中国大陆科学钻探工程主孔（734～933m）榴辉岩和片麻岩元素及Sr-Nd同位素地球化学研究

对中国大陆科学钻探工程主孔两段榴辉岩与片麻岩互层的岩芯样品(Ⅰ:734.21-737.16m和Ⅱ:929.67-932.86m)分别进行了主要元素和微量元素以及Sr-Nd同位素分析。结果表明:(1)榴辉岩具有较大的成分变化范围(SiO2含量为46.8%-59.8%),表现出平坦或轻稀土(LREE)富集的分布模式和大离子亲石元素(LILE)富集或亏损以及Nb、Ta负异常特征。部分榴辉岩样品具有明显低的活动性元素(Rb、Ba和K)含量,指示了板块俯冲过程中的脱水变质效应;(2)两段岩芯中的片麻岩具有明显不同的主量和微量元素组成,其中第Ⅰ段具有相对较低的SiO2含量(61.3%～66.2%)和高的重稀土(HREE)含量,而第Ⅱ段具有明显偏高的SiO2含量(73.8%～74.1%)和低的HREE含量。但两段均表现出LREE富集和Eu负异常以及LILE富集和高场强元素(Nb、Ta、Ti)负异常特征;(3)榴辉岩和第Ⅰ段岩芯中的片麻岩具有相近的且偏高的εNd(750Ma)值(-3.6- 0.5),而第Ⅱ段岩芯中的片麻岩具有明显偏低的εNd(750Ma)值(-8.7)。部分片麻岩样品表现出较高的87Sr/86Sr比值(0.7070)和非常低的Rb/Sr比值(0.008),指示岩石Rb-Sr同位素体系受到了变质扰动。非活动性元素如Zr、Hf、Nb、Ta、Ti、Y、REE和Ti在脱水变质过程中没有受到明显扰动,因此可用于恢复榴辉岩和片麻岩的原岩性质及其形成的大地构造背景。根据分析样品的元素和Nd同位素特点,推测榴辉岩原岩具有板内玄武岩性质,第Ⅰ段岩芯中的片麻岩原岩为玄武质岩浆上升过程中同化地壳物质形成的中性岩,而第Ⅱ段岩芯中的片麻岩原岩为地壳物质重熔形成的酸性岩。因此,深钻榴辉岩和片麻岩原岩为新元古代华南陆块北缘裂谷构造带双峰式岩浆活动的产物,在岩浆侵位过程中经历了高温大气降水热液蚀变。     

大西洋洋中脊TAG热液区中块状硫化物的Os同位素研究

新测得TAG热液区中5件海底块状硫化物样品的锇含量及其同位素组成,187Os/186Os比值在2.305～7.879之间,均值为5.986,介于现代海水和上部洋壳岩石的锇同位素组成之间,表明该区海底块状硫化物中锇是海水和上部洋壳来源锇混合的产物.在海底热液循环过程中,海水的混入对该区热液流体的Os浓度及其同位素组成产生了明显的影响。     

原油在储层介质中的加水裂解生气模拟实验

采用高温高压热模拟实验方法,开展了原油在砂岩和火成岩储层介质中的加水裂解生气模拟实验研究.结果表明,原油开始大量裂解的温度是400℃,随模拟温度增加,甲烷相对含量增大,乙烷以上重烃气尤其是丙烷相对含量减小.其中砂岩的油水混合物裂解生气主要发生在450～500℃之间,生气窗范围小,对应的烃气产率高,火成岩的油水混合物裂解生气主要发生在450～600℃之间,生气窗范围大,对应的烃气产率小.模拟烃气的组分碳同位素分馏显著,随模拟温度增加呈变重趋势.在裂解生气过程中,水解加氢和催化作用对烃气的组成、产率和碳同位素分布有重要影响。     

沐川太平砂岩型铼钼（饿）矿点的地质特征和矿化时代

四川沐川县民主-太平-带含钼砂岩为一新矿化类型——沉积砂岩型铼钼（锇）矿点。X-射线粉晶衍射分析结果表明其中微-细晶鳞片状含钼矿物为晶质辉钼矿；高精度质谱分析发现辉钼矿中分散元素Re和铂族元素Os含量很高，具有重要的综合利用价值；高精度Re-Os同位素测年证明辉钼矿形成年龄与含矿的中生代红物学和矿床学均具有重要的理论意义和应用价值。     

苏皖地区石炭纪海相碳酸盐岩碳和氧同位素演化规律

对江苏南京孔山和安徽巢湖凤凰山石炭系碳酸盐岩C、O稳定同位素进行了测定。结果表明，苏皖地区石炭系δ^13C,δ^18O记录是以4个同位素演化阶段为特征，前3个同位素演化阶段与同时代的北美石炭纪相似，仅仅是内部演化特征略有不同，这反映了区域性的沉积环境的不同变化。在金陵组下部、和州组下部、黄龙组中下部和船山组层段，δ^13C表现出明显的正漂移，这可能是受植物和生物量增长、有机碳储藏量增加所引起的。δ^18O记录总体上与δ^13C值呈相似的变化趋势。δ^18O增加记录了气候变冷和冰川作用的结果。δ^18O负漂移与气候变暖和冰川消融是一致的。在浅水潮坪环境，大气淡水的淋滤作用使δ^13C和δ^18O值明显降低。     

Constraints on the application of carbon isotope thermometry in high- to ultrahigh-temperature metamorphic terranes

Nine marble horizons from the granulite facies terrane of southern India were examined in detail for stable carbon and oxygen isotopes in calcite and carbon isotopes in graphite. The marbles in Trivandrum Block show coupled lowering of δ¹³C and δ¹⁸O values in calcite and heterogeneous single crystal δ¹³C values (? 1 to ? 10‰) for graphite indicating varying carbon isotope fractionation between calcite and graphite, despite the granulite facies regional metamorphic conditions. The stable isotope patterns suggest alteration of δ¹³C and δ¹⁸O values in marbles by infiltration of low δ¹³C–δ¹⁸O‐bearing fluids, the extent of alteration being a direct function of the fluid‐rock ratio. The carbon isotope zonation preserved in graphite suggests that the graphite crystals precipitated/recrystallized in the presence of an externally derived CO₂‐rich fluid, and that the infiltration had occurred under high temperature and low f_O2 conditions during metamorphism. The onset of graphite precipitation resulted in a depletion of the carbon isotope values of the remaining fluid+calcite carbon reservoir, following a Rayleigh‐type distillation process within fluid‐rich pockets/pathways in marbles resulting in the observed zonation. The results suggest that calcite–graphite thermometry cannot be applied in marbles that are affected by external carbonic fluid infiltration. However, marble horizons in the Madurai Block, where the effect of fluid infiltration is not detected, record clear imprints of ultrahigh temperature metamorphism (800–1000 °C), with fractionations reaching <2‰. Zonation studies on graphite show a nominal rimward lowering δ¹³C on the order of 1 to 2‰. The zonation carries the imprint of fluid deficient/absent UHT metamorphism. Commonly, calculated core temperatures are > 1000 °C and would be consistent with UHT metamorphism.     

Neoproterozoic to Early Cambrian history of an active plate margin in the Teplá–Barrandian unit—a correlation of U–Pb isotopic-dilution-TIMS ages (Bohemia, Czech Republic)

The Teplá–Barrandian unit (TBU) of the Bohemian Massif shared a common geological history throughout the Neoproterozoic and Cambrian with the Avalonian–Cadomian terranes. The Neoproterozoic evolution of an active plate margin in the Teplá–Barrandian is similar to Avalonian rocks in Newfoundland, whereas the Cambrian transtension and related calc-alkaline plutons are reminiscent of the Cadomian Ossa–Morena Zone and the Armorican Massif in western Europe. The Neoproterozoic evolution of the Teplá–Barrandian unit fits well with that of the Lausitz area (Saxothuringian unit), but is significantly distinct from the history of the Moravo–Silesian unit.The oldest volcanic activity in the Bohemian Massif is dated at 609+17/−19 Ma (U–Pb upper intercept). Subduction-related volcanic rocks have been dated from 585±7 to 568±3 Ma (lower intercept, rhyolite boulders), which pre-dates the age of sedimentation of the Cadomian flysch ( t chovice Group). Accretion, uplift and erosion of the volcanic arc is documented by the Neoproterozoic Dob í conglomerate of the upper part of the flysch. The intrusion age of 541+7/−8 Ma from the Zgorzelec granodiorite is interpreted as a minimum age of the Neoproterozoic sequence. The Neoproterozoic crust was tilted and subsequently early Cambrian intrusions dated at 522±2 Ma (T ovice granite), 524±3 Ma (V epadly granodiorite), 523±3 Ma (Smr ovice tonalite), 523±1 Ma (Smr ovice gabbro) and 524±0.8 Ma (Orlovice gabbro) were emplaced into transtensive shear zones.     

云南腾冲地块北部空树河组一个菱铁矿结核中的C、O同位素变化特征

空树河组是滇西腾冲地块北部的石碳－二叠纪冈瓦纳相沉积。菱铁矿结核见于该组顶部的黑色泥岩中。将一个结核通过中心切开，在切面上由中心向边缘用牙钻等间隔提取10个样品。同位素测试结果显示，δ^13C自中心向边缘逐渐由－8．09％减为－16．12％，最外一个样例外（－15．39‰），而δ^18O自中心向边缘逐渐由－10．64‰增加为0‰左右。δ^13C的变化情况表明，菱铁矿结核可能形成于硫酸盐还原带。在解释δ^18o的变化情况时，推测在结核开始生长时可能有δ^18O亏损的大气降水掺入，随着埋藏深度的逐渐加大，孔隙水的O同位素逐渐趋近正常海水的值（0‰）。     

Continental crust and lithospheric mantle interaction beneath North China: isotopic evidence from granulite xenoliths in Hannuoba, Sino-Korean craton

Mafic granulite and pyroxenite xenoliths from Cenozoic alkaline basalts at Hannuoba, Hebei Province, North China have been selected for a systematic geochemical and Sr–Nd–Pb isotopic study, which provides a unique opportunity to explore nature of the lower crust and the interaction between the continental crust and lithospheric mantle beneath an Archean craton. The major, compatible and incompatible elements and radiogenic isotopes of these xenoliths suggest great chemical heterogeneity of the lower crust beneath the Hannuoba region. Petrological and geochemical evidences indicate a clear cumulate origin, and most likely, they are related to basaltic underplating in different geological episodes. However, the Sr–Nd–Pb isotopic compositions of the xenoliths reveal a profound enriched source signature (EM I) with some influence of EM II, which implies that some portion of pre-existing, old metasomatized subcontinental lithospheric mantle could have played an important role in their genesis. It is suggested that the interaction between continental crust and subcontinental mantle as manifested by basaltic underplating would be closely related to regional tectonic episodes and geodynamic processes in the deep part of subcontinental lithospheric mantle.     

Study on Paleoenvironment since Late Glacial Eooch in Lanzhou Area, China

The Hongzuisi Section in Lanzhou area is used to infer the paleoclimate since the late glacial epoch. Through combined analysis of organic carbon isotope and CaCO3 content, paleoenvironment evolution of Hongzuisi Section since the late glacial epoch is discussed. There were changes in both drymoist and warm-cold. Especially the climate changes can be compared with synchronous sections of other areas, which provides useful information for our future forecast.