Implications of Analcime Hydrothermally Formed from Na-alumino-borosilicate Glasses Containing Cs and Sr for the Stability of High-level Radioactive Waste Form

Abstract. In order to know the behaviors of radioactive elements such as cesium and strontium during a hydrothermal alteration of borosilicate glass of radioactive waste, some alumino-borosilicate glasses belonging to the systems Na₂O-Al₂O₃-B₂O₃-SiO₂-SrO, Na₂O-Al₂O₃-B₂O₃-SiO₂-Cs₂O and Na₂O-Al₂-O₃-B₂O₃-SiO₂-SrO-Cs₂O have been treated hydrothermally at 200C under a vapor pressure of 1.54 MPa. The result shows that all glasses are changed into crystalline phases with running time up to 60 days, and that analcime-type zeolite is formed as a major product. The formed zeolite is shown to contain cesium and/or strontium. Considering the fact that natural zeolite occurs in wide physicochemical conditions including hydrothermal one, the analcime-type zeolite is expected to fix stably the radioactive elements in the disposal site. Since aluminum is necessary for the formation of the analcime-type zeolite, the waste glass should have aluminum as one of major components.     

Neoproterozoic accretionary and collisional events on the western margin of the Siberian craton: new geological and geochronological evidence from the Yenisey Ridge

The geological, structural and tectonic evolutions of the Yenisey Ridge fold-and-thrust belt are discussed in the context of the western margin of the Siberian craton during the Neoproterozoic. Previous work in the Yenisey Ridge had led to the interpretation that the fold belt is composed of high-grade metamorphic and igneous rocks comprising an Archean and Paleoproterozoic basement with an unconformably overlying Mesoproterozoic–Neoproterozoic cover, which was mainly metamorphosed under greenschist-facies conditions. Based on the existing data and new geological and zircon U–Pb data, we recognize several terranes of different age and composition that were assembled during Neoproterozoic collisional–accretional processes on the western margin of the Siberian craton. We suggest that there were three main Neoproterozoic tectonic events involved in the formation of the Yenisey Ridge fold-and-thrust belt at 880–860 Ma, 760–720 Ma and 700–630 Ma. On the basis of new geochronological and petrological data, we propose that the Yeruda and Teya granites (880–860 Ma) were formed as a result of the first event, which could have occurred in the Central Angara terrane before it collided with Siberia. We also propose that the Cherimba, Ayakhta, Garevka and Glushikha granites (760–720 Ma) were formed as a result of this collision. The third event (700–630 Ma) is fixed by the age of island-arc and ophiolite complexes and their obduction onto the Siberian craton margin. We conclude by discussing correlation of these complexes with those in other belts on the margin of the Siberian craton.     

Eastern Laurentia in Rodinia: constraints from whole-rock Pb and U/Pb geochronology

Whole-rock Pb isotopic signatures and U/Pb geochronology refute a Rodinian correlation of northeastern Laurentia and proto-Andean Amazonia. According to this previously proposed model, the Labrador–Scotland–Greenland Promontory (LSGP) of northeastern Laurentia collided with the proto-Andean margin of Amazonia, at the Arica Embayment, during the Grenville/Sunsás Orogeny (ca. 1.0 Ga). Links between the two margins were based upon the correlation of the LSGP with Arequipa-Antofalla Basement (AAB), a Proterozoic block along the proto-Andean margin of Amazonia adjacent to the Arica Embayment. Specifically, similarities in 1.8–1.0 Ga basement rocks in both regions suggested that the AAB was originally a piece of the LSGP. Furthermore, similarities in unique, post-collisional, but pre-rift, glacial sedimentary sequences also supported a link between the AAB and LSGP.Tests of these apparent similarities fail to support correlation of the AAB and the LSGP and, thus, eliminate a direct link between northeastern Laurentia and southwestern Amazonia in Rodinia. However, Pb isotopic compositions and U/Pb geochronology provide the basis for two new correlations, namely, (1) the ca. 1.3–1.0 Ga basement in the central and southern Appalachians may be an allochthonous block that was transferred to Laurentia from Amazonia at ca. 1.0 Ga, and (2) an allochthonous AAB may be a piece of the Kalahari Craton that was transferred to Amazonia at ca. 1.0 Ga. Based on these new correlations and a previously proposed Grenvillian connection between southern Laurentia (Llano) and Kalahari, we propose that Amazonia may have collided with a contiguous southeastern Laurentia/Kalahari margin at ca. 1.0 Ga.     

江西2003年夏季罕见高温气候特征及成因分析

对江西省2003年夏季罕见高温干旱的强度、气候历史地位、500hPa环流形势特征和海温特征等进行了分析。结果表明,2003年夏季高温强度在多项指标上均排建国以来第一位;在500hPa环流形势上具有特殊的分布特征;在前期环流形势场和海温场上具有一些前兆特征,有较好的预报意义。     

中国夏季降水异常空间模与副热带高压的关系

本文用1959～1994年6、7、8月全国范围47个5°×5°经纬度网格降水资料分析了夏季降水异常空间模的月际差异，并在此基础上用西太平洋副高指数及青藏高原指数#FKB#FS分析降水异常空间模与环流的关系，为检验环流指数与降水相关场的整体信度，还对8月份降水资料进行了Monte-Carlo检验。结果表明，夏季总降水异常的空间模在每一月份中并非表现得同样清楚，江淮流域与河套及华南的反相关在8月份表现得最清楚。而青藏高原中东部南北两侧的负相关在6月及8月很清楚，7月份次之。8月份西太平洋副高北界异常对江淮流域与河套及华南地区降水异常反相关的产生有很大作用。副高稳定偏北时，河套、华南易涝，江淮易旱。反之亦然。青藏高原指数#FKB#FS与逐月降水的相关分析表明，青藏高原上高压及低涡活动对高原中东部南北两侧负相关的产生有一定作用。当高压活动偏多时，北侧易旱、南侧易涝。并且6月及8月的作用较大，7月较小。另外，8月份副高活动对这一降水异常空间模的产生也有一定影响。     

胶东招掖郭家岭型花岗岩锆石年代学及其Pb同位素特征

采用SHRIMP测年技术，精确地测定了郭家岭型花岗岩年龄为130-126Ma，主要金矿化在126-120Ma之间，郭家岭型花岗岩与金矿化关系最密切。岩体Pb同位素组成反映了本区所处构造背景。     

Pb同位素三维空间拓扑投影与化探评价

通过对数据集合的拓扑学分析，获得了Pb同位素三维空间拓扑投影特征值V1和V2。运用特征值可以定量地预测隐伏铜金矿床的埋藏深度和隐伏矿量，是隐伏矿预测评价的新方法，开创了同位素化探的新领域。     

现代沉积的210Pb计年

²¹⁰Pb具有百年时间尺度沉积计年的重要价值。²¹⁰Pb_ex计年假设：沉积物是封闭系统；进入水体的²¹⁰Pb能有效地转移到沉积物中并不发生沉积后迁移；非过剩²¹⁰Pb与其母体²²⁶Ra保持平衡。²¹⁰Pb_ex计年可用稳定输入通量-稳定沉积物堆积速率模式、常量初始浓度模式或恒定补给速率模式。沉积物柱芯必须保持原态并以0．5～1cm间隔分截；用相应层节²²⁶Ra校正。沉积物表层混合作用及²²²Rn的丢失可能导致顶部²¹⁰Pb_ex异常。季节性缺氧湖泊沉积物顶部可能存在²¹⁰Pb及²¹⁰Po的再迁移。²¹⁰Pb与¹³⁷Cs两种计年方法原理上具有根本差别。²¹⁰Pb，¹³⁷Cs与沉积纹理方法对比是准确计年的重要保证。     

西藏聂拉木高喜马拉雅结晶岩系的伸展变形

西藏聂拉木高喜马拉雅结晶岩系在区域上以单一的叶理和单一的拉伸线理占主要地位，其变形带的组构主要反映了透入性的伸展变形；根据显微构造分析表明早期由北往南推覆，晚期由南向北伸展，且晚期表现非常明显。     

扬子地块西缘灯影组层控铅锌矿床成因的地球化学论证

扬子地块西缘灯影组层控铅锌矿床成因的地球化学论证邵世才（有色总公司北京矿产地质研究所，北京１０００１２）李朝阳（中国科学院地球化学研究所，贵阳５５０００２）关键词层控铅锌矿床地球化学矿床成因扬子地块西缘１矿床地质特征扬子地块西缘灯影组铅锌矿床呈南北向...