦合最强区;与历史时期(1958~2005年)比较,新疆中部和内蒙古阴山山脉附近的耦合指数ILH增大,而广西和广东地区的则减小;对于耦合指数ILH的年代际变化(2006~2055年),2026~2035年间华北最大而华南最小,西北地区变化不大,而内蒙古中部地区的耦合强度逐渐增大。     

Luciola hypertelescope space observatory: versatile, upgradable high-resolution imaging, from stars to deep-field cosmology

Luciola is a large (1 km) “multi-aperture densified-pupil imaging interferometer”, or “hypertelescope” employing many small apertures, rather than a few large ones, for obtaining direct snapshot images with a high information content. A diluted collector mirror, deployed in space as a flotilla of small mirrors, focuses a sky image which is exploited by several beam-combiner spaceships. Each contains a “pupil densifier” micro-lens array to avoid the diffractive spread and image attenuation caused by the small sub-apertures. The elucidation of hypertelescope imaging properties during the last decade has shown that many small apertures tend to be far more efficient, regarding the science yield, than a few large ones providing a comparable collecting area. For similar underlying physical reasons, radio-astronomy has also evolved in the direction of many-antenna systems such as the proposed Low Frequency Array having “hundreds of thousands of individual receivers”. With its high limiting magnitude, reaching the m _v?=?30 limit of HST when 100 collectors of 25 cm will match its collecting area, high-resolution direct imaging in multiple channels, broad spectral coverage from the 1,200 Å ultra-violet to the 20 μm infra-red, apodization, coronagraphic and spectroscopic capabilities, the proposed hypertelescope observatory addresses very broad and innovative science covering different areas of ESA’s Cosmic Vision program. In the initial phase, a focal spacecraft covering the UV to near IR spectral range of EMCCD photon-counting cameras (currently 200 to 1,000 nm), will image details on the surface of many stars, as well as their environment, including multiple stars and clusters. Spectra will be obtained for each resel. It will also image neutron star, black-hole and micro-quasar candidates, as well as active galactic nuclei, quasars, gravitational lenses, and other Cosmic Vision targets observable with the initial modest crowding limit. With subsequent upgrade missions, the spectral coverage can be extended from 120 nm to 20 μm, using four detectors carried by two to four focal spacecraft. The number of collector mirrors in the flotilla can also be increased from 12 to 100 and possibly 1,000. The imaging and spectroscopy of habitable exoplanets in the mid infra-red then becomes feasible once the collecting area reaches 6 m², using a specialized mid infra-red focal spacecraft. Calculations (Boccaletti et al., Icarus 145, 628–636, 2000) have shown that hypertelescope coronagraphy has unequalled sensitivity for detecting, at mid infra-red wavelengths, faint exoplanets within the exo-zodiacal glare. Later upgrades will enable the more difficult imaging and spectroscopy of these faint objects at visible wavelengths, using refined techniques of adaptive coronagraphy (Labeyrie and Le Coroller 2004). Together, the infra-red and visible spectral data carry rich information on the possible presence of life. The close environment of the central black-hole in the Milky Way will be imageable with unprecedented detail in the near infra-red. Cosmological imaging of remote galaxies at the limit of the known universe is also expected, from the ultra-violet to the near infra-red, following the first upgrade, and with greatly increasing sensitivity through successive upgrades. These areas will indeed greatly benefit from the upgrades, in terms of dynamic range, limiting complexity of the objects to be imaged, size of the elementary “Direct Imaging Field”, and limiting magnitude, approaching that of an 8-m space telescope when 1,000 apertures of 25 cm are installed. Similar gains will occur for addressing fundamental problems in physics and cosmology, particularly when observing neutron stars and black holes, single or binary, including the giant black holes, with accretion disks and jets, in active galactic nuclei beyond the Milky Way. Gravitational lensing and micro-lensing patterns, including time-variable patterns and perhaps millisecond lensing flashes which may be beamed by diffraction from sub-stellar masses at sub-parsec distances (Labeyrie, Astron Astrophys 284, 689, 1994), will also be observable initially in the favourable cases, and upgrades will greatly improve the number of observable objects. The observability of gravitational waves emitted by binary lensing masses, in the form of modulated lensing patterns, is a debated issue (Ragazzoni et al., MNRAS 345, 100–110, 2003) but will also become addressable observationally. The technology readiness of Luciola approaches levels where low-orbit testing and stepwise implementation will become feasible in the 2015–2025 time frame. For the following decades beyond 2020, once accurate formation flying techniques will be mastered, much larger hypertelescopes such as the proposed 100 km Exo-Earth Imager and the 100,000 km Neutron Star Imager should also become feasible. Luciola is therefore also seen as a precursor toward such very powerful instruments.     

An analytical approach to small amplitude solutions of the extended nearly circular Sitnikov problem

The model of extended Sitnikov Problem contains two equally heavy bodies of mass m moving on two symmetrical orbits w.r.t the centre of gravity. A third body of equal mass m moves along a line z perpendicular to the primaries plane, intersecting it at the centre of gravity. For sufficiently small distance from the primaries plane the third body describes an oscillatory motion around it. The motion of the three bodies is described by a coupled system of second order differential equations for the radial distance of the primaries r and the third mass oscillation z. This problem which is dealt with for zero initial eccentricity of the primaries motion, is generally non integrable and therefore represents an interesting dynamical system for advanced perturbative methods. In the present paper we use an original method of rewriting the coupled system of equations as a function iteration in such a way as to decouple the two equations at any iteration step. The decoupled equations are then solved by classical perturbation methods. A prove of local convergence of the function iteration method is given and the iterations are carried out to order 1 in r and to order 2 in z. For small values of the initial oscillation amplitude of the third mass we obtain results in very good agreement to numerically obtained solutions.     

气袋采样法对还原硫化物测定的影响因素分析及机理研究

还原硫化物是一Z类典型的恶臭物质,其特点是活性高、不易储存,因此适宜的储存条件对还原硫化物的准确测定具有重要意义。本文使用气相色谱-质谱联用技术,从气袋材质、还原硫化物初始浓度、还原硫化物性质和储存时间四个因素探究袋采样法储存还原硫化物过程的损失情况。以Tedlar~? PVF和Teflon~? FEP为目标采样袋,使用5个初始浓度(0. 001、0. 010、0. 100、1. 000和10. 000μg/m L)的混合还原硫化物,选择0、2、6、12、24、48以及72h的储存时间,以响应因子和相对回收率作为评价因子,并使用配对t检验法和吸附动力学,研究影响储存效果的主要因素、物质损失机理以及两种采样袋的储存能力。结果表明,储存时间越长、物质初始浓度越高,物质活性越强,损失情况越严重;在环境温度达到60℃时,Tedlar~? PVF的基质背景较Teflon~? FEP更复杂;相同条件下,还原硫化物在Teflon~? FEP储存过程中损失更严重。依据研究结果建议:(1)样品采集后避光保存;(2)低浓度含硫样品的测定在采样后8h内完成,高浓度含硫样品的测定在2h内完成;(3)若待测样品气体温度较高,优先选择Teflon~? FEP采样袋,气体温度较低条件下选择Tedlar~? PVF采样袋,可最大限度保持样品的原始状态。本研究成果有利于确保还原硫化物样品的储存稳定性,最大限度还原恶臭污染现场情况,为恶臭污染的分析测试以及后续的恶臭污染控制与治理提供技术支持。