矿物材料应用于香烟过滤嘴降害的研究现状与展望

总结了近几十年来包括活性炭、沸石、蒙脱石、海泡石、麦饭石、凹凸棒石、氧化铝、氢氧化钠、明矾、纳米材料等矿物材料作为卷烟滤嘴添加剂以去除烟气中有毒有害物质的研究和实验应用及效果。实验结果和市场调查表明,活性炭是减少卷烟危害最快、香烟市场应用增长最快的过滤嘴添加剂。从降低卷烟有害成分的比例和成本等综合因素来看,铝硅酸盐类滤嘴和多材料复合滤嘴亦有很好的应用前景和市场需求,应积极进行研制。     

内蒙古赛乌素金矿稳定同位素组成特征及成因意义

内蒙古赛乌素金矿是产于中-新元古代白云鄂博群变质碎屑岩中的石英脉型金矿,矿床稳定同位素地球化学特征表明,成矿热液来源复杂,可能有岩浆水和大气降水的混合作用;成矿早期的硫来自花岗岩浆,成矿晚期的硫有一部分可能来自地层,铅同位素特征表明铅来自地幔,因此推断成矿物质主要来自于岩浆活动.     

Evaluation of Simultaneous Analyte Leaching/Vapour Phase Introduction for Direct Osmium Isotope Ratio Measurements in Solid Samples by Double-Focusing Sector Field ICP-MS

The analytical performance of a method for Os isotope ratio measurement by double‐focusing, sector field ICP‐MS (ICP‐SFMS) was evaluated. The method is based on several optimised, concurrent processes: Os extraction from samples in hot concentrated nitric acid; separation of Os from the digest solution by the formation of volatile osmium tetroxide accelerated by continuous hydrogen peroxide addition; transport of analyte vapour by an oxygen flow into the ICP; and isotopic determination by ICP‐SFMS. Due to the very efficient utilisation of analyte (approaching 0.5‰), Os isotope ratio measurement could be performed at low pg levels. Combined with an ability to process sample sizes up to 2 g (up to 50 g if the organic matrix of biological or botanical samples is eliminated by ashing), materials with Os concentrations in the low, or even sub pg g^?1 range could be determined by this method. Given that two complete digestion/distillation systems were available for interchangeable use, throughputs of up to fifteen samples per 8 hour shift could be achieved. The method precision, evaluated as the long‐term reproducibility of ¹⁸⁷ Os/¹⁸⁸Os ratio measurements in a commercial Os reference sample containing 0.5 ng Os, was 0.16% relative standard deviation (RSD, 1s). The method has been applied to perform replicate ¹⁸⁷ Os/¹⁸⁸ Os ratio measurements on a suite of fifty reference materials of various origins and matrix compositions, with Os concentrations varying from < 0.1 pg g^?1 to > 100 ng g^?1, yielding an average precision of 3% RSD. Though none of the materials tested are certified for Os content or Os isotope composition, comparison of the obtained data with published Os isotope information for similar sample types revealed close agreement between the two. The method can also be used for the simultaneous, semi‐quantitative determination of Os concentrations.     

Determination of Bromine and Iodine in Twenty-three Geochemical Reference Materials by ICP-MS

Trace amounts (from nanogram to microgram levels) of bromine and iodine were determined by inductively coupled plasma-mass spectrometry (ICP-MS) in twenty-three geochemical reference materials issued by the GSJ, USGS, IAEA etc. The pyrohydrolysis technique was used to separate bromine and iodine from samples analysed in the form of powder. The accuracy and precision of the experimental values were assessed by the comparative analysis of well established reference materials such as USGS AGV-1, BCR-1 and IGGE GBW07312. The measured values agreed well with reported values within a 10% error range. We also report reliable new data for these elements in these geochemical reference materials.     

应变组合的地质意义及其分解实例

以分析递进变形序列为主线,论述了主有限应变和增量应变的内部旋转所组合的应变扇形区的空间展布。结合发育于剪切带中的一个微细粒浸染型金矿的找矿实际,指出该理论的野外应用方法。     

General absorbing boundary conditions for dynamic analysis of fluid-saturated porous media

General absorbing boundary conditions based on Biot's two-phase mixture theory and paraxial approximation is presented for the dynamic analysis of fluid-saturated porous media with isotropic, transverse isotropic, and anisotropic properties. For the last two cases, the equivalent Lame's constants, under conditions of uniqueness, are introduced to facilitate the analytical solutions. The numerical results show that the proposed absorbing boundary can greatly suppress spuriously reflected waves and efficiently model the far field of the system with sufficient accuracy.     

Determination of the Platinum-Group Elements and Gold in Twenty Rock Reference Materials by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) after Pre-Concentration by Nickel Sulfide Fire Assay

The platinum-group elements (PGE) and gold have been determined in twenty international rock reference materials by inductively coupled plasma-mass spectrometry (ICP-MS) after pre-concentration by a nickel sulfide fire assay. It was possible to achieve determination limits for a 50 g sample that ranged from 1 pg g^-1 (Rh) to 23 pg g^-1 (Au). Compared to published certified and recommended values for rock reference materials, the trueness of the method was found to be good. However, in some cases we observed large deviations for all elements in the sub 10 ng g^-1 range within individual reference sample splits. Our results show that the PGE and Au are inhomogeneously distributed in the reference materials analysed here, where they are present in low concentrations, using 50 g test portions.     

A note on permeability changes in geologic material due to stress

Summary Stress produces framatic changes in fluid permeability of geologic materials. An increase of nearly threefold occurred in granite at high stress, an increase of 20 percent in sandstone, and a hundredfold decrease in compacted sand. Permeability of sand and sandstone did not follow the effective stress law. Flow along joints was very sensitive to effected stress changes, a fourfold change being caused by as little as 1.0 MPa.     

Multiscale approach to geo‐composite cellular structures subjected to rock impacts

Geo‐composite cellular structures are an efficient technological solution for various applications in civil engineering. This type of structure is particularly well adapted to resisting rockfalls and can act as a defensive structure. However, the design of such structures is for the most part empirically based; this lack of research‐based design stagnates optimization and advanced development. In this paper, the mechanical behaviour of a geo‐composite cellular structure is investigated using a multi‐scale approach, from the individual cell made up of an assembly of rocky particles contained in a wire netting cage to the entire structure composed of a regular array of cells. Based on discrete modelling of both the cell and structure scales, a computational tool has been developed for design purposes. Copyright © 2007 John Wiley & Sons, Ltd.