Experimental study of the joins forsterite–diopside–leucite– and forsterite–leucite–åkermanite up to 2.3 GPa [P(H2O) = P(Total)] and variable temperatures: Its petrological significance

We conducted a series of melting experiments in the join forsterite–diopside–leucite under 0.1 and 2.3 GPa and in the join forsterite–leucite–åkermanite under 2.3 GPa to understand paragenetic relationships amongst different types of lamproitic and lamprophyric magmas with K-rich mafic and ultramafic volcanic (kamafugitic) rocks. Both the joins were studied in the presence of excess water. The experimental results of the join forsterite–diopside–leucite at 0.1 GPa show that the five-phase point of forsterite (Fo)_ss + diopside (Di)_ss + leucite (Lc)_ss + liquid (Liq) + vapour (V) (equivalent to ugandite lava) occurs at Fo₂Di₅₀Lc₄₈ at 880 ± 5 °C. Phlogopite appears as the last phase at 830 ± 15 °C. The final crystalline assemblage of forsterite_ss + diopside_ss + leucite_ss + phlogopite is similar to the phenocryst assemblage of missourite lava. Present study suggests that an olivine leucitite (ugandite) can be derived from an olivine italite, a slightly potassic peridotite and a leucitite magma.

A study of the join Fo–Di–Lc [P(H₂O) = P(Total)] at 2.3 GPa shows that liquid compositions penetrate the primary phase volumes of forsterite_ss, phlogopite_ss, kalsilitess, K-feldspar_ss and diopside_ss. It has the following three five-phase points: 1) one occurring at Fo₉Di₄₉Lc₄₂ and 1005 ± 5 °C, where liquid and vapour coexists with forsterite_ss, phlogopite_ss and diopside_ss (phlogopite-bearing madupite), 2) the second one at Fo₄Di₅₀Lc₄₆ and 990 ± 10 °C, where diopside_ss, K-feldspar_ss and phlogopite_ss coexist with liquid and vapour (pyroxene-bearing minette), and 3) the third one at Fo₃Di₂₁Lc₇₆ and 775 ± 5 °C, where phlogopite_ss, kalsilite_ss and K-feldspar_ss are in equilibrium with liquid plus vapour (kalsilite-bearing minette).

The experimental results of the join Fo–Lc–åkermanite (Ak) show that the join 40 penetrates the primary phase volumes of forsterite_ss, phlogopite_ss, kalsilite, K-feldspar_ss, diopside_ss and merwinite_ss. The data indicate the presence of four five-phase points: 1) one occurring at Fo₇Lc₄₂Ak₅₁ and 1165 ± 5 °C, where phlogopite_ss, forsterite_ss, diopside_ss coexists with liquid and vapour (olivine-bearing madupite), 2) the second one at Fo₃Lc₄₉Ak₄₈ and 1140 ± 10 °C, where a liquid is in equilibrium with phlogopite_ss, K-feldspar_ss, diopside_ss and vapour (pyroxene-bearing minette), 3) the third one at Fo₁₈Lc₂₁Ak₆₁ and 1255 ± 10 °C, where merwinite_ss, forsterite_ss and diopside_ss are in equilibrium with liquid and vapour (merwinite-bearing wherlite), and 4) the fourth one at Fo₅Lc_73.5Ak_21.5 and 770 ± 5 °C, where kalsilite_ss, phlogopite_ss and K-feldspar coexist with liquid and vapour (kalsilite-bearing minette). The present data suggest that high pressure heteromorphic equivalent of a katungite magma is represented by a kalsilite-bearing minette, a pyroxene-bearing minette, or an olivine-bearing madupite.     

Kyanite eclogite xenolith from the orthogneiss terrane of the Tisza Megaunit, Jánoshalma area, crystalline basement of southern Hungary

New evidence for high-pressure, eclogite facies metamorphism in the crystalline basement of the Tisza Megaunit (southern Hungary) is reported. The retrogressed mafic eclogite forms a small lens in the orthogneiss and it was found in the borehole near Jánoshalma. The carbonated eclogite contains the peak metamorphic assemblage omphacite + garnet + phengite + kyanite + clinozoizite + rutile + K-feldspar + quartz. Omphacite (Xjd_0.40–0.41Xdio_0.52–0.53Xhd_0.05Xaug_1.55–2.85) occurs in the matrix and as inclusions in garnet (Xpy_0.37–0.38Xgrs_0.21–0.22Xalm_0.39–0.40Xsps_0–0.01Xadr_0–0.01) and kyanite. Thermobarometry based on net-transfer reactions between garnet, omphacite, kyanite and phengite yields P–T conditions of 710 ± 10 °C and 2.6 ± 0.75 GPa. Retrogression during decompression is manifested by formation of symplectites; the most typical are diopside + plagioclase after omphacite, corundum + spinel + plagioclase after kyanite and biotite + plagioclase after phengite. Carbonatization along the veins of the retrogressed eclogite was probably coeval with formation of these symplectites. At places where carbonate is absent the rock was completely hydrated and retrogressed down to the greenschist facies with the development of actinolite. Similar eclogites together with abundant orthogneisses occur mainly in the eastern parts of the Tisza Megaunit, suggesting the existence of an ancient (possibly Variscan) subduction/accretionary complex.     

2007年8月大连地区一次暴雨过程特征分析

运用常规天气图资料,并根据地面自动站和多普勒雷达等资料,综合分析了2007年8月10－12日大连地区暴雨天气过程。结果表明：地面中尺度气旋的生成和发展是产生大暴雨的动力条件,低空急流的建立为暴雨产生提供了大量水汽,稳定的高压坝是暴雨落区在大连出现的必要前提。     

P-V-T equation of state of lawsonite

A pressure-volume-temperature data set has been obtained for lawsonite [CaAl₂Si₂O₇(OH)₂.H₂O], using synchrotron X-ray diffraction and an externally heated diamond anvil cell. Unit-cell volumes were measured to 9.4 GPa and 767 K by angle dispersive X-ray diffraction using imaging plates. Phase changes were not observed within this pressure-temperature range, and lawsonite compressed almost isotropically at constant temperature. The P-V-T data have been analyzed using a Birch- Murnaghan equation of state and a linear equation of state expressed as β=–1/V₀ (∂V/∂P) _T . At room temperature, the derived equation of state parameters are: K ₀=124.1 (18) GPa K'₀ set to 4) and β^–1=142.0(24) GPa, respectively. Our results are intermediate between previously reported measurements. The high-temperature data show that the incompressibility of lawsonite decreases with increasing temperature to ∼500 K and then increases above. Hence, the second order temperature derivative of the bulk modulus is taken into account in the equation of state; a fit of the volume data yields K ₀=123.9(18) GPa, (∂K/∂T)_P=–0.111(3) GPa K^–1, (∂² K/∂T ²)_P=0.28(6) 10^–3 GPa K^–2, α₀=3.1(2) 10^–5 K^–1, assuming K'₀=4. Received: 2 June 1998 / Revised, accepted: 12 Ocotber 1998     

X刀在CT下定位与高压注射器配合使用的技术研讨

目的：通过Ｘ刀在ＣＴ下的定位扫描来确定病灶,为Ｘ刀放疗治疗计划确定靶点,制定治疗计划提供准确的数据。方法：本文通过回顾性总结出了Ｘ刀在ＣＴ下的定位与高太注射器配合使用的方法,较详细地介绍了所用设备的主要参数指标以及参数的设定。结论：该方法定位显示病变清楚,提供数据准确。可以迅速完成治疗计划,并保证治疗的完整、精确、直观、高效和安全。     

承德北部高压基性麻粒岩的同位素年龄及其地质意义

最近在承德市北部地区发现了许多呈透镜状包体产于花岗片麻岩中的高压基性麻粒岩。运用全岩Ｓｍ －Ｎｄ、Ｒｂ－Ｓｒ、单颗粒锆石Ｕ－Ｐｂ 等多种同位素方法对这些高压麻粒岩进行了年代测定,得出了７个可供研究的年龄数据,即全岩Ｓｍ －Ｎｄ 等时线年龄２５５０±２１Ｍａ和３０６０±２．３Ｍａ,全岩Ｒｂ－Ｓｒ等时线年龄１５５０±３３Ｍａ 和１５６８Ｍａ,和单颗粒锆石Ｕ－Ｐｂ 同位素不一致线的上、下交点年龄分别为３４３２±５５６Ｍａ 和１８１７±１７Ｍａ, 颗粒锆石的谐和年龄１８３１±４ Ｍａ。在详细分析这些年代学数据可能的地质解释的基础上,认为该区的高压麻粒岩经历了复杂的地质演化过程,推测其原岩最早可能形成于新太古代早期至中太古代,并经受了太古宙末期花岗质岩浆侵入和变质作用改造。但其高压麻粒岩相变质很可能是古元古代末一次碰撞造山作用的产物, 最终进入上地壳可能在中元古代早期才完成, 与中元古代地壳的大规模拉张和燕辽裂陷槽的形成有关     

High-pressure phase transition and behavior of protons in brucite Mg(OH)2: a high-pressure–temperature study using IR synchrotron radiation

 Infrared absorption spectra of brucite Mg (OH)₂ were measured under high pressure and high temperature from 0.1 MPa 25 °C to 16 GPa 360 °C using infrared synchrotron radiation at BL43IR of Spring-8 and a high-temperature diamond-anvil cell. Brucite originally has an absorption peak at 3700 cm⁻¹, which is due to the OH dipole at ambient pressure. Over 3 GPa, brucite shows a pressure-induced absorption peak at 3650 cm⁻¹. The pressure-induced peak can be assigned to a new OH dipole under pressure. The new peak indicates that brucite has a new proton site under pressure and undergoes a high-pressure phase transition. From observations of the pressure-induced peak under various P–T condition, a stable region of the high-pressure phase was determined. The original peak shifts to lower wavenumber at −0.25 cm⁻¹ GPa⁻¹, while the pressure-induced peak shifts at −5.1 cm⁻¹ GPa⁻¹. These negative dependences of original and pressure-induced peak shifts against pressure result from enhanced hydrogen bond by shortened O–H···O distance, and the two dependences must result from the differences of hydrogen bond types of the original and pressure-induced peaks, most likely from trifurcated and bent types, respectively. Under high pressure and high temperature, the pressure-induced peak disappears, but a broad absorption band between 3300 and 3500 cm⁻¹ was observed. The broad absorption band may suggest free proton, and the possibility of proton conduction in brucite under high pressure and temperature. Received: 16 July 2001 / Accepted: 25 December 2001     

Tourmaline breakdown in a pelitic system: implications for boron cycling through subduction zones

Pressure–temperature conditions of tourmaline breakdown in a metapelite were determined by high-pressure experiments at 700–900°C and 4–6 GPa. These experiments produced an eclogite–facies assemblage of garnet, clinopyroxene, phengite, coesite, kyanite and rare rutile. The modal proportions of tourmaline clearly decreased between 4.5 and 5 GPa at 700°C, between 4 and 4.5 GPa at 800°C, and between 800 and 850°C at 4 GPa, with tourmaline that survived the higher temperature conditions appearing corroded and thus metastable. Decreases in the modal abundance of tourmaline are accompanied by decreasing modal abundance of coesite, and increasing that of clinopyroxene, garnet and kyanite; the boron content of phengite increases significantly. These changes suggest that, with increasing pressure and temperature, tourmaline reacts with coesite to produce clinopyroxene, garnet, kyanite, and boron-bearing phengite and fluid. Our results suggest that: (1) tourmaline breakdown occurs at lower pressures and temperatures in SiO₂-saturated systems than in SiO₂-undersaturated systems. (2) In even cold subduction zones, subducting sediments should release boron-rich fluids by tourmaline breakdown before reaching depths of 150 km, and (3) even after tourmaline breakdown, a significant amount of boron partitioned into phengite could be stored in deeply subducted sediments.     

东天山三条高压变质带地质特征和流体作用

微板块活动边缘常常产生高压变质作用,我们在东天山地区发现了三条高压变质带,分别出露在南天山北缘、中天山北缘和北天山南缘的早古生代至晚古生代地层中,它们是天山微板块多期次俯冲-碰撞-拼贴作用的产物。(南天山北缘铜花山高压变质带中有不同变异的蓝闪石类高压矿物,蓝闪石Ar~(40)/Ar~(39)同位素测定为360Ma年龄,而在同一带的西部的榆树沟有C型和B型的榴辉岩分布。中天山北缘乌斯特沟-米什沟高压变质带中发现了青铝闪石,同一阶段生成的多硅白云母为345Ma的年龄;北天山南缘后峡高压变质带中以出露在石炭世地层中钠闪石和多硅白云母为特征,三条高压变质带均经历过三个变质-变形作用阶段:①高压变质;②退变质;③韧性-脆性变质变形作用。) 流体活动与微板块构造作用密切相关,不同构造阶段有不同的变质-变形作用和矿物-流体反应:①高压变质作用阶段:微板块碰撞阶段产生不同的进变质作用,主要发生脱挥发组分的矿物反应,含水矿物转化成无水或少水矿物。南天山北缘有两次微板块与洋壳碰撞-俯冲作用,第一次碰撞-俯冲的热力学条件是:中-高温、高压和埋藏深度较大(540～720℃,0.92～1.29GPa,35～>50km),导致榴辉岩的生成,除了大量挥发组分逸出以外,另有不少熔体产生,变质矿物以捕获大量熔体和少量气-液流体包裹