南秦岭佛坪麻粒岩的矿物学和地球化学特征及其构造意义

采用电子探针、红外光谱和全岩化学分析方法,对佛坪麻粒岩开展了系统的矿物学和地球化学研究。研究结果表明本区麻粒岩以酸性岩为主,主要组成矿物为长石、石英、石榴子石、紫苏辉石及少量的黑云母和钙质角闪石。岩石富集轻稀土和大离子亲石元素,亏损高场强元素,具有强烈的Nb、Ta负异常,表明源岩在成因上与洋壳的俯冲消减作用有关。结合区域地质和测年资料,我们认为佛坪麻粒岩源岩的形成与勉略古洋壳向南秦岭地块之下的俯冲有关,是中—晚三叠世南秦岭与扬子地块的陆-陆碰撞所导致的麻粒岩相变质作用的产物。     

An experimental,analytical and numerical study on the thermal efficiency of energy piles in unsaturated soils

Energy piles are bi-functional foundation elements used as structural support as well as ground heat exchangers for shallow geothermal energy systems. Because they are relatively short, energy piles may be partially embedded in unsaturated soils. Saturation conditions influence the thermal properties of the ground and therefore the heat exchange rate, which in turn affects the efficiency of energy piles. This paper combines analytical, experimental and numerical investigations to evaluate the heat exchange rate of energy piles partially or fully embedded in unsaturated soils. The proposed analytical solution is based on the cylindrical heat source theory that treats the soil as a semi-infinite, homogeneous, and isotropic medium. The solution from this theory is multiplied by a function developed analytically in this paper and the outcome is the heat exchange rate for energy piles in unsaturated soils. The proposed function depends on soil saturation, soil and pile thermal properties, and pile geometry. The analytical solution was compared against a finite element solution; which was in turn validated against results from laboratory experiments. Very satisfactory agreements between the analytical, numerical and experimental outputs were observed. The proposed method can be used for a quick and simple evaluation of the efficiency of energy piles in unsaturated conditions. The proposed analytical solution can also be a useful tool for the verification of numerical codes developed for the design of energy piles in unsaturated soils.     

Magnetostratigraphy of Upper Cretaceous strata in Grand Staircase-Escalante National Monument,southern Utah: The Santonian–Campanian Stage boundary,reassessment of the C33N/C33R magnetochron boundary,and implications for regional sedimentation patterns within the Sevier Foreland Basin

Samples were collected for magnetostratigraphic analysis from the Upper Cretaceous Straight Cliffs and Wahweap formations within Grand Staircase-Escalante National Monument, southern Utah, in an attempt to locate the C34n–C33r and C33r–C33n boundaries; the former approximates the Santonian–Campanian Stage boundary. Locating both of these horizons within the Monument provides for refined temporal resolution of the many new fossil localities discovered in these units, while also adding to our understanding of the overall Straight Cliffs–Wahweap sequence stratigraphic architecture. Results indicate that the John Henry and Drip Tank members of the Straight Cliffs Formation are of normal polarity, and represent the later part of C34n, the Cretaceous Normal Polarity Super-Chron. The C34n–C33r boundary apparently resides in a significant hiatus determined to occur between the Drip Tank Member of the Straight Cliffs Formation and the lower part of the overlying Wahweap Formation. In stratigraphically ascending order, the informally named lower, middle, and most of the upper members of the Wahweap Formation are of reversed polarity. The C33r–C33n polarity change occurs in the upper part of the upper member, and C33n continues stratigraphically upward through the capping sand member of the Wahweap Formation and into the overlying Kaiparowits Formation. The presence of over 200 m of reversely magnetized strata above a level in the lower part of the middle member dated to 79.9 ± 0.3 Ma, which coincides with the GTS2012 date for the C33r–C33n boundary of 79.9 Ma, suggests that the published age of that boundary may be in error. A new date of approximately 78.91 Ma is proposed, in turn allowing for the thick sequence of reversely magnetized strata above the 79.9 Ma level. Age revision of the Kaiparowits Basin's Late Cretaceous record demonstrates that during late Santonian through early middle Campanian time, except in central Utah, a close correlation in time and facies successions with other successions throughout the Western Interior Basin suggests a eustatic influence on the depositional patterns. Starting in the late middle Campanian, the Kaiparowits record, along with those both to the north and south, appear to diverge in style and facies successions. We consider this to have resulted from a fundamental change in depositional controls triggered by the Laramide Orogeny. The anomalous central Utah record appears to have been profoundly influenced by a massive salient (Nebo-Charleston thrust system) in the Sevier Fold and Thrust belt that was active for much of the Late Cretaceous.     

扬子陆块西部古隆起演化及其对郁南运动的反映

寒武纪—奥陶纪之交的郁南运动是华南重要构造事件,但以往研究与认识局限于中国东南部。同期构造运动对扬子陆块的影响尚不明确,制约了对郁南运动的全面理解。本文以扬子陆块西部为例,分析芙蓉统(末寒武统)至下奥陶统地层接触关系,特别是地层不整合面分布,重建了古隆起演化过程并初步探讨其机制;在各期沉积相和岩相古地理演化基础上,总结了盆山耦合与沉积响应特征。结果表明:寒武纪—奥陶纪之交的构造运动在扬子陆块西部有显著表现,反映为大规模古隆起形成、相对海平面和沉积相配置变化;其机制与克拉通边缘基底古陆对地壳位移、变形的阻挡有关,从板块尺度上看,可能是扬子陆块东南侧构造挤压在陆块西部的同步响应。据此笔者提出,寒武纪—奥陶纪之交的华南存在广义的、可对比的"郁南运动",可能是早古生代构造—盆地性质由拉张向挤压转型的重要节点。     

Regional metamorphism and the alteration response of selected Silurian to Devonian mineral systems in the Nymagee area,Central Lachlan Orogen,New South Wales: a HyLogger™ case study

The southern Cobar Superbasin includes the Mount Hope, Cobar and Rast troughs and adjacent Winduck, Mouramba and Kopyje shelves. These stratotectonic units host a range of mineral systems within deformed upper Silurian to Lower Devonian rocks. Despite the metallogenic importance of the terrane the regional metamorphic- and alteration-related mineral assemblages have not been systematically described until now. Here, we present a study using the HyLogger? spectral scanner to systematically map changes in both background and alteration-related mineralogy for 14 mineral systems across the Nymagee area. The study found that, with the exception of the late diagenetic zone assemblages associated with the Winduck Shelf, the mineral assemblages for zones away from mineralisation are consistent with uniform sub- to lowest-greenschist facies metamorphic conditions, with no evidence for a regional, thermal field gradient across the basin. By contrast, proximal to mineralisation, there are significant changes in alteration-related mineral abundances and species reflecting elevated fluid temperatures. For several zones, including Browns Reef, Great Central, Hera, May Day, Nymagee and Shuttleton, there is a systematic change in chlorite composition from Fe- and/or Fe–Mg-chlorites to more Mg-rich varieties towards mineralisation. In addition, talc was noted for May Day, Mineral Hill and Shuttleton. The change in chlorite composition suggests that these ore-forming fluids were undersaturated with respect to iron. Furthermore, although present in discrete zones, carbonate alteration is not a dominant alteration type. However, at Manuka and Blue Mountain, the mineralisation is associated with carbonate-rich (calcite, ankerite, dolomite) units that have been dolomitised (Mg alteration) but not all dolomite-rich zones are mineralised. For Mineral Hill, there are systematic changes to mineral species/chemistry with observed data consistent with Parkers Hill being proximal to the centre of a mineralising system. The G and H Lode area (Southern Ore Zone) is slightly more distal whereas the Pearse deposit may represent a zone more distal again.     

Rock–water interactions and pollution processes in the volcanic aquifer system of Guadalajara,Mexico, using inverse geochemical modeling

In order to understand and mitigate the deterioration of water quality in the aquifer system underlying Guadalajara metropolitan area, an investigation was performed developing geochemical evolution models for assessment of groundwater chemical processes. The models helped not only to conceptualize the groundwater geochemistry, but also to evaluate the relative influence of anthropogenic inputs and natural sources of salinity to the groundwater. Mixing processes, ion exchange, water–rock–water interactions and nitrate pollution and denitrification were identified and confirmed using mass-balance models constraint by information on hydrogeology, groundwater chemistry, lithology and stability of geochemical phases. The water–rock interactions in the volcanic setting produced a dominant NaHCO₃ water type, followed by NaMgCaHCO₃ and NaCaHCO₃. For geochemical evolution modeling, flow sections were selected representing recharge and non-recharge processes and a variety of mixing conditions. Recharge processes are dominated by dissolution of soil CO₂ gas, calcite, gypsum, albite and biotite, and Ca/Na exchange. Non-recharge processes show that the production of carbonic acid and Ca/Na exchange are decreasing, while other minerals such as halite and amorphous SiO₂ are precipitated. The origin of nitrate pollution in groundwater are fertilizers in rural plots and wastewater and waste disposal in the urban area. This investigation may help water authorities to adequately address and manage groundwater contamination.     

Brunovistulian terrane (Bohemian Massif, Central Europe) from late Proterozoic to late Paleozoic: a review

The Brunovistulian terrane represents a microcontinent of enigmatic Proterozoic provenance that was located at the southern margin of Baltica in the early Paleozoic. During the Variscan orogeny, it represented the lower plate at the southern margin of Laurussia, involved in the collision with the Armorican terrane assemblage. In this respect, it resembles the Avalonian terrane in the west and the Istanbul Zone in the east. There is a growing evidence about the presence of a Devonian back-arc at the margin of the Brunovistulian terrane. The early Variscan phase was characterized by the formation of Devonian extensional basins with the within-plate volcanic activity and formation of narrow segments of oceanic crust. The oldest Viséan flysch of the Rheic/Rhenohercynian remnant basin (Protivanov, Andelska Hora and Horní Benesov formations) forms the highest allochthonous units and contains, together with slices of Silurian Bohemian facies, clastic micas from early Paleozoic crystalline rocks that are presumably derived from terranes of Armorican affinity although provenance from an active Brunovistulian margin cannot be fully excluded either. The development of the Moravo–Silesian late Paleozoic basin was terminated by coal-bearing paralic and limnic sediments. The progressive Carboniferous stacking of nappes and their impingement on the Laurussian foreland led to crustal thickening and shortening and a number of distinct deformational and folding events. The postorogenic extension led to the formation of the terminal Carboniferous-early Permian Boskovice Graben located in the eastern part of the Brunovistulian terrane, in front of the crystalline nappes. The highest, allochthonous westernmost flysch units, locally with the basal slices of the Devonian and Silurian rocks thrusted over the Silesicum in the NW part of the Brunovistulian terrane, may share a similar tectonic position with the Giessen–Harz nappes. The Silesicum represents the outermost margin of the Brunovistulian terrane with many features in common with the Northern Phyllite Zone at the Avalonia–Armorica interface in Germany.     

Isothermal decompression history in the “Western Granulite” terrain, central Tanzania: Evidence from reaction textures and trapped fluids in metapelites

The Mozambique Belt (MB) of the East Africa Orogen contains large areas of granulite-facies migmatitic gneisses with Archaean and Palaeoproterozoic protolith ages and that were recycled during the Neoproterozoic Pan-African orogeny. The study area is situated along the Great Ruaha River and within the Mikumi National Park in central Tanzania where migmatitic gneisses and mafic to intermediate granulites are interlayered with Neoproterozoic granulite-facies migmatitic metapelites. Mineral textures suggest isothermal decompression, with the peak mineral assemblage comprising Grt–Bt–Ky–Kfs–Pl–Qtz ± Phn ± Ti-Oxide ± melt and amphibolite-facies retrograde assemblage Grt–Bt–Sil–Ms–Kfs–Pl–Qtz ± Fe–Ti-Oxide. The near isothermal retrograde overprint is seen in well-developed formation of pseudomorphs after garnet. The HP granulite-facies assemblages record P–T conditions of 13–14 kbar at 760–800 °C. Retrogression and the release of fluids from crystallizing melts occurred at 7 kbar and 650–700 °C. A fluid inclusion study shows three types of fluid inclusion consisting of nearly pure CO₂, as well as H₂O–NaCl and H₂O–CO₂ mixtures. We suggest that a immiscible CO₂-bearing brine represents the fluid composition during high-grade peak metamorphism, and that the fluid inclusions containing H₂O–NaCl or nearly pure CO₂ represent trapped fluids from in situ crystallised melt. The results suggest strong isothermal decompression, which is probably related to a fast exhumation after crustal thickening in the central part of the Mozambique Belt in Tanzania.     

Chinese Trade in Latin America Compared to the European Union and the United States: The Case of Technology-Intensive Exports

Using trade data submitted by United Nations member states from 1995 to 2013, this article contributes to understanding China's trade with Latin America. By employing and building on the TECH score methodology, this project highlights China's growing economic connectivity with nine large and important Latin American economies. The analysis conducted here shows that compared with exports originating from other, more traditional foreign investors (i.e., the United States and the European Union member states), Chinese exports to these Latin American countries—although growing in sophistication over time—are relatively less technologically sophisticated during the study period. This work clarifies that in spite of these Latin American economies being highly complementary (for their natural resources and consumer markets) to China's manufacturing-intensive economy and despite the rapid growth in bilateral and biregional trade, China's displacement of traditional foreign actors, in terms of its technology-intensive exports to the region, is not supported by the data to date.     

Human–Wildlife Conflicts and their Associated Livelihood Impacts in and Around Chebera-Churchura National Park,Ethiopia

Human–wildlife conflict is one of the major challenges in conservation biology. Here, we investigated the human–wildlife conflicts and their impacts in and around Chebera-Churchura National Park, Ethiopia. We conducted semistructured interview for 300 people and five focus group discussions from November 2010 to January 2011. In addition, scats of 60 spotted hyenas were collected and analyzed. Totally, 12 carnivores, 6 herbivores, and 2 primate species posing a significant problem were identified. Intensive human–wildlife conflict was observed in Churchura, Sere, and Chebera villages which were very close to the park. The carnivore’s attacks during 2007–2011 had caused about 30.49% of livestock losses. The overall economic loss by wildlife attacks was estimated to be US$ 75,234 (US$ 83/household/year). Scat analysis confirmed a substantial contribution (59%) of livestock to spotted hyena’s diet. Thus, combined strategies like improving livestock husbandries and strengthen the capacity of managers are imperative to mitigate the problems.