勉略构造带新元古代洋盆俯冲作用：来自略阳地区纸房沟岩片火山岩锆石U- Pb年龄和Lu- Hf同位素的证据

纸房沟岩片位于勉略构造带略阳地区。通过细致的岩石学和地球化学研究,将纸房沟岩片内的火山岩分为拉斑玄武岩系列（Ⅰ类）和钙碱性火山岩系列（Ⅱ类）。Ⅰ类火山岩稀土配分曲线左倾,富Na贫P,整体具有N- MORB特点,形成于洋脊构造环境。相比Ⅰ类火山岩,Ⅱ类火山岩具有更高的SiO2(49.02％~61.86％)和K2O(0.32％~1.55％)含量,相对亏损Nb、Ta、P和Ti,形成于陆缘弧构造环境。Ⅱ类火山岩锆石Lu- Hf同位素测试结果显示,εHf(t)值主体为负值,介于-8.01~+0.77,表明其主要为古老地壳物质熔融成因。Ⅱ类火山岩LA- ICP- MS锆石U- Pb测年结果为854±3Ma(MSWD=0.12, n=30)、844±4Ma (MSWD=0.03, n=15),表明纸房沟岩片火山岩结晶时代为新元古代早中期。综合前人成果认为,纸房沟岩片火山岩为新元古代勉略洋盆俯冲的产物,俯冲作用一直持续到800Ma左右,该俯冲过程很可能是对全球性Rodinia超大陆聚合事件的响应。     

古亚洲洋俯冲板片断离与后造山伸展：贺根山缝合带火山岩年代学和地球化学证据

本文以出露于贺根山缝合带迪彦庙蛇绿混杂岩北侧的乌兰拜其白音高老组流纹岩- 粗面岩为研究对象,通过野外地质调查和岩石学、地球化学、锆石U- Pb年代学研究,探讨岩石成因类型、构造环境和古亚洲洋俯冲板片断离与后造山伸展过程。岩石地球化学研究表明, 乌兰拜其地区白音高老组流纹岩具有较高的SiO 2、Al 2O 3、K 2O和Na 2O+K 2O含量,以及较高的Ga/Al比值,相对贫CaO、MgO、Sr、Ba、Eu、Ti和P,稀土元素配分曲线为右倾海鸥式分布,负铕异常显著。该区粗面岩属于钾玄岩系列,具有高碱(Na 2O+K 2O)、高K 2O、高Al 2O 3、低TiO 2,富集Rb、Ba、U和轻稀土元素, 亏损 Nb、Ta 和 Ti,稀土元素配分曲线为右倾式分布。岩石学和岩石地球化学特征表明,乌兰拜其地区白音高老组流纹岩为迪彦庙- 白音布拉格蛇绿混杂岩带早白垩世后造山A型花岗岩浆的喷出相- A型流纹岩,其形成于后造山伸展构造环境;粗面岩为后造山型钾玄质火山岩,与洋壳俯冲作用有关,形成于俯冲板片断离- 后造山伸展构造背景。流纹岩和粗面岩锆石LA- ICP- MS U- Pb同位素测年,获得206Pb/238U加权平均年龄分别为140. 4±1. 2Ma和134. 9±1. 1Ma,表明白音高老组流纹岩- 粗面岩喷发于早白垩世,反映了贺根山缝合带早白垩世后造山A型花岗岩浆- 钾玄质岩浆作用事件。结合贺根山缝合带的壳幔电性结构特征和晚古生代蛇绿岩- 岛弧岩浆岩、中生代后造山A型岩浆岩的时空分布与演化关系,认为根山缝合带三叠纪- 早白垩世后造山伸展岩浆作用与古亚洲洋俯冲板片断离作用有关,提出了该区后造山A型花岗岩浆- 钾玄质岩浆作用的俯冲板片断离- 后造山伸展地球动力学模式。     

内蒙古贺斯格乌拉牧场白音高老组火山岩U-Pb年龄及地球化学特征

白音高老组火山岩在大兴安岭地区广泛分布,本文对大兴安岭中南部贺斯格乌拉牧场白音高老组酸性火山岩进行了锆石U-Pb年代学、岩石地球化学和Sr-Nd同位素分析,探讨其岩石成因及构造背景。位于大兴安岭中南段东乌旗地区的白音高老组火山岩,主要岩性为流纹岩、流纹质凝灰岩等,LA-ICP-MS锆石U-Pb年龄分别为129. 8±0. 8 Ma、128. 2±2. 8 Ma,属早白垩世早期;从岩石地球化学特征上看,其主量元素SiO_2含量68. 76%～76. 18%、Al_2O_3含量11. 84%～13. 38%,属高钾钙碱性岩石;稀土总量较高,(La/Yb)N 6,(La/Sm)_N 3,显示为轻稀土富集型,δEu显示负铕异常(0. 4～0. 6),微量元素以富集大离子亲石元素K、Rb、Ba,贫高场强元素Nb、P、Ti为特征; Sr-Nd同位素组成上具有低I_(Sr)、高ε_(Nd)(t)和低t_(DM)的特征(I_(Sr)=0. 7039～0. 7045,ε_(Nd)(t)=2. 65～4. 39)。火山岩浆来源于下地壳基性物质的部分熔融,综合研究并结合前人资料认为,白音高老组流纹岩形成于滨太平洋板块俯冲后伸展及蒙古-鄂霍次克洋闭合后的综合效应下。     

长白山火山活动发展阶段及火山灾害评价

长白山地区火山活动划分二个发展阶段：以点一线形式喷发形成的广阔玄武岩台地阶段一焊缝构造发展阶段;中心式大规模喷发形成的锥状火山机构一焊点构造发展阶段,长白山地区乃至吉林东部地区中一新生代以来抬升平均速率81m／Ma及白头山一泉阳一露水河一带中生代以来存在一个火山坳陷盆地。     

烃源岩不同性质有机酸的分离及其检测方法

烃源岩中的有机酸来源于有机质,但有机质具有不同的赋存形式,有机酸具有不同性质,这将影响有机酸与不同赋存有机质的关系,进而影响分离和检测方法。文章在总结前人对有机质赋存形式和有机酸性质等特征的基础上,提出烃源岩中的有机酸并以非单一的形式存在,具有水溶性、脂溶性和难溶性有机酸三种类型,游离有机质中存在水溶性和脂溶性有机酸,而结合有机质中存在水溶性、脂溶性和难溶性有机酸。因此在检测方法上需采取分步分离的方法,且根据有机酸的性质选取合适的检测方法,即水溶性有机酸利用离子色谱检测,索氏抽提得到的脂溶性有机酸利用气相色谱—质谱检测,通过酸解抽提残渣得到的难溶性有机酸利用红外光谱检测,全面系统地认识烃源岩中有机酸含量和类型等特征。这对进一步探讨烃源岩各种类型有机酸特征和演化规律,深化烃源岩有机质生烃以及有机—无机相互作用等机理都具有重要意义。     

Petrology and geochemistry of mafic and ultramafic cumulate rocks from the eastern part of the Sabzevar ophiolite (NE Iran): Implications for their petrogenesis and tectonic setting

The Late Cretaceous Sabzevar ophiolite represents one of the largest and most complete fragments of Tethyan oceanic lithosphere in the NE Iran. It is mainly composed of serpentinized mantle peridotites slices; nonetheless, minor tectonic slices of all crustal sequence constituents are observed in this ophiolite. The crustal sequence contains a well-developed ultramafic and mafic cumulates section, comprising plagioclase-bearing wehrlite, olivine clinopyroxenite, olivine gabbronorite, gabbronorite, amphibole gabbronorite and quartz gabbronorite with adcumulate, mesocumulate, heteradcumulate and orthocumulate textures. The crystallization order for these rocks is olivine ​± ​chromian spinel → clinopyroxene → plagioclase → orthopyroxene → amphibole. The presence of primary magmatic amphiboles in the cumulate rocks shows that the parent magma evolved under hydrous conditions. Geochemically, the studied rock units are characterized by low TiO₂ (0.18–0.57 ​wt.%), P₂O₅ (<0.05 ​wt.%), K₂O (0.01–0.51 ​wt.%) and total alkali contents (0.12–3.04 ​wt.%). They indicate fractionated trends in the chondrite-normalized rare earth element (REE) plots and multi-element diagrams (spider diagrams). The general trend of the spider diagrams exhibit slight enrichment in large ion lithophile elements (LILEs) relative to high field strength elements (HFSEs) and positive anomalies in Sr, Pb and Eu and negative anomalies in Zr and Nb relative to the adjacent elements. The REE plots of these rocks display increasing trend from La to Sm, positive Eu anomaly (Eu/Eu1 ​= ​1.06–1.54) and an almost flat pattern from medium REE (MREE) to heavy REE (HREE) region [(Gd/Yb)_N ​= ​1–1.17]. Moreover, clinopyroxenes from the cumulate rocks have low REE contents and show marked depletion in light REE (LREE) compared to MREE and HREE [(La/Sm)_N ​= ​0.10–0.27 and (La/Yb)_N ​= ​0.08–0.22]. The composition of calculated melts in equilibrium with the clinopyroxenes from less evolved cumulate samples are closely similar to island arc tholeiitic (IAT) magmas. Modal mineralogy, geochemical features and REE modeling indicate that Sabzevar cumulate rocks were formed by crystal accumulation from a hydrous depleted basaltic melt with IAT affinity. This melt has been produced by moderate to high degree (~15%) of partial melting a depleted mantle source, which partially underwent metasomatic enrichment from subducted slab components in an intra-oceanic arc setting.     

大兴安岭满归地区变中酸性火山岩LA-ICP-MS锆石U-Pb年龄及其地质意义

对大兴安岭满归地区新元古界—下寒武统大网子组变中酸性火山岩进行锆石U-Pb同位素年代学研究,探讨其形成时代及地质意义。大网子组由变安山岩、变英安岩、变流纹岩和少量变晶屑凝灰岩组成,缺少板岩、变砂岩、片岩等沉积岩夹层。通过对变安山岩进行锆石U-Pb同位素年龄测定,获得其锆石²⁰⁶Pb/²³⁸U加权平均年龄为(199±1) Ma,表明大网子组变中酸性火山岩形成于早侏罗世早期,非前人认为的形成于新元古代—早寒武世。额尔古纳地块早侏罗世火山岩为漠河盆地提供了物源,表明额尔古纳地块在早侏罗世处于火山-岩浆弧构造背景。该研究为蒙古—鄂霍茨克洋闭合过程中的地球动力学研究提供了新资料。     

History of scoria-cone eruptions on the eastern shoulder of the Kenya–Tanzania Rift revealed in the 250-ka sediment record of Lake Chala near Mount Kilimanjaro

Reconstructions of the timing and frequency of past eruptions are important to assess the propensity for future volcanic activity, yet in volcanic areas such as the East African Rift only piecemeal eruption histories exist. Understanding the volcanic history of scoria-cone fields, where eruptions are often infrequent and deposits strongly weathered, is particularly challenging. Here we reconstruct a history of volcanism from scoria cones situated along the eastern shoulders of the Kenya–Tanzania Rift, using a sequence of tephra (volcanic ash) layers preserved in the ~250-ka sediment record of Lake Chala near Mount Kilimanjaro. Seven visible and two non-visible (crypto-) tephra layers in the Lake Chala sequence are attributed to activity from the Mt Kilimanjaro (northern Tanzania) and the Chyulu Hills (southern Kenya) volcanic fields, on the basis of their glass chemistry, textural characteristics and known eruption chronology. The Lake Chala record of eruptions from scoria cones in the Chyulu Hills volcanic field confirms geological and historical evidence of its recent activity, and provides first-order age estimates for seven previously unknown eruptions. Long and well-resolved sedimentary records such as that of Lake Chala have significant potential for resolving regional eruption chronologies spanning hundreds of thousands of years.     

青海共和盆地中三叠世花岗岩组合岩石成因:地球化学、锆石U-Pb年代学及Hf同位素约束

青海共和盆地位于青藏高原东北缘,以往有关共和盆地及邻区早-中三叠世岩浆岩成因机制的认识分歧较大,且研究主要集中在露头岩石方面。本文以共和盆地干热岩GR1井深部花岗岩岩芯样品作为研究对象,对其进行岩石学、长石电子探针、主微量元素地球化学、锆石U-Pb年代学及Lu-Hf同位素研究。矿物组成及长石电子探针测试结果显示花岗岩主要为奥长花岗岩、英云闪长岩及花岗闪长岩。锆石U-Pb测年结果表明,奥长花岗岩的结晶年龄为236.5±1.7Ma,英云闪长岩的岩浆结晶年龄为241.6±3.0Ma。主、微量元素地球化学显示这些花岗岩主要为准铝质,属于高钾钙碱性系列。全岩Ta-Nb-Hf等不相容元素图解及锆石Hf同位素数据表明共和盆地的236.5~241.6Ma花岗岩显示火山弧及同碰撞花岗岩成分特征,说明中三叠世共和地区发生俯冲-碰撞转换。结合本文数据与区域背景资料,作者认为：共和盆地早-中三叠世花岗岩组合的形成与印支期宗务隆洋的南向俯冲作用密切相关,此时,在宗务隆-青海南山-西秦岭北缘存在统一的大陆边缘弧环境;在236~241Ma时发生俯冲-碰撞转换;晚三叠世时宗务隆-青海南山-西秦岭北缘已处于碰撞期和后碰撞期。