He–Ar and Nd–Sr isotopic compositions of late Pleistocene felsic plutonic back arc basin rocks from Ulleungdo volcanic island, South Korea: Implications for the genesis of young plutonic rocks in a back arc basin

We report analyses of noble gases and Nd–Sr isotopes in mineral separates and whole rocks of late Pleistocene (< 0.2 Ma) monzonites from Ulleungdo, South Korea, a volcanic island within the back arc basin of the Japan island arc. A Rb–Sr mineral isochron age for the monzonites is 0.12 ± 0.01 Ma. K–Ar biotite ages from the same samples gave relatively concordant ages of 0.19 ± 0.01and 0.22 ± 0.01 Ma. ⁴⁰Ar/³⁹Ar yields a similar age of 0.29 ± 0.09 Ma. Geochemical characteristics of the felsic plutonic rocks, which are silica oversaturated alkali felsic rocks (av., 12.5 wt% in K₂O + Na₂O), are similar to those of 30 alkali volcanics from Ulleungdo in terms of concentrations of major, trace and REE elements. The initial Nd–Sr isotopic ratios of the monzonites (⁸⁷Sr/⁸⁶Sr = 0.70454–0.71264, ¹⁴³Nd/¹⁴⁴Nd = 0.512528–0.512577) are comparable with those of the alkali volcanics (⁸⁷Sr/⁸⁶Sr = 0.70466–0.70892, ¹⁴³Nd/¹⁴⁴Nd = 0.512521–0.512615) erupted in Stage 3 of Ulleungdo volcanism (0.24–0.47 Ma). The high initial ⁸⁷Sr/⁸⁶Sr values of the monzonites imply that seawater and crustally contaminated pre-existing trachytes may have been melted or assimilated during differentiation of the alkali basaltic magma.A mantle helium component (³He/⁴He ratio of up to 6.5 RA) associated with excess argon was found in the monzonites. Feldspar and biotite have preferentially lost helium during slow cooling at depth and/or during their transportation to the surface in a hot host magma. The source magma noble gas isotopic features are well preserved in fluid inclusions in hornblende, and indicate that the magma may be directly derived from subcontinental lithospheric mantle metasomatized by an ancient subduction process, or may have formed as a mixture of MORB-like mantle and crustal components. The radiometric ages, geochemical and Nd–Sr isotopic signatures of the Ulleungdo monzonites as well as the presence of mantle-derived helium and argon, suggests that these felsic plutonic rocks evolved from alkali basaltic magma that formed by partial melting of subcontinental lithospheric mantle beneath the back arc basin located along the active continental margin of the southeastern part of the Eurasian plate.     

碳酸盐岩裂缝与岩溶作用研究

从构造与非构造作用角度出发,突出研究断层对裂缝的控制作用、断裂与岩溶的关系和裂缝与岩溶之间的关系,揭示碳酸盐岩裂缝与岩溶的发育规律。研究表明：构造裂缝为岩溶发育提供岩溶作用进行的有利通道,非构造裂缝则可以加速溶蚀作用的进行,促进岩溶的发育;裂缝与岩溶之间的关系始终是相辅相成、相互促进的关系。     

中国大别山东南缘首次发现大坝陨坑构造

简介首次在大别山东南缘安徽省境内发现的大坝陨坑构造。经初步评价,知陨坑呈椭圆形,长轴呈北北东向,长约19km,短轴长约12km,最大坑深约2km,是一个有中央隆起区的复杂型陨坑。在卫片上陨坑显示环形影像,地貌形态为一洼地。陨坑基座保存尚好,可对它直观和追索陨坑构造边界。形成于230Ma左右的各类撞击变质岩石系列齐全,其中含有柯石英等典型的撞击变质矿物及撞击碎理等超微构造,特别是在陨坑基座内壁普遍发现有鉴别陨坑构造最可靠的标志——干裂自角砾岩,都证明大坝环形影像是一个典型的陨星撞击坑构造。它的发现,具有很大的科学及经济意义,对今后褶皱山区寻找和研究陨坑构造具有示范和指导作用,同时大大丰富了建设大别山世界地质公园的地质依据。无庸置疑此发现将促进大别山旅游业的发展及陨星撞击科普知识的传播。     

浙江杭州地区中下奥陶统岩石地层研究

笔者以城市基岩地质填图和剖面研究资料为基础,选择临安市板桥乡南山上中下奥陶统剖面为候选层型,根据剖面的地层层序、岩性组合、分界标志,结合区域变质的总体特征,重新厘定、划分了4个组级岩石地层单位,并依据荆山岭与板桥剖面的地层、生物化石对比,确定其地层时代为早中奥陶世。这对重建杭州地区层型剖面与地质遗迹保护、岩石地层填图、奥陶纪石灰岩矿产资源的开发利用都具有重要意义。     

北大别白垩纪镁铁－超镁铁岩的铂族元素地球化学研究

采用镍锍火试金法结合ICP-MS分析了12个北大别白垩纪镁铁-超镁铁岩样品的Ir,Ru,Rh,Pt和Pd的含量,结果显示铂族元素（PGE）的含量较低,原始地幔标准化后的PGE分布模式呈正斜率型,PPGE相对原始地幔略微亏损,而IPGE强烈亏损,Pd/Ir值远高于相应的地幔比值。这些镁铁-超镁铁岩中PGE的强烈分异是地幔低程度的部分熔融过程中,PPGE主要受硫化物控制,而Ir则存在于非硫化物相如尖晶石,可能还有合金之中造成的。同时,铂族元素的分布特征表明这些镁铁-超镁铁岩是岩浆结晶分异的产物。     

胶南构造混杂岩带中糜棱岩的显微形变特征与古构造环境——来自榴辉岩围岩的构造信息

以胶南构造混杂岩带中榴辉岩的围岩——套程度不同的糜棱岩化岩石为研究对象,重点研究了其显微形变的结构特征及环境意义、石英组构特征及动力学信息,并讨论其形成的古构造环境和构造机制。     

Facies recognition of some Tertiary coals applied to prediction of oil source rock occurrence

Coals are oil source rocks in many of the Tertiary basins of Southeast Asia. The precursors of these hydrogen rich and oxygen poor coals are coastal plain peats which have mainly developed in an everwet and tropical climate. In these environments water flow and reworking can concentrate liptinitic kerogen in preference to vitrinitic kerogen. The distribution, petrography and chemistry of the coaly Miocene source rocks present in the Kutai Basin are described. The recognition of environmental controls on the accumulation of potentially oil-prone coals and coaly shales in deltaic environments is an aid to predictive source bed recognition in petroleum exploration. Comments on the environment of deposition of coaly sediments in the basins of the Norwegian Sea are discussed with reference to their possible oil and/or gas sourcing potential. The Triassic - Jurassic coals of the Haltenbanken area may become more oil-prone towards the delta margins, and facies mapping could aid oil exploration in this area.     

Evaluation of distributed recharge in an upland semi-arid karst system: the West Bank Mountain Aquifer,Middle East

Assessment of recharge in a structurally complex upland karst limestone aquifer situated in a semi-arid environment is difficult. Resort to surrogate indicators such as measurement of spring outflow and borehole discharge, is a common alternative, and attempts to apply conventional soil moisture deficit analysis may not adequately account for the intermittent spate conditions that arise in such environments. A modelling approach has been made using the West Bank Mountain Aquifer system in the Middle East as a trial. The model uses object oriented software which allows various objects to be switched on and off. Each of the main recharge processes identified in the West Bank is incorporated. The model allows either conventional soil moisture deficit analysis calculations or wetting threshold calculations to be made as appropriate, and accommodates both direct recharge and secondary recharge. Daily time steps enable recharge and runoff routing to be calculated for each node. Model runs have enabled a series of simulations for each of the three aquifer basins in the West Bank and for the whole of the West Bank. These provide recharge estimates comparable to those prepared by earlier workers by conventional means. The model is adaptable and has been successfully used in other environments.     

In situ estimation of the effective chemical diffusion coefficient of a rock matrix in a fractured aquifer

An in situ method of estimating the effective diffusion coefficient for a chemical constituent that diffuses into the primary porosity of a rock is developed by abruptly changing the concentration of the dissolved constituent in a borehole in contact with the rock matrix and monitoring the time-varying concentration. The experiment was conducted in a borehole completed in mudstone on the campus of the University of the Free State in Bloemfontein, South Africa. Numerous tracer tests were conducted at this site, which left a residual concentration of sodium chloride in boreholes that diffused into the rock matrix over a period of years. Fresh water was introduced into a borehole in contact with the mudstone, and the time-varying increase of chloride was observed by monitoring the electrical conductivity (EC) at various depths in the borehole. Estimates of the effective diffusion coefficient were obtained by interpreting measurements of EC over 34 d. The effective diffusion coefficient at a depth of 36 m was approximately 7.8×10^?6 m²/d, but was sensitive to the assumed matrix porosity. The formation factor and mass flux for the mudstone were also estimated from the experiment.     

Estimation of hydraulic permeability considering the micro morphology of rocks of the borehole YAXCOPOIL-1 (Impact crater Chicxulub,Mexico)

Internal surface, formation factor, Nuclear Magnetic Resonance (NMR)-T2 relaxation times and pore radius distributions were measured on representative core samples for the estimation of hydraulic permeability. Permeability is estimated using various versions of the classic Kozeny–Carman-equation (K–C) and a further development of K–C, the fractal PaRiS-model, taking into account the internal surface. In addition to grain and pore size distribution, directly connected to permeability, internal surface reflects the internal structure (“micro morphology”). Lithologies could be grouped with respect to differences in internal surface. Most melt rich impact breccia lithologies exhibit large internal surfaces, while Tertiary post-impact sediments and Cretaceous lithologies in displaced megablocks display smaller internal surfaces. Investigations with scanning electron microscopy confirm the correlation between internal surface and micro morphology. In addition to different versions of K–C, estimations by means of NMR, pore radius distributions and some gas permeability measurements serve for cross-checking and calibration. In general, the different estimations from the independent methods and the measurements are in satisfactory accordance. For Tertiary limestones and Suevites bulk with very high porosities (up to 35%) permeabilites between 10⁻¹⁴ and 10⁻¹⁶ m² are found, whereas in lower Suevite, Cretaceous anhydrites and dolomites, bulk permeabilites are between 10⁻¹⁵ and 10⁻²³ m².