变质流体研究某些重要进展

着重介绍了近年来国内外在变质流体与变质矿物共生组合，变质流体与变质反应温度，变质流体不混溶性以麻粒岩相变质流体特征研究方面所取得的一些重要进展。     

Roles for fluid and/or melt advection in forming high-P mafic migmatites, Fiordland, New Zealand

A series of striking migmatitic structures occur in rectilinear networks through western Fiordland, New Zealand, involving, for the most part, narrow anorthositic dykes that cut hornblende‐bearing orthogneiss. Adjacent to the dykes, host rocks show patchy, spatially restricted recrystallization and dehydration on a decimetre‐scale to garnet granulite. Although there is general agreement that the migration of silicate melt has formed at least parts of the structures, there is disagreement on the role of silicate melt in dehydrating the host rock. A variety of causal processes have been inferred, including metasomatism due to the ingress of a carbonic, mantle‐derived fluid; hornblende‐breakdown leading to water release and limited partial melting of host rocks; and dehydration induced by volatile scavenging by a migrating silicate melt. Variability in dyke assemblage, together with the correlation between dehydration structures and host rock silica content, are inconsistent with macroscopic metasomatism, and best match open system behaviour involving volatile scavenging by a migrating trondhjemitic liquid.     

江西印支期蔡江岩体中暗色微粒包体的发现及其地质意义

文章报道了江西蔡江花岗质岩体中发现暗色微粒包体,以及这些包体的地质、岩相学、LA-ICP-MS锆石U-Pb年代学和元素地球化学特征。包体多呈椭圆状,显示淬冷边和反向脉,具有典型的岩浆结构并含有针状磷灰石,有的包体含有长石捕虏晶。包体具有相对较低的SiO₂（低至57.05 wt%）和较高的MgO+Fe₂O₃（高达14.21 wt%）含量。LA-ICP-MS锆石U-Pb定年数据表明,包体形成于晚三叠世（224 Ma）,与寄主花岗岩（230~228 Ma）在误差范围内基本一致。上述特征表明,包体是离散的幔源偏基性岩浆团或者是幔源与寄主岩浆混合的产物。原始包体岩浆属于超钾质岩浆,可能是通过岩石圈地幔中交代成因的金云母辉石岩脉发生部分熔融而形成的。暗色微粒包体的发现为幔源岩浆底侵提供了直接证据,从而为蔡江花岗质岩石形成于较高温度提供佐证。该研究对于进一步探讨华南印支期花岗岩形成的热源机制具有意义。     

西南天山柯坪地区萨尔干基性岩脉U-Pb年代学及地球化学特征

柯坪地区发育一套沿走滑断层侵位的萨尔干基性岩脉,其产出于西南天山造山带与塔里木克拉通的接触部位,具有重要的意义。文章通过对萨尔干基性岩脉样品进行锆石LA-ICP-MS U-Pb年代学、岩石地球化学分析,探讨西南天山中新生代陆内造山作用过程。结果表明,萨尔干基性岩脉的LA-ICP-MS锆石U-Pb年龄为（49.14±0.8） Ma,表明该套岩石形成于始新世。地球化学表明该套岩石形成于与青藏高原碰撞远程效应相关的构造背景。     

Asymmetrically zoned reaction rims: assessment of grain boundary diffusivities and growth rates related to natural diffusion-controlled mineral reactions

This study explores garnet coronas around hedenbergite, which were formed by the reaction plagioclase + hedenbergite→garnet + quartz, to derive information about diffusion paths that allowed for material redistribution during reaction progress. Whereas quartz forms disconnected single grains along the garnet/hedenbergite boundaries, garnet forms ～20‐μm‐wide continuous polycrystalline rims along former plagioclase/hedenbergite phase boundaries. Individual garnet crystals are separated by low‐angle grain boundaries, which commonly form a direct link between the reaction interfaces of the plagioclase|garnet|hedenbergite succession. Compositional variations in garnet involve: (i) an overall asymmetric compositional zoning in Ca, Fe²⁺, Fe³⁺ and Al across the garnet layer; and (ii) micron‐scale compositional variations in the near‐grain boundary regions and along plagioclase/garnet phase boundaries. These compositional variations formed during garnet rim growth. Thereby, transfer of the chemical components occurred by a combination of fast‐path diffusion along grain boundaries within the garnet rim, slow diffusion through the interior of the garnet grains, and by fast diffusion along the garnet/plagioclase and the garnet/hedenbergite phase boundaries. Numerical simulation indicates that diffusion of Ca, Al and Fe²⁺ occurred about three to four, four and six to seven orders of magnitude faster along the grain boundaries than through the interior of the garnet grains. Fast‐path diffusion along grain boundaries contributed substantially to the bulk material transfer across the growing garnet rim. Despite the contribution of fast‐path diffusion, bulk diffusion through the garnet rim was too slow to allow for chemical equilibration of the phases involved in garnet rim formation even on a micrometre scale. Based on published garnet volume diffusion data the growth interval of a 20‐μm‐wide garnet rim is estimated at ～10³–10⁴ years at the inferred reaction conditions of 760 ± 50 °C at 7.6 kbar. Using the same parameterization of the growth law, 100‐μm‐ and 1‐mm‐thick garnet rims would grow within 10⁵–10⁶ and 10⁶–10⁷ years respectively.     

Petrological And Geochemical Characteristics Of The Granulitic Terrain Of Brejses, Bahia, Brazil

New petrological and geochemical characteristics of the Brejtes region, situated in the south of Bahia, Brazil are discussed. The region forms a part of the most important and extensive granulite facies terrain in Brazil of Archean/Paleoproterozoic age. Five groups of rock types all equilibrated in the granulite facies are identified in this region. They are: i) supracrustal and related rocks, ii) undifferentiated granulites, iii) hornblende bearing enderbite-charnockites, iv) hornblende free enderbite-charnockites, v) charnockites. The first group appears to be the oldest in the region as they form enclaves in the 2.9 Ga old undifferentiated granulites. The third and fourth group are enderbite-charnockites, whose protoliths constitute two series of calc-alkaline rocks, one titanium poor (hornblende free) and another titanium rich (hornblende bearing). U/Pb zircon SHRIMP dates indicate ages of formation at 2.81 Ga (hornblende free) and 2.69 Ga (hornblende bearing) for the two groups. The fifth group of rocks have charnockitic affinity and are present in the center of the Brejtes Dome. These rocks are also have calc-alkaline affinity, but show petrographic and geochemical characteristics distinct from those of other groups. Preliminary geochronological investigations by zircon Pb-Pb evaporation method yielded 2.6 Ga and 2.0 Ga for the charnockites from the inner core of the Brejtes Dome. These age data suggest that the circular structure was formed by the re-fusion of the 2.6 Ga old deep crustal material generating younger charnockites at 2.0 Ga.     

阿尔泰造山带富蕴基性麻粒岩折返过程:来自裂变径迹热年代学的限定

论文在阿尔泰造山带富蕴县乌恰沟基性麻粒岩的锆石SHRIMP年代学、地球化学、变质温压条件和形成的大地构造背景研究基础上,利用麻粒岩、围岩片麻岩和侵入到麻粒岩的辉绿岩岩墙的裂变径迹热年代学探讨了麻粒岩从深部折返至地表的过程。裂变径迹年代学研究发现基性麻粒岩的锆石裂变径迹年龄为三叠纪,而麻粒岩、围岩片麻岩和侵入到麻粒岩的辉绿岩岩墙的磷灰石裂变径迹年龄均显示为晚白垩世至新生代早期。对磷灰石裂变径迹测试所得到的径迹长度和单颗粒年龄数据进行热史模拟表明,三叠纪时,基性麻粒岩抬升至约地表以下7.8km的上地壳,温度冷却至锆石裂变径迹的封闭温度;晚白垩世至新生代早期(约100～50Ma),麻粒岩、围岩片麻岩和辉绿岩抬升至约地表以下3.5km,温度冷却至磷灰石裂变径迹的封闭温度;约50～15Ma,三者滞留在约地表以下1.7km的磷灰石部分退火带;约15Ma以来,喜马拉雅运动使得它们被抬升剥蚀至地表。     

塔里木克拉通东北缘二叠纪镁铁质岩浆氧化物与硫化物成矿条件对比

塔里木克拉通东北缘坡北、磁海等地二叠纪幔源岩浆活动形成了镍钴硫化物矿床和铁钴氧化物矿床,两者赋矿镁铁-超镁铁岩体的年龄相近(290～260 Ma),主、微量元素和Sr-Nd-Hf同位素组成相似,分配系数接近的微量元素比值分布于相同趋势线,揭示两者岩浆源区相同,可能为俯冲板片流体交代的亏损地幔或软流圈地幔。两类矿床镁铁-超镁铁质岩中Co与Ni含量正相关,Co主要富集在基性程度高的岩石中;块状硫化物与磁铁矿矿石中Co与Ni相关性差,Co和Ni具有不同的富集机制,Co热液富集作用明显。北山镁铁-超镁铁杂岩体是地幔柱相关软流圈上涌,诱发俯冲板片交代的亏损岩石圈地幔发生部分熔融,形成的高镁母岩浆演化过程中经历壳源混染、硫化物饱和富集镍钴形成铜镍钴硫化物矿床,富铁母岩浆氧逸度高、富水,岩浆分离结晶磁铁矿、叠加热液作用富集钴,形成铁钴氧化物矿床。     

New constraints on granulite facies metamorphism and melt production in the Lewisian Complex,northwest Scotland

In this study, we investigate the metamorphic history of the Assynt and Gruinard blocks of the Archean Lewisian Complex, northwest Scotland, which are considered by some to represent discrete crustal terranes. For samples of mafic and intermediate rocks, phase diagrams were constructed in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O₂ (NCKFMASHTO) system using whole‐rock compositions. Our results indicate that all samples equilibrated at similar peak metamorphic conditions of ~8–10 kbar and ~900–1,000°C, consistent with field evidence for in situ partial melting and the classic interpretation of the central region of the Lewisian Complex as representing a single crustal block. Melt‐reintegration modelling was employed in order to estimate probable protolith compositions. Phase equilibria calculated for these modelled undepleted precursors match well with those determined for a subsolidus amphibolite from Gairloch in the southern region of the Lewisian Complex. Both subsolidus lithologies exhibit similar phase relations and potential melt fertility, with both expected to produce orthopyroxene‐bearing hornblende granulites, with or without garnet, at the conditions inferred for the Badcallian metamorphic peak. For fully hydrated protoliths, prograde melting is predicted to first occur at ~620°C and ~9.5 kbar, with up to 45% partial melt predicted to form at peak conditions in a closed‐system environment. Partial melts calculated for both compositions between 610 and 1,050°C are mostly trondhjemitic. Although the melt‐reintegrated granulite is predicted to produce more potassic (granitic) melts at ~700–900°C, the modelled melts are consistent with the measured compositions of felsic sheets from the central region Lewisian Complex.     

Garnet-bearing Granulite Facies Rock Xenoliths from Late Mesozoic Volcaniclastic Breccia, Xinyang, Henan Province

This paper presents the primary results of petrologic, mineralogical and petrochemical studies of garnet-bearing granulite facies rock xenoliths from Xinyang, Henan Province. These xenoliths, which are found in a pipe of late Mesozoic volcaniclastic breccia, are of high density (3.13-3.30 g/cm3) and high seismic velocity (Vp = 7.04-7.31 km/s), being products of underplating of basaltic magmas and had experienced granulite facies metamorphism. The underplating and metamorphism took place before the eruption of the host rock. Petrographical studies and equilibrium T-P calculations show that these xenoliths were captured at a 49 km depth and experienced at least a 16 km uplift before they were captured. The dynamics of the uplift could be related to the continent-continent collision between the North China plate and the Yangtze plate during the Triassic.