Correlation between geochemical environments and controlling factors in the metallation of porphyrins

Experimental study on metallation of tetrapyrroles in biphasic systems showed that complexation with metal cations of the first transition series is a feasible under chemical environments similar to the naturally occurring ones. The metal transport from the aqueous media to the organic, which is a novel approach using naturally occurring fatty acids hydroxy aromatic compounds and thiols, is demonstrated. Selectivity between Ni²⁺ and VO²⁺ complexation is achieved under sulfurous rich conditions. The kinetic implications are discussed in view of their geoenvironmental applicability.     

Annual heat balance and equilibrium temperature of Lake Aegeri,Switzerland

The mean heat budget of Lake Aegeri, Switzerland, is 950 MJ·m^–2, comparable to that of neighbouring lakes. The annual variation in the net heat flux can be adequately described using a six-term heat balance equation based on 12 years of monthly mean meteorological and surface temperature data. Although the magnitude of the net heat flux is dominated by the radiative terms of the equation, the one-month backward shift of the net flux and total heat content extrema from the solstices and equinoxes respectively is due to the phase shift of the non-radiative with respect to the radiative terms. A linear approximation was used to express the net heat flux in terms of a heat exchange coefficient and an equilibrium temperature. The former varies from 17 to 28 W·m^–2·K^–1 in the course of a year; fluctuations in the latter are found to depend mainly on fluctuations in cloud cover and relative humidity, whilst the effect of fluctuations in air temperature and wind speed is slight.     

青藏高原模式大气(暂用)

本文根据青藏高原地区高空温、压、湿的气候资料并参考中纬度与热带模式大气初步建立了青藏高原不同季节的模式大气,以供该地区辐射传输研究的需要。     

The influence of medium-range transport on O3 levels at a rural site in Israel

Simultaneous ozone measurements were made at a rural site, 25 km SSW of the city of Jerusalem, and in the center of the city during a period of 28 months. The ozone data were supplemented by SO₂, NO/NO _x ,and meteorological measurements at both sites. Elevated ozone concentrations were recorded at the rural site, mostly during the spring months (May and June) during which the monthly averages and the monthly averages of the daily 30 min maximum levels equalled those measured in the city. During the summer months, both average and peak levels were lower at the rural site by 20 and 35 ppb. The increased ozone levels at the rural site were accompanied by a parallel increase of SO₂ and NO _x ,suggesting hat the excess ozone at the rural site is a result of a transformation during transport of air pollutants from coastal sources.     

Global spectra of energy and enstrophy and their fluxes during July 1979

Transient and stationary spectra of kinetic energy (KE), available potential energy (APE) and enstrophy (EN), and their spectral fluxes as a function of the two-dimensional wavenumbern were computed for July 1979. Triangular truncation at zonal wavenumber 42 was used for computation. The slopes of various spectra in the wavenumber range 14≤n≤25 were obtained by fitting a straight line in log-log scale by the least square method. The transientKE, APE andEN spectra in the lower (upper) troposphere had slopes −2·21 (−2·30), −2·65 (−2·64) and −0·36 (−0·46), respectively. The effect of stationary and divergent motion on the slope values was investigated. The possible correlation between the slope and percentage of transient component in the combined energy and enstrophy was examined to identify the transient motion of the atmosphere with the two-dimensional homogeneous isotropic turbulence. The vertically averaged slope of kinetic energy and enstrophy in the lower (upper) troposphere was close to the value at 700 (200) hPa level. The spectral fluxes of kinetic energy and enstrophy in the wavenumber range 14≤n≤25 satisfied, to a very rough approximation, the criteria of inertial subrange. The stationary fluxes were small. The estimated stationary-transient component of flux was larger, comparable and less than the corresponding transient flux of APE, KE and EN. Representative levels for computation of energy and enstrophy spectra and their fluxes in the lower and upper troposphere were identified.     

伸展盆地转换带分析──以松辽盆地北部为例

转换带可划分为５种类型：离散型转换带，汇聚型高凸起与低凸起转换，同向型高凸起与低凸起转换带。其中当伸展增加时，高凸起转换带可能发展为低凸起转换带。转换带的形成是由于变形地壳物质组成的不均一笥或区域张应力场的不均一性，而使伸展断层呈侧列或雁列式发生。松辽地发育种类型转换带，而以同向型高凸起低凸起转换带最为发育，推测高凸起转换带是盆岭式裂谷系的典型转换带。转换带是油气有利聚集区。     

Gravel transport and morphological change in braided sunwapta river,Alberta, Canada

The relation between morphological change and patterns of variation in bedload transport rate in braided streams was observed by repeated, daily topographic surveys over a 25 day study period in a 60 m reach of the proglacial Sunwapta River, Alberta, Canada. There are two major periods of morphological change, each lasting several days and each involving the complete destruction and reconstruction of bar complexes. Bar complex destruction was caused by redirection of the flow and by downstream extension of the confluence scour zone upstream. Reconstruction involved accretion of unit bars on bar head, flank and tail and in one case was initiated by disection of a large, lobate unit bar. High rates of sediment movement, measured from net scour and fill of the cross-sections, coincided with these morphological changes. Sediment was supplied from both bed and bank erosion, and patterns and distances of transfer were highly variable. Rates of transport estimated by matching upstream erosional volumes with downstream deposition were much greater than those estimated from either a step-length approach or a sediment budget. Measurements of scour and fill and observations of morphological change indicate that step lengths (virtual transport distances) were typically 40–100m during a diurnal discharge cycle. Shorter step lengths occurred when transfer was confined to a single anabranch and longer steps involved channel changes at the scale of the entire reach. Sediment budgeting was used to describe the spatial patterns of sediment transport associated with the morphological changes and to estimate minimum daily reach-averaged transport rates. Mean bedload transport rates correlate with discharge, but with considerable scatter. The largest deviations from the mean relation can be tied to phases of channel incision, bank erosion, scour hole migration, bar deposition and channel filling apparently controlled by changes and fluctuations in sediment supply from upstream, independent of discharge. These are interpreted as field evidence of ‘autopulses’ or ‘macropulses’ in bedload transport, previously observed only in laboratory models of braided streams.     

Diurnal freeze–thaw depth in rockwalls: Field measurements and theoretical considerations

Rock temperatures were monitored for a year at two alpine rockwalls in the Akaishi Range, Japan, where permafrost is absent. Diurnal frost and thaw penetration depths were evaluated from subsurface isotherms drawn on the basis of the temperature records at 0, 10 and 40 cm depths. The surface of the rockwalls experienced more than 100 diurnal freeze-thaw cycles, most of which accompanied a frost or thaw penetration shallower than 50 cm, and several long duration cycles with deeper frost or thaw penetration. Theoretical frost and thaw depths were also calculated by incorporating the surface freezing indices into the modified Berggren equation, the results from which were then compared with the actual values. The modified Berggren equation provided values that showed a strong correlation with observed depths, despite somewhat underestimating the actual values. Using the modified Berggren equation, the seasonal frost depth in the observed winter was estimated to be about 4·5 m. The frost and thaw depths are considered to give the maximum estimation of the depth to which frost-induced cracking can propagate in the bedrock.