盐津地区峨眉山玄武岩地球化学特征及成因分析

峨眉山火成岩省东部盐津地区玄武岩的岩石地球化学分析结果表明,盐津玄武岩w(SiO2)为47.97%~52.33%,w(Na2O+K2O)为3.35%~6.57%,Ti/Y值为496.29~567.80,w(TiO2)为3.60%~4.14%,属于钙碱性高钛玄武岩(HT)。岩石LREE/HREE值为7.34~7.88,轻稀土元素富集,分馏程度高,总体亏损Ba,K,Sr,P。高场强元素Nb/U比值为26.39,Ce/Y-Sm/Y和Th/Nb-Ce/Nb等比值均呈明显正相关系,表明盐津地区峨眉山玄武岩受到了明显地壳混染作用。Nb-Nb/Y和La-La/Sm图解中样品投点呈倾斜直线,表明盐津玄武岩岩浆受分离结晶作用影响较弱,δEu值为0.86~0.93,CaO/Al2O3与Mg#无明显相关关系,以及镜下观察均表明仅有少量斜长石、单斜辉石的分离结晶。盐津玄武岩与盐源和越西等地高钛玄武岩地球化学特征相似,具地幔柱成因特征,岩浆可能起源于富集地幔。分配系数相近的强不相容元素Ce/Sm比值为25.50,La/Yb-Sm/Yb图解中样品靠近石榴石尖晶石二辉橄榄岩区域,表明岩浆源区为石榴石尖晶石二辉橄榄岩。     

雷州半岛玛珥湖区玄武岩的年代、地球化学特征及其意义

我国南部雷州半岛是亚洲季风影响的核心区,区域内田洋、青桐洋和九斗洋这3个干玛珥湖沉积序列可为揭示低纬地区亚洲季风的轨道尺度变化提供关键证据。查明这些玛珥湖的形成年代、基底玄武岩的地球化学组成及其风化产物特征,为进一步获得沉积序列的年代控制、揭示沉积物替代指标的古气候意义提供了基础。本研究对3个干玛珥湖基底的玄武岩进行了K-Ar测年、地球化学成分和玛珥湖周围风化剖面粘土矿物的测试分析,得出了以下结论：1）田洋玛珥湖湖盆的形成年代为0.73~0.87 Ma,首次报道的青桐洋和九斗洋湖盆的形成时代分别为0.82 Ma和0.81~1.08 Ma,它们均属于早更新世晚期到中更新世早期的石峁岭期火山射气喷发形成的。2）田洋、青桐洋和九斗洋玛珥湖基底玄武岩均属于石英拉斑玄武岩。同一时期喷发的石英拉斑玄武岩广泛分布在玛珥湖的周围,这些玄武岩风化的产物以高岭石、三水铝石以及赤铁矿为主,在降水较为充沛的时期,物理或化学风化的产物随地表径流汇入湖盆,是玛珥湖沉积的主要来源。本研究为正在进行的低纬地区更新世轨道尺度季风降水重建提供了基础。

     

六合—仪征第三纪大陆碱性玄武岩微量元素地球化学

本文报道了六合-仪征第三纪大陆碱性玄武岩十八个样品的REE、Rb、Ba、Sr、Nb、Zr、Ni、Cr、V、Sc、Y、Ga、Zn、Cu等痕量元素含量,讨论了该岩套的成因及其地幔源区的特征。石榴石橄榄岩型地幔源区经较小程度部分熔融形成了基性原始岩浆;其后经过橄榄石和单斜辉石为主的结晶分异作用,演化后的岩浆喷出地表形成玄武岩套。本区碱性玄武岩的地幔源区曾受近期富集作用影响,具有富集LREE等不相容元素的特征。     

Mg-Sr isotopes of low-δ26Mg basalts tracing recycled carbonate species: Implication for the initial melting depth of the carbonated mantle in Eastern China

ABSTRACT

Recent studies show that crustal carbonates recycled into the mantle can be traced using Mg isotopes of basalts. However, the species of recycled carbonates are poorly constrained. Carbonates have lower δ²⁶Mg values and higher ⁸⁷Sr/⁸⁶Sr ratios relative to the mantle, but different carbonate species display different mixing curves with the mantle in the Mg-Sr isotopic diagram because of differences in their Sr and Mg contents. Thus a combined study of Mg-Sr isotopes can constrain the species of deeply recycled carbonates. Here, we present newly determined ⁸⁷Sr/⁸⁶Sr ratios of the <110 Ma basalts from Eastern China, and together with published Mg isotopic data we evaluate the species of recycled carbonates in the mantle and discuss their implication. The <110 Ma basalts display low δ²⁶Mg values of ?0.60 to ?0.30‰ and relatively low initial ⁸⁷Sr/⁸⁶Sr ratios of 0.70328 to 0.70537, suggesting that their mantle source was hybridized by recycled carbonates with a light Mg isotopic composition which had more significant effects on Mg than Sr isotope ratios. Mg-Sr isotopic data indicate that the recycled carbonates consist of magnesite and aragonite, but the possibility of calcite and dolomite cannot be eliminated. Based on the carbonated peridotite solidus, the equilibrium line between dolomite and magnesite + aragonite, as well as the mantle adiabat, the initial melting depth of the carbonated mantle, the source region of the studied basalts, was constrained at ~300–360 km. Thus, the subducted depth of the west Pacific slab underlying the carbonated mantle and supplying recycled carbonates should be greater than ~300–360 km, consistent with the seismic tomography result that the west Pacific slab now stagnates in the mantle transition zone.     

攀西地区红格钒钛磁铁矿床地球化学异常特征分析及矿床成因探讨

攀西地区基性-超基性含矿岩体以赋存超大型钒钛磁铁矿矿床而闻名于世,是我国重要的铁矿产地和重要的钒钛资源基地.通过对该矿床的地质特征、构造与围岩对成矿的控制作用及地球化学异常特征分析研究,认为红格钒钛磁铁矿成矿物质来源于上地幔,玄武岩浆结晶分异过程中有地壳物质混入地幔物质.矿床的形成对时间与空间要求严格.基性-超基性岩、灯影组白云质灰岩和峨眉山玄武岩是形成红格钒钛磁铁矿床的必要条件.     

河北汉诺坝玄武岩中深源包体和巨晶分布的动力学机理

汉诺坝碱性玄武岩是深源包体和巨晶的主要寄主岩,同时,也有不含包体的碱性玄武岩和含包体的拉斑玄武岩。本文基于理论计算,探讨了包体和巨晶分布的动力学机理。     

新疆东昆仑阿克苏库勒蛇绿岩地球化学特征和形成时限——来自辉长岩岩墙和枕状玄武岩的证据

康西瓦-苏巴什-鲸鱼湖混杂岩带作为昆仑造山带一条重要的混杂岩带,通常被认为是古特提斯洋的残存带,其形成时限一直受到地质界的密切关注。在该带新识别出一套蛇绿岩,采用LA-ICP-MS锆石U-Pb测年,获得该蛇绿岩铁镁质单元中辉长岩的年龄为270.3±0.7Ma（MSWD=0.65）,枕状玄武岩年龄为263.4±7.4Ma（MSWD=1.5）,属于晚二叠世,代表蛇绿岩的形成年龄。通过岩石地球化学特征、区域背景等分析,认为其形成于洋中脊环境,属于典型的MORB型蛇绿岩。结合主量、微量元素特征、构造环境及同位素年龄讨论,认为古特提斯洋主洋盆至少持续到晚二叠世。     

Preliminary geochemical study of volcanic rocks in the Pang Mayao area, Phrao, Chiang Mai, northern Thailand: tectonic setting of formation

The least-altered, Permian mafic volcanic rocks from the Pang Mayao area, Phrao District, Chiang Mai Province, part of Chiang Rai–Chiang Mai volcanic belt, have been analyzed and are found to be mid-ocean ridge and ocean–island basalts. The mid-ocean ridge basalts occur as lava flows or dike rocks. They are equigranular, fine- to medium-grained and consist largely of plagioclase, clinopyroxene and olivine. These basalt samples are tholeiitic, and have compositions very similar to T-MORB from the region where the Du Toit Fracture Zone intersects the Southwest Indian Ridge. The ocean–island basalt occurs as pillow breccia, and lava flows or dike rocks. They are slightly to moderately porphyritic, with phenocrysts/microphenocrysts of clinopyroxene, olivine, plagioclase and/or Fe–Ti oxide. The groundmass is very fine-grained, and made up largely of felty plagioclase laths with subordinate clinopyroxene. These basalt samples are alkalic, and chemically analogous to those from Haleakala Volcano, Maui, Hawaiian Chain. These mafic volcanic rocks may have been formed in a major ocean basin rather than in a mature back-arc basin.     

华夏陆块钠质高镁玄武岩地球化学特征及地质意义

赣州盆地位于钦杭(钦州—杭州)结合带南侧华夏陆块西部,由晚白垩世早期红色碎屑沉积岩系组成,其底部夹有一套玄武岩,全岩Si O_2含量为46.50%~48.13%,具有钠质高镁特征(Mg O=15.47%~18.24%,Mg~#=74~77,K_2O/Na_2O=0.22~0.39)。稀土元素配分型式表现出轻稀土富集右倾,没有明显的Eu异常的特点,表明岩浆没有明显的斜长石分离结晶作用;微量元素上富集大离子亲石元素,高场强元素特别是Ta、Nb、Ti亏损不明显,Cr、Ni的含量分别为235×10~(-6)~617×10~(-6)、157×10~(-6)~493×10~(-6),与原生岩浆的Cr、Ni含量接近,Ba/Nb值(13.51~23.18)和La/Nb值(0.82~1.03)表明源区有富集地幔组分;Sr—Nd—Pb—O同位素显示出源区性质具有EMⅡ型富集地幔特征。岩石学和地球化学特征表明,玄武岩具有原生岩浆性质,是富集地幔部分熔融的产物。同时为中生代华夏陆块EMⅡ型岩石圈地幔提供了准确的证据。由赣州盆地晚白垩世构造背景和构造环境判别图解可知,本区玄武岩形成于板内拉张环境,可能与古太平洋俯冲条件的转变有关。     

Large phreatomagmatic vent complex at Coombs Hills, Antarctica: Wet, explosive initiation of flood basalt volcanism in the Ferrar-Karoo LIP

The Mawson Formation and correlatives in the Transantarctic Mountains and South Africa record an early eruption episode related to the onset of Ferrar-Karoo flood basalt volcanism. Mawson Formation rocks at Coombs Hills comprise mainly (≥80% vol) structureless tuff breccia and coarse lapilli tuff cut by irregular dikes and sills, within a large vent complex (>30 km²). Quenched juvenile fragments of generally low but variable vesicularity, accretionary lapilli and country rock clasts within vent-fill, and pyroclastic density current deposits point to explosive interaction of basalt with groundwater in porous country rock and wet vent filling debris. Metre-scale dikes and pods of coherent basalt in places merge imperceptibly into peperite and then into surrounding breccia. Steeply dipping to sub-vertical depositional contacts juxtapose volcaniclastic rocks of contrasting componentry and grainsize. These sub-vertical tuff breccia zones are inferred to have formed when jets of debris + steam + water passed through unconsolidated vent-filling deposits. These jets of debris may have sometimes breached the surface to form subaerial tephra jets which fed subaerial pyroclastic density currents and fall deposits. Others, however, probably died out within vent fill before reaching the surface, allowing mixing and recycling of clasts which never reached the atmosphere. Most of the ejecta that did escape the debris-filled vents was rapidly recycled as vents broadened via lateral quarrying of country rock and bedded pyroclastic vent-rim deposits, which collapsed along the margins into individual vents. The unstratified, poorly sorted deposits comprising most of the complex are capped by tuff, lapilli tuff and tuff breccia beds inferred to have been deposited on the floor of the vent complex by pyroclastic density currents. Development of the extensive Coombs Hills vent-complex involved interaction of large volumes of magma and water. We infer that recycling of water, as well as recycling of pyroclasts, was important in maintaining water supply for phreatomagmatic interactions even when aquifer rock in the vent walls lay far from eruption sites as a consequence of vent-complex widening. The proportion of recycled water increased with vent-complex size in the same way that the proportion of recycled tephra did. Though water recycling leaves no direct rock record, the volcaniclastic deposits within the vent complex show through their lithofacies/structural architecture, lithofacies characteristics, and particle properties clear evidence for extensive and varied recycling of material as the complex evolved. Editorial responsibility: J. Donnelly-Nolan