坦桑尼亚西北部苏库马绿岩带含金石英脉成矿特征

坦桑尼亚克拉通西北部的苏库马绿岩带是坦桑尼亚环维多利亚湖绿岩带重要的金矿聚集区。区内金矿化类型以含金石英脉为主,矿体的产出主要受剪切构造带控制。通过研究区域构造特征和岩石地球化学特征,认为苏库马绿岩带中玄武岩为弧后环境形成,流纹岩和花岗岩形成于陆弧环境,N--S向挤压作用和E--W向伸展作用是区域内主要的构造展布特征。建立了含金石英脉的成矿模式,表明具有金矿化作用的石英脉集中分布在EW、SEE、NE向剪切构造破碎带中,含金石英脉富矿体的形成经历了多期构造变形和成矿流体的叠加、富集作用。     

JMD型滤池双层滤料的净水试验及比较

大量的试验数据表明石英砂和陶粒组成的双层滤料，其净水处理性能明显好于石英砂和无烟煤双层滤料以及单层石英砂滤料，特别是出水浊度、微絮凝作用，反冲洗周期、藻类的去除、絮凝剂的使用量等指标上具有明显优势，陶粒做为一种新的水处理滤料，正被应用于净水和污水处理。     

Fluid Inclusion Studies of Comb Quartz and Stibnite at the Hishikari Au–Ag Epithermal Deposit,Japan

Fluid inclusion microthermometry was conducted on late‐stage barren comb quartz and the latest stibnite at the Hishikari deposit to characterize the hydrothermal activity responsible for vein formation. Eight fluid inclusion assemblages (i.e. fluid inclusions trapped at the same time, ‘FIAs’) were studied to determine the formation fluid temperatures and salinities for the comb quartz in the Shosen No. 2 vein, Sanjin ore zone, and the stibnite in the Seisen No. 1–1 vein, Yamada ore zone. The average homogenization temperatures (the formation temperatures) of the seven FIAs from the comb quartz were between 207 and 230°C, while the average homogenization temperature (the formation temperature) of an FIA from the stibnite was 113°C. The measured fluid salinities of the seven FIAs from the comb quartz were low, ranging between 0.0 and 1.1 wt% NaCl equiv., indicating that dilute fluids were responsible for the comb quartz formation. By comparison with previous microthermometric data, the formation temperatures of the studied comb quartz were higher than those of columnar adularia and comb quartz at most other veins (generally around 200°C) but were similar to those of columnar adularia at Keisen veins (230°C) in the same ore zone. The higher formation temperatures both in the Shosen and the Keisen veins in the Sanjin ore zone indicate that the fractures corresponding to the vein system at the Sanjin ore zone were main conduits for hot ascending fluids. The low formation temperature of stibnite in the latest stage (113°C) indicates that stibnite precipitation occurred during a waning stage of hydrothermal activity. Combined with previous thermodynamic data on antimony solubilities, the large discrepancy between the formation temperature of the comb quartz (200–230°C) and that of the stibnite suggests that the stibnite may have precipitated as a result of a drastic cooling of the hydrothermal system.     

法国Echassieres地区石英网脉中黑钨矿及其共生矿物的固溶体研究

Echassiares石英网脉中的黑钨矿主要系钨锰矿一钨铁矿系列中的铁端员矿物一钨铁 矿，富泥但贫担，当其与妮铁矿共生时，钨铁矿可含8.91% Nb205。在该矿物中常见的元素置换 有:(1)Fe2+→Mn2+;(2)Wg6+Fe2+→Nb5+ +Fe+3 (3) 3W6+ +Fe2+ →4Nb5+。 妮铁矿呈它形，富含Ta. W,Ti。钨铁捉矿以枝状形态位于钨铁矿和妮铁矿之间，形成完整的矿物组合。Beauvoir花岗岩的侵位带入的热液交代钨铁矿是形成这种矿物组合的主要原因。同时,铅钨铁矿中的裂隙带或其边部还局部发生钨锰矿化。     

安家营子金矿含金和无金石英的标型特征

系统研究了安家营子金矿区含金石英和无金石英的微量元素、流体包裹体、颜色、比重、发光、晶胞参数和红外光谱等标型特征，并依据所得数据对这两类石英进行了判别分析，提出了一系列的找矿标志。     

Silica mobility and fluid movement during metamorphism of the Connemara schists, Ireland

Quartz veins are developed in a wide range of metasediment types in the upper amphibolite facies rocks of Connemara, and attest to considerable migration of silica. Contrary to common assumptions, there is clear evidence that these veins do not primarily result from movement of fluid to regions of lower P–T down the regional geothermal gradient. Under amphibolite facies conditions, a dilute chloride fluid moving down temperature has the potential to alter 60g of plagioclase to muscovite for each gram of vein quartz precipitated, while cooling over the temperature interval from 650 to 500° C. The absence of significant metasomatic effects in the vein walls effectively precludes a simple origin from such through-flowing, externally derived fluids. The oxygen isotopic composition of matrix quartz shows considerable differences between different rock types (quartzite, pelite and marble), with a range of δ¹⁸O_SMOW from c.+ 11.5% (quartzite) to + 18.5% (marble). In each rock type, vein quartz compositions closely match those of the matrix quartz. These results demonstrate the importance of local segregation processes in the formation of veins, and suggest that fluid convection cells were not developed during metamorphism on a scale larger than the individual sedimentary formations, if at all. Both oxygen isotope data and the absence of metasomatism indicate that veins form primarily by segregation of quartz from the host lithologies, with only a relatively minor component of through flow of externally derived fluid. Veins are clearly not the major pathways of metamorphic dewatering. It is proposed that abundant veins in the predominantly pelitic Ballynakill Formation formed during peak metamorphic D3 folding because the formation was embrittled by high fluid pressures but was capped by impermeable marble. Hence the pelitic formation fractured repeatedly and the pore fluid drained through the fractures to form veins, while irreversible loss through the rest of the succession was a much less important process. In the central mountains of Connemara, rather pure, unreactive quartzites are cut by widely spaced, laterally extensive quartz veins that are axial planar to D3 folds. These veins may mark pathways whereby metamorphic fluid made its way through the massive impermeable quartzite from lower parts of the nappe pile, but here too, oxygen isotope data indicate considerable segregation of locally derived quartz, reflecting the importance of pumping of fluid between wail rocks and fractures relative to the component of through flow.     

高纯球形-准球形亚微米晶质SiO2材料的制备与表征

以天然粉石英为基本原料,通过氢氟酸与盐酸混合酸溶蚀技术和机械强力搅拌处理,制备了高纯球形-准球形亚微米晶质SiO2材料。XRD,SEM表征结果表明,制备的高纯球形亚微米晶质SiO2材料为纯结晶SiO2相,粒子呈球形-准球形,球化-准球化率达80%～90%,粒径一般为300 nm～800 nm;其化学组成为:w(SiO2)99.90%,w(Al2O3)192×10-6,w(Fe2O3)33×10-6,w(Mg)1×10-6,w(Ca)2×10-6,w(Cl-)20×10-6。     

The Role of Seal and Source Rocks in Fluid-rock Interactions and their Reservoir Effects within the Carbonate Deep Burial Realm

Discoveries of deep high-quality carbonate reservoirs challenged the general understanding on the evolution of porosity decreasing with depth. New mechanisms of pore generation and preservation in the deep realm require to be proposed. Dolostones in the Feixianguan and Dengying Formations experienced maximum depths in excess of 8000 m, but still retained high porosity. Petrographic observation and homogenization temperatures help to identify products of deep fluid-rock interactions, visual and experimental porosity were used to quantify reservoir effects, the distribution of products finally being plotted to unravel the mechanisms. Th data reveal that thermochemical sulfate reduction (TSR), burial dissolution and quartz cementation are typical deep fluid-rock interactions. The SO42? of residual porewater sourced from the evaporative dolomitizing fluid was supplied for TSR in the hydrocarbon column, the TSR-inducing calcite cements were homogeneously dispersed in the hydrocarbon column. Quartz cementation was caused by the increasing acidity and Si-rich residual porewater in the oil column. Burial dissolution is forced by organic acid and limited in oil–water contact. This study suggests that seal and source rocks not only play important roles in hydrocarbon accumulation, but also have a general control on the deep fluid-rock interactions and porosity evolution in the deep burial realm.     

浅成火山岩中石英斑晶的分离方法研究

在总结大量矿物分选的实践基础上,系统研究了用混合重液法分离石英斑晶的理论和操作方法及用折光率法间接测量混合重液的技术.发现了用折光率值为1.577~1.579的系列混合重液分离石英斑晶效果最好,分离纯度达到95%~98%,解决了从浅成火山岩中分选单晶石英的难题,极大地提高了石英的分离效率、纯度和回收率,从过去石英的富集率20茗提高到95%~98%,从人工挑选的几克增至几百克,可从挑选的40~80目扩大到120目.     

Geology of Gold Ore Deposits in Western Linyi of Shandong Province,China

1IntroductionWestern Linyi of Shandong Province is one of the most important gold ore mineralization concen-tration areas. Tongjing skarn type gold copper de-posit, Jinchang skarn type gold copper deposit and Duijinshan porphyry type gold deposit were found in 1960's (Edited committee, 1996). Following the discovery of Guilaizhuang gold ore deposit related to alkaline rocks in 1988, the western Linyi region becomes one of the extensively studied areas of gold deposits in China (Lin etal.,…