The heat capacity of cerium orthophosphate CePO<Subscript>4</Subscript>, the synthetic analogue of monazite

The heat capacity of CePO₄ monazite-type structure was measured by the hybrid adiabatic relaxation method in the temperature range 0.5 to 320 K and by differential scanning calorimetry from 400 to 1370 K. A thermal anomaly was observed below T 4.5 K. A semi-empirical method has been used to describe the total specific heat as the sum of a lattice and an excess component. From the heat-capacity measurements, the thermodynamic functions of CePO₄ were determined at the standard temperature of 298.15 K.     

Equation of state of iron–silicon alloys to megabar pressure

The stability and pressure–volume equation of state of iron–silicon alloys, Fe-8.7 wt% Si and Fe-17.8 wt% Si, have been investigated using diamond-anvil cell techniques up to 196 and 124 GPa, respectively. Angular–dispersive X-ray diffractions of iron–silicon alloys were measured at room temperature using monochromatic synchrotron radiation and an imaging plate (IP). A bcc–Fe-8.7 wt% Si transformed to hcp structure at around 1636 GPa. The high-pressure phase of Fe-8.7 wt% Si with hexagonal close-packed (hcp) structure was found to be stable up to 196 GPa and no phase transition of bcc–Fe-17.8 wt% Si was observed up to 124 GPa. The pressure–volume data were fitted to a third-order Birch–Murnaghan equation of state (BM EOS) with zero–pressure parameters: V₀=22.2(8) ų, K₀=198(9) GPa, and K₀=4.7(3) for hcp–Fe-8.7 wt% Si and V₀=179.41(45) ų, K₀=207(15) GPa and K₀=5.1(6) for Fe-17.8 wt% Si. The density and bulk sound velocity of hcp–Fe-8.7 wt% Si indicate that the inner core could contain 3–5 wt% Si.     

Lead contamination of soil along road and its remediation

With a rapid development of road systems and an associated drastic increase in number of automobiles, the traffic has induced more and more obvious environmental pollution such as noise, dust, emission and heavy metal contamination. Lead, as one of the most harmful heavy metal contaminants, can execute a significant impact on soil quality and plant growth, depending on its form, as well as its transport and accumulation in soil. This paper describes the source and characteristics of Pb contaminant in soil along a road, and reviews the results of research on remediation of Pb-contaminated soils, aiming at identifying promising approaches to soil remediation along roads.     

Timing of post-collisional H-type to A-type granitic magmatism: U–Pb titanite ages from the Alpine central Anatolian granitoids (Turkey)

The last stages of the continental collision during the closure of the Neotethyan ocean in central Anatolia are characterized by post-collisional H- and A-type granitoids intruding both the metamorphic country rocks and allochthonous ophiolitic rocks of the central Anatolian crystalline complex. Available Rb–Sr and K–Ar whole-rock and mineral age data on the H- and A-type granitoids in central Anatolia are inconsistent. To better constrain the geological relevance and the timing of the change in the chemical character of magmatism in the wake of the Alpine orogeny in Anatolia, we re-evaluated the geochemical characteristics and dated titanite from representative H- (Baranadag quartz-monzonite: BR) and A-type (Çamsari quartz-syenite: CS) granitoids by the U–Pb method. BR is a high-K calc-alkaline intrusion with mafic microgranular enclaves and shows enrichment of LILE relative to HFSE. The alkaline CS displays higher SiO₂, Na₂O+K₂O, Fe/Mg, Rb, Th and HFSE with corresponding depletion in CaO, MgO, Fe₂O₃^tot, P₂O₅, Ba, Sr, and Ti. Chondrite-normalized REE patterns of the BR and CS samples have LREE-enriched and flat HREE patterns, whereas CS differs from BR by higher LREE enrichment and lower MREE and HREE contents. Mineralogical and geochemical characteristics suggest that BR and CS were not products of the same magma source. BR was derived from a subduction-modified depleted hybrid-source and CS had an enriched mantle source with significant crustal contribution. The U–Pb titanite ages of the H-type central Anatolian granitoids (BR) and the A-type granitoids (CS) are 74.0±2.8 and 74.1±0.7 Ma, respectively. The coeval evolution of post-collisional/calc-alkaline H- to A-type magmatism was possibly associated with source heterogeneity and variable involvement of continental materials during the evolution of these granitoids. These new age data constrain the timing of the onset of a post-collision extensional period following the Alpine thickening within the passive margin of the Tauride–Anatolide platform, which occurred before the opening of the latest Cretaceous central Anatolian basins.An erratum to this article can be found at     

Static compression of α-Fe<Subscript>2</Subscript>O<Subscript>3</Subscript>: linear incompressibility of lattice parameters and high-pressure transformations

The high-pressure behavior of -Fe₂O₃ has been studied under static compression up to 60 GPa, using a laser-heated diamond anvil cell. Synchrotron-based angular-dispersive X-ray diffraction shows that the sample remains in the corundum structure up to 50 GPa, but with the appearance of coexisting diffraction lines from a high-pressure phase at pressures above 45 GPa. A least-squares fit of low-pressure phase data to an Eulerian finite-strain equation of state yields linear incompressibilities of K _{a 0}=749.5 (± 18.4) GPa and K _{c 0}= 455.7 (± 21.4) GPa, differing by a factor of 1.6 along the two directions. The enhanced compressibility of the c axis may lead to breaking of vertex- or edge-sharing bonds between octahedra, inducing the high-pressure phase transformation at 50 GPa. Analysis of linear compressibilities suggests that the high-pressure phase above 50 GPa is of the Rh₂O₃ (II) structure. Continuous laser heating reveals a new structural phase transformation of -Fe₂O₃ at 22 GPa, to an orthorhombic structure with a=7.305(3) Å, b=7.850(3) Å, and c=12.877(14) Å, different from the Rh₂O₃ (II) structure.     

Packet Structure of Surface Eddies in the Atmospheric Boundary Layer

A smoke visualization experiment has beenperformed in the first 3,m ofneutral and unstable atmospheric boundary layersat very large Reynolds number(Re > 10⁶). Under neutral atmosphericconditions mean wind profiles agreewell with those in the canonical flatplate zero-pressure-gradient turbulentboundary layer. The experiment was designedto minimize the temperaturedifference between the passive marker (smoke)and the air to ensure that anyobserved structures were due to vortical, ratherthan buoyant, motions. Imagesacquired in the streamwise–wall-normal planeusing a planar laser light-sheetare strikingly similar to those observed inlaboratory experiments at low to moderate Reynolds numbers. They reveal large-scaleramp-like structures withdownstream inclination of 3°–35°.This inclination isinterpreted as the hairpin packet growthangle following the hairpin vortexpacket model ofAdrian, Meinhart, and Tomkins.The distribution of this characteristicangle agrees with the results of experiments at far lower Reynolds numbers,suggesting a similarity in structures among low, moderate, and high Reynoldsnumber boundary layers at vastly different scales. These results indicate thatthe hairpin vortex packet model extends over a large range of scales. Theeffect of vertical heat transport in an unstable atmosphere on wall structuresis investigated in terms of the hairpin vortex packet model.     

Le Toarcien inférieur du Haut Atlas de Todrha–Dadès (Maroc) : sédimentologie et lithostratigraphie

The survey of sedimentological and lithostratigraphic Liassic facies of the Todrha–Dades area (southwestern part of the central High Atlas) permits to establish new data on the Tagoudite formation. Its environment deposit and its micropalaeontological content are evidenced in relation with the geodynamic evolution of the High Atlas Basin during the Early Toarcian. To cite this article: M. Ettaki, E.H. Chellaï, C. R. Geoscience 337 (2005).     

高压输电线对GPS静态测量的影响

对高压线下GPS测量数据进行对比分析，得到高压输电线对GPS测量成果影响的定性结论：对于高压线下精度不高的定位测量，GPS定位技术是可以胜任的。     

Electron microprobe dating of monazite substantiates ages of major geological events in the southern Brazilian shield

To obtain the chemical Th^*–Pb isochron ages and surface maps of monazite crystals in igneous and metamorphic rocks from the southern Brazilian Shield, we employ Th–U-total Pb dating by an electron probe microanalyzer. The ages of two Trans-Amazonian metamorphic events are given by a felsic, garnet-bearing granulite from the Santa Maria Chico granulitic complex. The age of the first event, at approximately 2.35 Ga, was obtained by surface mapping in a grain included in garnet. The dating of the second event, 1899±43 Ma, is in agreement with previous data obtained in zircon crystals with sensitive high-resolution ion microprobe. Other determinations belong to the Brasiliano cycle. In the São Gabriel block, an age of 643±129 Ma was obtained on monazite from a staurolite-garnet schist of the Cambaizinho Formation, whereas a staurolite-bearing schist from the Passo Feio complex yielded a 510±68 Ma age. Several units in the Dom Feliciano belt were dated, including the biotite-sillimanite gneisses of the Várzea do Capivarita complex (552±90 Ma), the sillimanite-garnet gneisses of Camboriú complex (565±77 Ma), the Três Figueiras granite (558±57 Ma), and the Plaza Itapema granite (545±55 Ma). The ages presented in this study, obtained through monazite chemical dating, are confirmed through comparison with previous data regarding zircon crystals from the same geological units.     

高纯氢氧化镁及其水热处理技术评述

比较分析了高纯氢氧化镁制备的方法,水热改性对其组织结构的影响及产品的应用及市场前景。