Synchrotron IR study of hydrous ringwoodite (γ-Mg2SiO4) up to 30 GPa

High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm⁻¹ at ambient temperature for hydrous Mg-ringwoodite (γ-Mg₂SiO₄) up to 30 GPa. The main feature in the OH⁻ stretching region is an extremely broad band centred at 3,150 cm⁻¹. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm⁻¹ and an absorption plateau persist with a maximum wavenumber of 3,800 cm⁻¹. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition.     

Analysis and classification of hyperspectral data for mapping land degradation: An application in southern Spain

Desertification is a severe stage of land degradation, manifested by “desert-like” conditions in dryland areas. Climatic conditions together with geomorphologic processes help to mould desert-like soil surface features in arid zones. The identification of these soil features serves as a useful input for understanding the desertification process and land degradation as a whole. In the present study, imaging spectrometer data were used to detect and map desert-like surface features. Absorption feature parameters in the spectral region between 0.4 and 2.5 μm wavelengths were analysed and correlated with soil properties, such as soil colour, soil salinity, gypsum content, etc. Soil groupings were made based on their similarities and their spectral reflectance curves were studied. Distinct differences in the reflectance curves throughout the spectrum were exhibited between groups. Although the samples belonging to the same group shared common properties, the curves still showed differences within the same group.Characteristic reflectance curves of soil surface features were derived from spectral measurements both in the field and in the laboratory, and mean reflectance values derived from image pixels representing known features. Linear unmixing and spectral angle matching techniques were applied to assess their suitability in mapping surface features for land degradation studies. The study showed that linear unmixing provided more realistic results for mapping “desert-like” surface features than the spectral angle matching technique.     

影响华东地区热带气旋年频数与热带对流场的关系

利用由美国NOAA系列卫星观测的OLR资料研究了影响华东地区热带气旋年频数（记为ATC）与热带对流场的关系，结果表明两者存在密切的联系：（1）当华东地区热带气旋年频数ATC为异常偏多（少）时，ITCZ位置累积距平为正（负）值，即ITCZ位置异常偏北（南）；（2）利用OLR设计了Walker综合指数WI，该指数的强弱可以反映ATC的异常情况，即当ATC为异常偏多（少）时，walker环流圈异常强（弱）；（3）OLR距平累积量场能较好的表征ATC异常年份所对应的低纬度及中高纬地区大气环流的配置，其可以作为预测影响华东地区热带气旋年频数的强信号。     

Electrical aerosol spectrometer of Tartu University

The electrical aerosol spectrometer (EAS) of the parallel measuring principle at Tartu University is an efficient instrument for rapid measurement of the unstable size spectrum of aerosol particles. The measuring range from 10 nm to 10 μm is achieved by simultaneously using a pair of differential mobility analyzers with two different particle chargers. The particle spectrum is calculated and measurement errors are estimated in real time by using a least-squares method. Experimental calibration ensures reliability of measurement. The instrument is well suited for continuous monitoring of atmospheric aerosol.     

Spectroscopic evidence for pressure-induced phase transitions in diopside

 Raman spectra of diopside were collected from atmospheric pressure to 71 GPa. The pressure dependences of 22 modes were determined. Changes occurred in the spectra at three different pressures. First, at approximately 10 GPa, the two Raman modes at 356 and 875 cm⁻¹ disappeared, while the mode at 324 cm⁻¹ split into two modes, diverging at this pressure with significantly different pressure shifts; second, at approximately 15 GPa, a small (1 to 2 cm⁻¹) drop in several of the frequencies was observed accompanied by changes in the pressure dependency of some of the modes; and third, above 55 GPa, the modes characteristic of chains of tetrahedrally coordinated silicon disappeared, while those for octahedrally coordinated silicon appeared. The first change at 10 GPa appears to be a C2/c to C2/c transition involving a change in the Ca coordination. The third change above 55 GPa appears to be a change in the silicon coordination. At 15 GPa, it is suggested that a change in compressional mechanism takes place. Received: 14 November 2000 / Accepted: 9 January 2002     

城市震害高危害小区的研究和GIS的实现技术

论述了在城市地震灾害中如何考虑诸方面因素来评价城市的灾害轻重分布情况。中建立坑危害小区分析模型，设想将城市划分等面积网格，给每个单元网格赋予灾害指数，以确定城市中受灾较为严重的区域，为求灾指挥提供决策信息。同时，将高危害小区的模型研究结果转化为计算机技术可以实现的GIS模型。该研究结果已应用于泰安市防震减灾示范研究项目中。     

饱和岩石的各向异性及非线性黏弹性响应

在MTS伺服压机上对不同饱和状态的砂岩、大理岩标本进行了垂直层理和平行层理两个方向的正弦波加载试验,研究了饱和岩石的各向异性及非线性黏弹性行为. 在最大载荷低于岩石的屈服点时,获得的衰减、杨氏模量、泊松比、波速都表现出显著的各向异性,同时它们还具有较明显的应变振幅效应和频率效应. 随着应变振幅的增大,衰减近似呈线性增长,杨氏模量和泊松比近似呈线性下降. 在0.005-4Hz频段内除衰减不明显依赖频率以外,杨氏模量、泊松比、波速对频率的依赖性都较强; 当频段扩大到15Hz时,这4个参数都表现出较强的频率效应. 饱和岩石的衰减、杨氏模量、泊松比、波速均随饱和液体的黏滞系数增大而增大.     

关于绝对重力仪的发展和我们的思考

介绍了近年来出现的新型绝对重力仪，认为该仪器是控制地球重力场信息的重要工具，特别对FG5型的如何改进及我国绝对重力仪的如何发展，提出了建议。     

Tracking recent recovery from eutrophication in a high arctic lake (Meretta Lake, Cornwallis Island, Nunavut, Canada) using fossil diatom assemblages

Meretta Lake (Resolute Bay, Cornwallis Island, Nunavut, Canada) is a high arctic lake that received raw sewage for almost 50 years from the Canadian Department of Transport Base. The lake was sampled from 1968–72 during the International Biological Programme, as part of the Char Lake Project. As the number of users at the Transport Base declined throughout the 1990s, so too did the lake's nutrient levels, and Meretta Lake is now classified as oligotrophic. A previous diatom-based paleolimnological study revealed marked species assemblage shifts coincident with sewage inputs beginning in the late 1940s; however, because the core was taken at a time when nutrient levels were still relatively high (i.e., 1993), the diatom record did not yet track any signs of recovery. In this present study, we examined fossil diatom assemblages from a sediment core taken in 2001. Our results indicate a shift to the pre-impact diatom assemblages in the most recent sediments, indicating that the paleolimnological record is tracking the decreased nutrient inputs to this high arctic lake, and confirms that no significant lags exist in these largely ice-covered lakes.     

Les dykes basiques du massif ancien de l'Ourika (Atlas de Marrakech,Maroc) : géochimie et significationThe basic dykes of the Ourika old massif (High Atlas of Marrakech): Geochemistry and significance

The Precambrian massif of Ourika is crosscut by two systems of basic dykes, striking N40°E and N90–120°E. Using incompatible trace elements, the two systems form two distinct chemical groups, displaying a continental tholeiitic affinity. The composition variations between the two defined groups can be due to heterogeneities of mantle sources and to contamination, during the magma ascent, by the continental crust. The emplacement of these basic dykes, before the late-PIII formations, can be related to the Neoproterozoic distension generalised to the Anti-Atlas chain. To cite this article: A. Barakat et al., C. R. Geoscience 334 (2002) 827–833.