浙中后山店花岗斑岩体的LA-ICP-MS锆石U-Pb定年、锆石Hf同位素及其地质意义

针对浙中地区后山店花岗斑岩体进行高精度LA-ICP-MS锆石U-Pb测年和锆石Lu-Hf同位素的测定。测年结果显示其加权平均年龄值为148.5 Ma±1.2 Ma(MSWD=1.4),说明浙中地区有晚侏罗世侵入岩的存在,属于燕山早期晚阶段岩浆活动的产物,其成岩时代可能代表了古太平洋构造域下的板内岩浆活动和陆缘弧间的过渡阶段。锆石的εHf(t)值为-10.3~-3.5,均为负值,二阶段模式年龄tHf2(Ma)变化范围主要集中于1 400 Ma~1 829 Ma之间,反映其物质来源可能为中元古代下地壳基底物质,并在成岩过程中有幔源组分的参与。     

Formation and Evolution of Early Precambrian Continental Crust in Alxa Block

By the analysis of the published zircon U-Pb ages and Hf isotope data, this paper firstly presents a comprehensive review about the staggered growth and reworking of early Precambrian continental crust in Alxa Block. The results show that the ancient crustal remnants of Alxa Block was formed in Meso-Paleo Archean, which was recorded by 3.0~3.6 Ga detrital zircons and Hf model ages. The early crustal growth of Alxa Block could be traced back to early Paleo-archean. Currently, the oldest zircon U-Pb age is about 3.6 Ga. Analogous to the other places of North China Craton, the Alxa Block underwent two-stage crustal growth at 2.7~2.9 Ga and 2.5~2.6 Ga respectively, and the former might be wider. The ~2.5 Ga (TTG) tectono-magmatic event, which represents the North China continent’s cratonization, also existed in Alxa Block. The corresponding zircon Hf isotope data indicate that the TTGs were mainly derived by melting of 2.7~2.9 Ga juvenile crust, possibly by mixing with a certain ancient crust, and a small portion was produced by instant reworking of 2.5~2.6 Ga juvenile crust. Proceeding to Paleo-proterozoic, the Alxa Block underwent multi-stage tectono-magmatic events, approximately peaked at 2.30~2.35 Ga, 2.15~2.17 Ga, 2.00~2.10 Ga, 1.95~1.98 Ga and ~1.90 Ga. The continental crust was mainly formed by reworking of 2.7~2.9 Ga and 2.5~2.6 Ga juvenile crust, simultaneously by a fraction of ~2.1 Ga juvenile crust. In Paleo-proterozoic, not only the Archean crustal reworking but also the juvenile crustal growth existed in Alxa Block.     

越南西北部Phan Si Pan地区Ngoi Chi岩组的锆石U-Pb年龄和Hf同位素组成

本文对越南西北部Phan Si Pan地区变质地体中的一个Ngoi Chi片麻岩进行了锆石CL内部结构分析、LA-(MC)-ICP-MS锆石U-Pb定年和Hf同位素分析。CL图象和Th/U比值特征显示该片麻岩样品中的锆石主要为岩浆锆石,有少量窄的变质边。岩浆锆石的年龄为~2.9 Ga,表明该样品是越南西北部Phan Si Pan地区的基底岩石。它们的εHf(t)值为–4.70±0.92,二阶段Hf模式年龄为~3.5 Ga,表明其为更古老的(3.5 Ga)冥太古代地壳物质部分熔融作用形成。变质边部锆石给出了~1.8 Ga的年龄,表明变质作用发生在古元古代早期,Phan Si Pan地区在这一时期可能经历了一次重要的构造热事件。     

华北地块南缘花山、五丈山岩体LA-ICP-MS锆石U-Pb年龄、地球化学特征及成因

花山复式岩体位于华北地块南缘,采用LA-ICP-MS技术测得复式岩体中的中细粒似斑状黑云二长花岗岩的锆石U-Pb年龄为128±1Ma,此年龄被解释为成岩年龄。该岩体及邻近的五丈山岩体中花岗岩具有高硅、富碱特征,为准铝-弱过铝质高钾钙碱性系列;在稀土和微量元素上,富集LREE、Rb、Ba、K、Sr等大离子亲石元素,亏损HREE、Zr、Hf、Ta、Nb、P、Ti等高场强元素,总体上Eu异常不明显,显示出I-A过渡型花岗岩的特征。锆石Lu-Hf同位素组成表明,花山花岗岩的ε_Hf(t)主要变化于-25.8~-19.6之间,t_DM2为2.81~2.43Ga,显示源区物质以古老的壳源物质为主,有年轻组分的参与。与岩体外围多金属成矿年龄的对比分析发现,外围金、钼矿床与花山复式岩体的年龄一致,比五丈山岩体晚20~25Ma,表明金、钼矿的形成与花山岩体在时空上联系密切,该岩体可能为成矿提供了热源。     

滇西新街岩体LA-ICP-MS锆石U-Pb年龄、Hf同位素和地球化学及其构造意义

新街岩体位于昌宁-孟连带北段,主要岩性为二长花岗岩。LA-ICP-MS锆石U-Pb定年结果表明,新街岩体侵位于约82Ma。岩体Si O2含量为74.28%~75.17%,富钾(K2O/Na2O=1.44~1.73)和较低钙Ca O(0.37%~0.41%),铝饱和指数(A/CNK)为1.121~1.156,富集Rb、Th、K、LREE等元素,相对亏损Nb、Ta、Ti、Zr、Hf等高场强元素。这些特征表明,新街岩体属于强过铝质S型花岗岩。新街岩体负且变化范围大的锆石εHf(t)值(-16.9~-0.5)和古老的Hf同位素地壳模式年龄(1.19~2.28Ga),表明其主要来源于古老地壳物质的重熔,并有不同程度的幔源物质加入。由于喜马拉雅新特提斯洋封闭发生在65Ma左右,新街岩体很可能是在喜马拉雅新特提斯洋洋壳俯冲的地球动力学背景下形成的。     

大兴安岭北段争光金矿英安斑岩地球化学特征、锆石U-Pb年龄及Hf同位素组成

争光金矿位于大兴安岭北段多宝山矿集区内,矿区内火成岩的成岩时代、岩石成因及成岩背景研究薄弱。因此,本文对矿区内英安斑岩进行了主微量元素、锆石U-Pb年龄和Hf同位素组成的系统研究,以期为探讨同时代火成岩的成因及矿床成矿背景提供帮助。锆石LA-ICP-MS U-Pb测年结果表明,争光金矿英安斑岩形成于早奥陶世(478~481Ma)。岩石地球化学特征显示,英安斑岩属准铝-过铝质高钾钙碱性系列,具有SiO_2≥56%(平均为63.91%)、高铝(Al_2O_3平均14.85%)、低镁(MgO平均2.70%)、低Y和Yb(Y=6.00×10~(-6)~7.74×10~(-6),Yb=0.70×10~(-6)~0.92×10~(-6))、高锶(平均368×10~(-6))、高Mg#(56.84~60.60)、轻重稀土分馏明显[(La/Yb)N=8.74~11.54]和Eu异常不明显的特点,类似于俯冲洋壳成因埃达克岩。锆石εHf(t)介于13.03~13.31之间,两阶段模式年龄(tDM2)为605~624Ma。综合岩石地球化学特征和锆石Hf同位素组成,我们认为争光英安斑岩由俯冲的新生洋壳发生部分熔融形成。本文研究结果也表明,早奥陶世,兴安地块和松嫩地块之间存在洋壳,并且该洋壳向兴安地块俯冲。     

西藏朱诺斑岩铜 钼 金矿区侵入岩锆石U Pb年龄、Hf同位素组成及其成矿意义

朱诺斑岩铜钼金矿位于冈底斯成矿带南缘,是近年来在冈底斯斑岩铜矿带最西端新发现的另一大型斑岩型铜-钼-金矿床,但一直以来对该矿区花岗岩年代学及成因分析缺乏系统的研究。本文选择矿区内主要岩浆岩体开展LA-ICP-MS锆石U-Pb定年,Hf同位素研究。获得黑云母花岗闪长岩锆石U-Pb年龄为14.14±0.32Ma,76 Hf/177 Hf介于0.282484~0.282750,εHf(t)介于-9.87~-0.49,二阶段模式年龄TDMC介于1.13~1.73Ga、似斑状二长花岗岩锆石U-Pb年龄为14.05±0.31Ma,176 Hf/177 Hf介于0.282633~0.282769,εHf(t)介于-4.61~0.21,二阶段模式年龄TDMC介于1.08~1.39Ga之间;角闪闪长玢岩锆石U-Pb年龄为14.10±0.29Ma,除4.1号为继承锆石外,其余测点176 Hf/177 Hf介于0.282607~0.282761,εHf(t)介于-5.53~-0.07,二阶段模式年龄TDMC介于1.10~1.45Ga之间。年代学与Hf同位素结果表明,朱诺斑岩铜矿与斑岩铜矿带中段和东段成岩成矿时代一致,集中在15~13Ma之间,指示了冈底斯在中新世的构造岩浆活动事件。花岗岩Hf同位素组成明显与中-东段斑岩矿床不同,具有富集Hf同位素特征以及古老二阶段模式年龄(1.08~1.73Ga)等特点,反映出朱诺矿区中新世岩浆岩源区与中-东段中新世斑岩矿床明显不同,可能指示古老拉萨地体的印迹。     

华北克拉通五台群LA-ICP-MS锆石U-Pb年龄和Hf同位素特征

通过对五台群石咀亚群金刚库组4个典型样品的LA-ICP-MS锆石U-Pb年龄和Hf同位素研究,对五台群的形成时代及华北克拉通新太古代—古元古代期间的地壳演化进行了探讨。锆石U-Pb同位素测定结果表明,侵入金刚库组中的片麻状花岗岩锆石的U-Pb年龄为2548Ma,因此五台群的上限年龄约为2.5Ga;金刚库组黑云母石英片岩和片麻状石英闪长岩的原岩锆石U-Pb年龄分别为2663Ma和2636Ma,因此五台群的下限年龄约为2.7Ga。五台群的地质年龄为2.5~2.7Ga,属于新太古代。锆石Hf同位素研究结果表明,黑云母石英片岩和片麻状石英闪长岩的二阶段Hf模式年龄(tDM2)均为2.8Ga左右,指示2.8Ga左右是五台山区乃至整个华北克拉通地壳生长的重要时期;片麻状花岗岩tDM2平均为2.57Ga,与锆石结晶年龄非常接近,表明2.5Ga左右也是华北克拉通地壳的主要增生期。地壳的增长是幕式的,2.8Ga和2.5Ga都是华北克拉通地壳生长时期。     

Exhumation History of a Garnet Pyroxenite-bearing Mantle Section from a Continent-Ocean Transition (Northern Apennine Ophiolites, Italy)

Garnet clinopyroxenite and garnet websterite layers occur locallywithin mantle peridotite bodies from the External Liguride Jurassicophiolites (Northern Apennines, Italy). These ophiolites werederived from an ocean–continent transition similar tothe present-day western Iberian margin. The garnet clinopyroxenitesare mafic rocks with a primary mineral assemblage of pyrope-richgarnet + sodic Al-augite (Na₂O 2·5 wt %, Al₂O₃ 12·5wt %), with accessory graphite, Fe–Ni sulphides and rutile.Decompression caused Na-rich plagioclase (An_50–45) exsolutionin clinopyroxene porphyroclasts and extensive development ofsymplectites composed of secondary orthopyroxene + plagioclase(An_85–72) + Al-spinel ± clinopyroxene ±ilmenite at the interface between garnet and primary clinopyroxene.Further decompression is recorded by the development of an olivine+ plagioclase-bearing assemblage, locally under syn-kinematicconditions, at the expense of two-pyroxenes + Al-spinel. Mg-richgarnet has been also found in the websterite layers, which arecommonly characterized by the occurrence of symplectites madeof orthopyroxene + Al-spinel ± clinopyroxene. The enclosingperidotites are Ti-amphibole-bearing lherzolites with a fertilegeochemical signature and a widespread plagioclase-facies myloniticfoliation, which preserve in places a spinel tectonite fabric.Lu–Hf and Sm–Nd mineral isochrons (220 ±13 Ma and 186.0 ± 1·8 Ma, respectively) have beenobtained from a garnet clinopyroxenite layer and interpretedas cooling ages. Geothermobarometric estimates for the high-pressureequilibration have yielded T 1100°C and P 2·8 GPa.The early decompression was associated with moderate cooling,corresponding to T 950°, and development of a spinel tectonitefabric in the lherzolites. Further decompression associatedwith plagioclase–olivine growth in both peridotites andpyroxenites was nearly isothermal. The shallow evolution occurredunder a brittle regime and led to the superposition of hornblendeto serpentine veining stages. The garnet pyroxenite-bearingmantle from the External Liguride ophiolites represents a raretectonic sampling of deep levels of subcontinental lithosphereexhumed in an oceanic setting. The exhumation was probably accomplishedthrough a two-step process that started during Late Palaeozoiccontinental extension. The low-pressure portion of the exhumationpath, probably including also the plagioclase mylonitic shearzones, was related to the Mesozoic (Triassic to Jurassic) riftingthat led to continental break-up. In Jurassic times, the studiedmantle sequence became involved in an extensional detachmentprocess that resulted in sea-floor denudation. KEY WORDS: garnet pyroxenite; ophiolite; non-volcanic margin; mantle exhumation; Sm–Nd and Lu–Hf geochronology     

The Central Scandinavian Dolerite Group—Protracted hotspot activity or back-arc magmatism?: Constraints from U–Pb baddeleyite geochronology and Hf isotopic data

The Central Scandinavian Dolerite Group (CSDG) occurs in five separate complexes in central Sweden and SW Finland. U–Pb baddeleyite ages of dolerite dikes and sills fall into three age intervals: 1264–1271 (the Dalarna complex), 1256–1259 (the Västerbotten-Ulvö-Satakunta complexes) and 1247 Ma (the Jämtland complex). Timing and spatial distribution of CSDG are unlike expressions of the voluminous and short-lived magmatism which characterises plume-associated large igneous provinces (LIPs). Protracted mafic magmatism in association with mantle plume tail (hotspot) activity beneath the Fennoscandian lithosphere or discrete events of extension behind an active margin (subduction) are considered more plausible tectonic settings. Both settings are consistent with timing, relative magma volumes between complexes and vertical ascent of individual magma pulses through the crust, as inferred from seismic sections [Korja, A., Heikkinen, P., Aaro, S., 2001. Crustal structure of the northern Baltic Sea palaeorift. Teconophysics 331, 341–358]. In the hotspot model, the lack of a linear track of intrusions can be explained by an almost stationary position of Fennoscandia relative to the hotspot, in agreement with palaeomagnetic data [Elming, S.-Å., Mattsson, H., 2001. Post Jotnian basic intrusion in the Fennoscandian Shield, and the break up of Baltica from Laurentia: a palaeomagnetic and AMS study. Precambrian Res. 108, 215–236]). Together with geological evidence, dolerite sill complexes and dike swarms in Labrador (Canada), S Greenland and central Scandinavia in the range 1234–1284 Ma are best explained by long-lived subduction along a continuous Laurentia-Baltica margin preceding Rodinia formation. There is no support for the hypothesis that CSDG was fed by magma derived from a distal mantle plume located between Baltica and Greenland and, hence, for rifting between the cratons at 1.26 Ga.The epsilon-Hf in various members of the CSDG varies between 4.7 and 10.3, which are overall higher than both older and younger Mesoproterozoic mafic intrusions in central Fennoscandia. Magma generated from a hotspot mantle source that was mixed to highly variable degrees with an enriched subcontinental lithospheric mantle could account for the wide range in Hf isotope composition. In the course of Hf isotope development work during this project we have analysed four fragments of the Geostandard 91500 reference zircon and after evaluating the existing ICPMS and TIMS data we calculate a mean ¹⁷⁶Hf/¹⁷⁷Hf value of 0.282303 ± 0.000003 (2σ).